Engineering thermodynamics: with worked examples
Gespeichert in:
1. Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
New Jersey
World Scientific
[2017]
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Ausgabe: | Second edition |
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis Klappentext |
Beschreibung: | xvii, 726 Seiten Illustrationen, Diagramme |
ISBN: | 9789813148079 9789813148086 |
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Datensatz im Suchindex
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adam_text | Contents
Preface v
Chapter 1
Thermodynamic Systems and Properties 1
1.1 Thermodynamics 1
1.2 Systems and Surroundings 1
1.2.1 Closed-system or control-mass 2
1.2.2 Open-system or control-volume 2
1.2.3 Isolated system 2
1.3 Properties of a System 2
1.3.1 Intensive properties 3
1.3.2 Extensive properties 3
1.4 State of a System 3
1.5 Some Basic Properties of Systems 3
1.5.1 Pressure 3
1.5.2 Temperature 5
1.5.3 Temperature scales 7
1.5.4 Density and specific volume 9
1.6 Macroscopic and Microscopic View Points 9
1.7 Thermodynamic Equilibrium 10
1.7.1 Quasi-equilibrium and non-equilibrium processes 10
1.8 Temperature Measurement and the Zeroth-Law 13
1.8.1 The Zeroth-law of thermodynamics 14
1.9 Worked Examples 14
Problems 38
References 41
ix
X
Contents
Chapter 2
Properties of a Pure Substance 43
2.1 The Pure Substance 43
2.2 Phase Equilibrium in a Pure Substance 44
2.3 Phase Diagrams 46
2.4 Independent Properties 49
2.5 Tables and Charts of Property Data: Equation of State 49
2.6 Ideal-Gas Equation of State 51
2.7 Microscopic View Point 52
2.8 Gas Laws 53
2.9 Van der Waals Equation of State 53
2.10 Worked Examples 54
Problems 83
References 85
Chapter 3
Work and Heat Interactions 87
3.1 Concept of Work in Mechanics 87
3.2 Work Interactions in Thermodynamics 89
3.2.1 Criterion for a work interaction 89
3.3 Work Done at a Moving Boundary 90
3.3.1 Pressure-volume diagram 92
3.3.2 Path dependence of work done 93
3.4 Work Done in Extending a Solid Rod 94
3.5 Work Done in Stretching a Liquid Surface 94
3.6 Systems Involving Electrical Work 95
3.7 Systems Involving Magnetic Work 96
3.8 Heat Interactions 96
3.9 Comparison of Heat and Work 97
3.10 Worked Examples 97
Problems 125
References 128
Chapter 4
The First Law of Thermodynamics 129
4.1 First Law for a Cyclic Process 129
Contents xi
4.2 First Law for a Change of State 131
4.2.1 An uncoupled-system 133
4.2.2 A coupled-system 135
4.3 Internal Energy — A Thermodynamic Property 136
4.4 State Postulate 138
4.5 Internal Energy and Heat Capacities 138
4.5.1 Heat capacity at constant volume 139
4.5.2 Enthalpy 140
4.5.3 Heat capacity at constant pressure 140
4.6 Properties of Ideal Gases 141
4.6.1 Internal energy, enthalpy and heat capacities
of an ideal gas 142
4.6.2 Heat capacities and kinetic theory 143
4.7 Temperature Dependence of Heat Capacity 146
4.8 Internal Energy and Enthalpy of a Pure Substance 146
4.9 Worked Examples 148
Problems 185
References 189
Chapter 5
First Law Analysis of Open Systems 190
5.1 Open Systems: An Example 190
5.2 General Form of the First Law for Control Volumes 191
5.3 Mass Conservation Law for Control Volumes 195
5.4 Steady-Flow Energy Equation (SFEE) 196
5.5 Fluid Mass Flow Rate in a Duct 197
5.6 Some Steady-Flow Devices 197
5.6.1 Nozzles and diffusers 198
5.6.2 Turbines and compressors 199
5.6.3 Mixing chambers and heat exchangers 200
5.7 Analysis of a Transient Filling Process 202
5.8 Worked Examples 204
Problems 238
References 240
XII
Contents
Chapter 6
The Second Law of Thermodynamics 241
6.1 The Heat Engine Cycle 241
6.1.1 Efficiency of a heat engine cycle 245
6.2 The Reversed Heat Engine Cycle 245
6.2.1 Coefficient of performance of a reversed
heat engine cycle 247
6.3 The Second Law of Thermodynamics 249
6.3.1 Equivalence of the Kelvin-Planck and
Clausius statements 250
6.4 Reversible and Irreversible Processes 251
