Polyoxometalate chemistry:
Gespeichert in:
| Weitere Verfasser: | , |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Cambridge, MA
Elsevier Academic Press
2017
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| Ausgabe: | First edition |
| Schriftenreihe: | Advances in inorganic chemistry
volume 69 |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | xii, 346 Seiten Illustrationen |
| ISBN: | 9780128111055 |
Internformat
MARC
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| 245 | 1 | 0 | |a Polyoxometalate chemistry |c edited by Rudi van Eldik, Leroy Cronin |
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Datensatz im Suchindex
| _version_ | 1804177378008629248 |
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| adam_text | Titel: Polyoxometalate chemistry
Autor: Eldik, Rudi van
Jahr: 2017
VOLUME SIXTY NINE Advances in INORGANIC CHEMISTRY Polyoxometalate Chemistry Edited by RUDI van ELDIK University of Erlangen-Nuremberg, Germany Jagiellonian University, Krakow, Poland LEROY CRONIN University of Glasgow, United Kingdom ACADEMIC PRESS An imprint of Elsevier elsevier.com
CONTENTS Contributors ix Preface xi 1. Exploring Self-Assembly and the Self-Organization of Nanoscale Inorganic Polyoxometalate Clusters 1 H. N. Miras, D.-L. Long, and L. Cronin I. Introduction to Polyoxometalate Chemistry 2 2. From Serendipity to Directed Assembly 4 3. Synthetic Methodologies 6 4 . POM-Based Supramolecular Structures 18 5. From Self-Assembled to Self-Organizing Cluster Systems 21 6 . Conclusions 24 References 25 2. Supramolecular Structures Formation of Polyoxometalates in Solution Driven by Counterion-Macroion Interaction 29 Y. Gao, S.A. Eghtesadi, and T. Liu 1. Introduction 30 2. Self-Assembly of POM Macroions Into Blackberries 33 3. Counterion-Mediated Self-Assembly of POM Macroions 35 4 . The Kinetic Properties and Lag Phase of POM Assembly 42 5 . POM-Counterion Ion Pairing in Solution 45 6. Dynamic of Alkali Counterions in POM Solution 47 7. Cation Transportation Through Blackberry Membrane 49 8. Selective Permeability of Uranyl Peroxide Nanocage 51 9 . Self-Recognition Behaviors During Their Self-Assembly 56 10. Simulation Studies on Self-Assembly of POM Macroions 60 11. Conclusions 62 Acknowledgments 63 Reference 63 3. Electron Transfer-Oxygen Transfer Reactions and Beyond With Polyoxometalates 67 R. Neumann 1. Mechanisms for the Aerobic Oxidation of Organic Compounds 68 2. The H s PV 2 Mo ]0 O 40 Polyoxometalate and Electron Transfer Oxidations 70 v
vi Contents 3. The First Example of Electron Transfer-Oxygen Transfer Catalyzed by H 5 PV 2 Mo 10 O 40 72 4 . Oxidation of Sulfides 73 5. Oxidation of Primary and Vicinal Alcohols 76 6. Oxidation of via Activation of C-H Bonds Revisited 79 7. Insertion of Oxygen Into a Carbon-Metal Bond 84 8. The Structure of H 5 PV 2 Mo,o 04 o During the Catalytic Reaction 85 9 . Conclusions 87 Acknowledgments 89 References 89 4. Oxygen-Isotope Exchange and Metastable Dissociation in Oxides 91 W.FI. Casey 1. Introduction 92 2 . Broad Reactivity Trends for Dissolving Materials and Glasses 94 3. Acid-Base Chemistry and Reactivity in Niobates 98 4 . The Transition to a Partly Detached Structure in MAI 12 Cations 102 5. Metastable Intermediates 105 6. Conclusions 112 Acknowledgments 113 References 113 5. Polyoxometalate Multielectron Catalysts in Solar Fuel Production 117 S.M. Lauinger, Q. Yin, Y.V. Geletii, and C.L. Hill 1. Introduction 118 2 . Definitions 119 3. Water Splitting Overview 123 4 . Water Oxidation Catalysts 124 5. Water Reduction Catalysts 134 6. Immobilization of Polyoxometalate WOCs 137 7. Assessment of Catalytic Activity 143 8. Stability in POM Catalytic Systems 145 9 . Conclusions 148 Acknowledgments 149 References 149
