Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries: Next-Generation High Performance Lithium–Sulfur Batteries
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Singapore
Springer Singapore
2017
|
| Schriftenreihe: | Springer Theses, Recognizing Outstanding Ph.D. Research
|
| Schlagworte: | |
| Online-Zugang: | BTU01 TUM01 Volltext Inhaltsverzeichnis |
| Beschreibung: | 1 Online-Ressource (XX, 115 p. 82 illus) |
| ISBN: | 9789811034060 |
| ISSN: | 2190-5053 |
| DOI: | 10.1007/978-981-10-3406-0 |
Internformat
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| 245 | 1 | 0 | |a Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries |b Next-Generation High Performance Lithium–Sulfur Batteries |c by Guangmin Zhou |
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Datensatz im Suchindex
| _version_ | 1804177344894599168 |
|---|---|
| adam_text | Contents
1 Introduction 1
1 1 Introduction of Lithium-Sulfur Secondary Battery 1
111 Cathode Materials 3
112 Anode Materials 13
113 Separators and Interlayers 15
114 Electrolyte 16
1 2 Motivations of the Thesis 18
References 19
2 Revealing Localized Electrochemical Transition of Sulfur
in Sub-nanometer Confinement 23
2 1 Research Background 23
2 2 Design, Fabrication, and Characterization of Carbon-Sulfur
Composite Cathode 25
221 Synthesis of Hierarchical Porous Carbon (HPC) 25
222 Synthesis of Carbon-Sulfur Composite 26
223 Structure Characterization of the Carbon-Sulfur
Composite 26
224 Electrochemical Performance of the Carbon-Sulfur
Composite Cathode 29
2 3 Mechanism Analysis of the Pore Size Dependence of
Confinement on Electrochemical Performance in Li-S
Batteries 32
2 4 Conclusion 35
References 35
3 Flexible Nanostructured Sulfur-Carbon Nanotube Cathode
with High-Rate Performance for Li-S Batteries 39
3 1 Research Background 39
3 2 Design and Fabrication of Flexible Nanostructured S-CNT
Cathode 41
xiii
XXV
Contents
321 Synthesis of S-Containing Anodic Aluminum
Oxide (AAO) Template 41
322 Synthesis of S-CNTs Composites 41
323 Synthesis of CNTs 42
324 Fabrication of Flexible S-CNT Membranes 42
3 3 Sulfur Formation Mechanism 42
3 4 Characterization of S-CNTs 43
3 5 Control of the Sulfur Content in the S-CNTs 45
3 6 First-Principles Calculations of the Sulfur Molecules
Diffusion Within the Micropores 46
3 7 Synthesis, Structure, and Performance of Flexible S-CNT
Electrode 46
3 8 Electrochemical Performance of Flexible Nanostructured
S-CNT Cathode 48
3 9 Fabrication of Flexible Silicon/Graphene Anode
and Assembly of Flexible Li-S Full Battery Prototype 50
391 Fabrication of Flexible Silicon/Graphene Composite
Film 50
392 Fabrication of Flexible Prelithiated Silicon/Graphene
Composite Film 51
393 Assembly of Flexible Li-S Full Battery Prototype 52
3 10 Conclusion 53
References 53
4 Fibrous Hybrid of Graphene and Sulfur Nanocrystals
for High-Performance Lithium-Sulfur Batteries 57
4 1 Research Background 57
4 2 Material Fabrication and Structure 58
421 Synthesis of GO 58
422 Synthesis of Intercalation Exfoliated Graphene 59
423 Synthesis of the Thermal Exfoliated-Reduced
Graphene 59
424 Preparation of G-S Hybrids 59
425 Preparation of G-S Hybrids (Powder) 59
426 Preparation of G-Smix 59
427 Structure Characterization of the Composites 60
4 3 Interaction Mechanism Between Oxygen-Containing Groups
and Sulfur/Polysulfides 65
4 4 Properties of Sulfur Nanocrystal/Graphene Composites 67
441 Electrical Property and Mechanical Flexibility 67
442 Electrochemical Performance 68
4 5 Conclusion 72
References 72
Contents
xv
5 Graphene-Pure Sulfur Sandwich Structure for Ultrafast,
Long-Life Lithium-Sulfur Batteries 75
5 1 Research Background 75
5 2 Construction of Sandwich Cathode Structure 77
521 GCC Fabrication 77
522 Fabrication of Sulfur-Coated GCC Electrodes 77
523 G-Separator Fabrication 77
5 3 Structure Characterization of the Sandwich Cathode
Structure 78
531 Structure Characterization of the Graphene Powder 78
532 Structure Feature of the GCC 78