6.4.1 Types of irreversible processes 254
6.4.2 Reversible heat engines and thermal reservoirs 255
6.5 Some Consequences of the Second Law 255
6.5.1 Efficiency of a Camot cycle using an ideal gas 258
6.5.2 Thermodynamic temperature scale 260
6.5.3 Cycles interacting with a single thermal reservoir 263
6.5.4 Cycles interacting with two thermal reservoirs 265
6.5.5 Cycles interacting with any number of
thermal reservoirs 266
6.6 Worked Examples 269
Problems 297
References 300
Chapter 7
Entropy 301
7.1 The Clausius Inequality and Entropy 301
7.1.1 Entropy --- A thermodynamic property 302
7.1.2 The temperature-entropy diagram 304
7.1.3 The ‘T-ds’ equation 306
7.1.4 Entropy of an ideal gas 306
7.1.5 Entropy of a pure thermal system 307
7.1.6 Entropy of a pure substance 308
7.2 Principle of Increase of Entropy 309
7.2.1 Storage, production and transfer of entropy 311
7.2.2 Entropy transfer in a heat engine 314
Contents
xiii
7.2.3 Entropy transfer in steady heat conduction 316
7.3 Limitations Imposed on Work Output by the Second Law 317
7.3.1 Helmholtz and Gibbs free energy 318
7.3.2 Availability 320
7.4 Maximum Work, Irreversibility and Entropy Production 322
7.5 Entropy, Irreversibility and Natural Processes 324
7.6 Worked Examples 326
Problems 358
References 362
Chapter 8
Second Law Analysis of Open Systems 363
8.1 The Entropy Balance Equation 363
8.2 The Combined First and Second Laws 367
8.2.1 Availability or exergy 371
8.2.2 First law and second law efficiency 373
8.3 Worked Examples 374
Problems 408
References 410
Chapter 9
Vapor Power Cycles 411
9.1 The Carnot Cycle Using a Vapor 411
9.2 The Rankine Cycle 413
9.2.1 Temperature-entropy and enthalpy-entropy
diagrams 415
9.2.2 Analysis of the Rankine cycle 417
9.3 The Reheat Cycle 418
9.3.1 Analysis of the reheat cycle 420
9.4 The Regenerative Power Cycle 421
9.4.1 Analysis of the regenerative cycle with
open-feed-heaters 423
9.4.2 Closed-feed-heaters 424
9.5 The Choice of Working Fluid 425
9.5.1 Binary vapor cycle 426
9.5.2 Analysis of the binary vapor cycle 427
XIV
Contents
9.5.3 Supercritical vapor power cycle 428
9.6 Combined-Heat and Power (CHP) Cycles 429
9.7 Deviations Between Actual and Ideal Cycles 430
9.8 Simplified Second Law Analysis of Power Cycles 432
9.9 Worked Examples 434
Problems 471
References 475
Chapter 10
Gas Power Cycles 476
10.1 Internal-Combustion Engine Cycles 476
10.1.1 Spark-ignition (SI) engines 476
10.1.2 Compression-ignition (Cl) engines 478
10.2 Air Standard Cycles 479
10.2.1 Analysis of the Otto cycle 480
10.2.2 Analysis of the Diesel cycle 482
10.2.3 The dual cycle 484
10.3 Gas Turbine Engine Cycles 485
10.3.1 Analysis of the Brayton cycle 486
10.3.2 Gas turbine cycle with regeneration 489
10.3.3 Analysis of the ideal regenerative cycle 491
10.4 Gas Turbine Cycles with Intercooling and Reheating 492
10.4.1 Staged-compression with intercooling 493
10.4.2 Multi-staged expansion with reheating 495
10.4.3 The Ericsson cycle 496
10.5 Air-Standard Cycle for Jet Propulsion 497
10.6 Idealizations in Air-Standard Cycles 498
10.7 Worked Examples 500
Problems 526
References 529
Chapter 11
Refrigeration Cycles 530
11.1 The Reversed-Camot Cycle Using a Vapor 530
11.2 The Vapor Compression Cycle 533
Contents
XV
11.2.1 Analysis of the vapor compression cycle 536
11.2.2 Actual vapor compression cycle 537
11.3 Modifications to the Vapor Compression Cycle 539
11.3.1 Two-stage compression with flash inter-cooling 539
11.3.2 Two-stage compression with two evaporators 540
11.4 Refrigerants for Vapor Compression Systems 541
11.5 The Vapor Absorption Cycle 543
11.5.1 The three-heat-reservoir-model 544
11.5.2 Analysis of the actual absorption cycle 545
11.5.3 Equilibrium of water-LiBr mixtures 546
11.6 The Air-Standard Refrigeration Cycle 547
11.6.1 The air-standard refrigeration cycle with a
heat exchanger 548
11.7 Worked Examples 549