Contents vii 6. [Co 9 (H 2 0) 6 (0H) 3 (HP0 4 ) 2 (PW 9 0 34 ) 3 ] 16 -. A Highly Efficient Catalyst for Water Oxidation 155 J. Soriano-López, S. Goberna-Ferrón, J.J. Carbó, J.M. Poblet, and J.R. Galán-Mascarós 1 . Introduction 156 2. Homogeneous Electrocatalytic Water Oxidation Activity of Co 9 158 3. Characterization of the Catalytic Activity of Co 9 With NaCIO 161 4 . Stability and Solution Speciation Under Catalytic Water Oxidation Conditions 166 5. Heterogeneous WOC With Modified Cog/Carbon Paste Electrodes 171 6. Conclusions 177 References 178 7. Polyoxometalate-Functionalized Nanocarbon Materials for Energy Conversion, Energy Storage, and Sensor Systems 181 C.-G. Lin, J. Hu, and Y.-F. Song 1 . Introduction 182 2. Synthesis of the POM/Nanocarbon Composites 183 3. Applications of the POM/Nanocarbon Composites 185 4 . Conclusions 208 References 209 8. Design of Magnetic Polyoxometalates for Molecular Spintronics and as Spin Qubits 213 J. J. Baldoví, S. Cardona-Serra, A. Gaita-Ari?o, and E. Coronado 1 . Introduction 213 2. Relevant Precedent Studies of POMs in Molecular Magnetism 217 3. Relevance of POMs In Molecular Spintronics 232 4. Recent Advances on the Use of POMs for Quantum Computing 236 5. Concluding Remarks 243 Acknowledgments 245 References 245 9. Perspectives for Polyoxometalates in Single-Molecule Electronics and Spintronics 251 K. Y. Monakhov, M. Moors, and P. Kögerler 1 . Introduction 252 2 . Basics of Molecular Spin Electronics 255
Contents viii 3. Material Requirements for Molecular Spintronics 258 4. Advantages of Magnetic Polyoxometalates 260 5. Polyoxometalates In Redox-Based Resistive Switching 277 6. Conclusions 282 Acknowledgments 283 References 283 10. Nonaqueous Polyoxometalate Synthesis for Systematic Studies of Hydrolysis, Protonation, and Reduction 287 RJ. Errington 1. Introduction 288 2. Synthesis of Llndqvlst-Type Heterometalates 289 3. Synthesis of Keggln-Type Heterometalates 299 4. Protonolysls of M-OR Bonds and Condensation 303 5. Synthesis and Reactivity of Chlorido {CIMW S } Lindqvist Anions 315 6. Studies of {MW 5 } Lindqvist Anion Protonation 319 7. Ligand Behavior of [(|i-0)(TIW 5 0 18 )2] 6 ~ 324 8. Reductive Transformations 327 9. Summary 332 Acknowledgments 333 References 333 Index 337 Errata: Catalytic Hydrogenation of Carbon Dioxide to Formic Acid 345
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| spelling | Polyoxometalate chemistry edited by Rudi van Eldik, Leroy Cronin First edition Cambridge, MA Elsevier Academic Press 2017 xii, 346 Seiten Illustrationen txt rdacontent n rdamedia nc rdacarrier Advances in inorganic chemistry volume 69 Eldik, Rudi van 1945- (DE-588)124564194 edt Cronin, Leroy edt Advances in inorganic chemistry volume 69 (DE-604)BV005678699 69 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029632319&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Polyoxometalate chemistry Advances in inorganic chemistry |
| title | Polyoxometalate chemistry |
| title_auth | Polyoxometalate chemistry |
| title_exact_search | Polyoxometalate chemistry |
| title_full | Polyoxometalate chemistry edited by Rudi van Eldik, Leroy Cronin |
| title_fullStr | Polyoxometalate chemistry edited by Rudi van Eldik, Leroy Cronin |
| title_full_unstemmed | Polyoxometalate chemistry edited by Rudi van Eldik, Leroy Cronin |
| title_short | Polyoxometalate chemistry |
| title_sort | polyoxometalate chemistry |
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