533 Structure Characterization of the GCC/S Cathode 80
534 Structure Characterization of the G-Separator 82
5 4 Electrochemical Performance of the Sandwich Cathode
Structure 83
5 5 Interaction Between Graphene and Sulfur Species
in Sandwich Cathode Structure 88
551 Function as a Current Collector 88
552 Function as a Separator Coating Layer 89
5 6 Conclusion 92
References 93
6 A Graphene Foam Electrode with High Sulfur Loading
for Flexible and High-Energy Li-S Batteries 95
6 1 Research Background 95
6 2 Fabrication and Characterization of the 3D GF-Based
Electrode 96
621 Preparation of PDMS/GF 96
622 Preparation of S-PDMS/GF Electrode 96
623 Structure Characterization of the S-PDMS/GF
Electrode 97
6 3 Mechanical Properties of the 3D GF-Based Electrode 100
6 4 Electrochemical Performance of the 3D GF-Based Sulfur
Electrode 101
6 5 Areal Capacity of the 3D GF-Based Sulfur Electrode 105
6 6 Conclusion 109
References 110
7 Conclusions and Perspective 113
7 1 Main Conclusion and Innovations 113
|
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| id | DE-604.BV044206384 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T07:46:36Z |
| institution | BVB |
| isbn | 9789811034060 |
| issn | 2190-5053 |
| language | English |
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| spelling | Zhou, Guangmin Verfasser aut Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries Next-Generation High Performance Lithium–Sulfur Batteries by Guangmin Zhou Singapore Springer Singapore 2017 1 Online-Ressource (XX, 115 p. 82 illus) txt rdacontent c rdamedia cr rdacarrier Springer Theses, Recognizing Outstanding Ph.D. Research 2190-5053 Chemistry Energy storage Electrochemistry Nanotechnology Energy Storage Nanotechnology and Microengineering Chemie Erscheint auch als Druck-Ausgabe 9789811034053 https://doi.org/10.1007/978-981-10-3406-0 Verlag Volltext HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029612778&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Zhou, Guangmin Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries Next-Generation High Performance Lithium–Sulfur Batteries Chemistry Energy storage Electrochemistry Nanotechnology Energy Storage Nanotechnology and Microengineering Chemie |
| title | Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries Next-Generation High Performance Lithium–Sulfur Batteries |
| title_auth | Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries Next-Generation High Performance Lithium–Sulfur Batteries |
| title_exact_search | Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries Next-Generation High Performance Lithium–Sulfur Batteries |
| title_full | Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries Next-Generation High Performance Lithium–Sulfur Batteries by Guangmin Zhou |
| title_fullStr | Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries Next-Generation High Performance Lithium–Sulfur Batteries by Guangmin Zhou |
| title_full_unstemmed | Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries Next-Generation High Performance Lithium–Sulfur Batteries by Guangmin Zhou |
| title_short | Design, Fabrication and Electrochemical Performance of Nanostructured Carbon Based Materials for High-Energy Lithium–Sulfur Batteries |
| title_sort | design fabrication and electrochemical performance of nanostructured carbon based materials for high energy lithium sulfur batteries next generation high performance lithium sulfur batteries |
| title_sub | Next-Generation High Performance Lithium–Sulfur Batteries |
| topic | Chemistry Energy storage Electrochemistry Nanotechnology Energy Storage Nanotechnology and Microengineering Chemie |
| topic_facet | Chemistry Energy storage Electrochemistry Nanotechnology Energy Storage Nanotechnology and Microengineering Chemie |
| url | https://doi.org/10.1007/978-981-10-3406-0 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029612778&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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