Problems 573
References 576
Chapter 12
Gas and Gas-Vapor Mixtures 577
12.1 Mixtures of Gases 577
12.1.1 Mass-fraction and mole-fraction 578
12.1.2 Partial pressure and partial volume 579
12.1.3 Dalton’s rule for ideal gas mixtures 580
12.1.4 Amagat-Leduc rule for ideal gas mixtures 581
12.1.5 Properties of ideal gas mixtures 581
12.1.6 Real gas mixtures 583
12.2 Mixtures of Ideal Gases and Vapors 584
12.2.1 Mixtures of air and water vapor 585
12.2.2 Relative humidity and humidity ratio 587
12.2.3 The psychrometrie chart 588
12.2.4 Adiabatic saturation and wet-bulb temperature 591
12.3 Processes of Air-Vapor Mixtures 595
12.3.1 Cooling, dehumidification and heating 595
12.3.2 Evaporative cooling 597
12.3.3 Cooling towers 599
XVI
Contents
12.4 Worked Examples 601
Problems 627
References 630
Chapter 13
Reactive Mixtures 631
13.1 Chemical Reactions of Fuels 631
13.1.1 Mass balance for a combustion reaction 632
13.2 Energy Balance for a Combustion Process 634
13.2.1 Enthalpy and internal energy of formation 63 5
13.2.2 Internal energy and enthalpy of reactants
and products 637
13.2.3 Heats of reaction and heating values 639
13.2.4 Adiabatic flame temperature 640
13.3 Second Law Analysis of Combustion Processes 640
13.4 Chemical Equilibrium 642
13.4.1 Reactions in ideal-gas mixtures 644
13.4.2 Dissociation 646
13.5 Worked Examples 647
Problems 674
References 676
Chapter 14
Thermodynamic Property Relations 677
14.1 Some Mathematical Relations 678
14.2 The Maxwell Relations 679
14.3 Clapeyron Equation 681
14.4 Thermodynamics Relations Involving Internal Energy,
Enthalpy, Entropy and Specific Heat Capacities 682
14.4.1 Expression for the change in internal energy 682
14.4.2 Expression for the change in enthalpy 683
14.4.3 Expression for the change in entropy 684
14.4.4 Relations involving specific heat capacities 685
14.5 Volume Expansivity, Isothermal Compressibility, and
Adiabatic Compressibility 686
14.6 The Joule-Thomson Coefficient 687
Contents xvii
14.7 Developing Thermodynamic Property Tables 687
14.8 Equations of State for Gases 689
14.9 Worked Examples 691
Problems 698
References 701
Chapter 15
Statistical Interpretation of Entropy 702
15.1 Background 702
15.2 Boltzmann Equation 703
15.3 Model for Thermal Entropy 706
15.4 Model for Configurational Entropy 710
15.5 Summary 713
15.6 Worked Examples 714
Problems 718
References 720
Index
723
Engineering
Thermodynamics
with Worked Examples
Second Edition
The laws of thermodynamics have wide ranging practical
applications in all branches of engineering.
This invaluable textbook covers all the subject matter in a typical
undergraduate course in engineering thermodynamics, and uses
carefully chosen worked examples and problems to expose
students to diverse applications of thermodynamics.
This new edition has been revised and updated to include two new
chapters on thermodynamic property relations, and the statistical
interpretation of entropy. Problems with numerical answers are
included at the end of each chapter. As a guide, instructors can
use the examples and problems in tutorials, quizzes and
examinations.
About the Author---------------------------
Nihal Wijeysundera received his BSc (Mechanical Engineering)
from the University of Ceylon, Sri Lanka and PhD (Nuclear Reactor
Physics) from the University of Birmingham, UK. He taught Mechanical
Engineering at the University of Peradeniya, Sri Lanka, and the National
University of Singapore (NUS). He was a member of the American
Society of Heating, Refrigeration and Air Conditioning Engineers
(ASHRAE) from 1986-2003, and was elected a Fellow of the American
Society of Mechanical Engineers (ASME) in 2002. He is contactable at:
nwijeysundera@gmail.com
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id | DE-604.BV044205720 |
illustrated | Illustrated |
indexdate | 2024-07-10T07:46:34Z |
institution | BVB |
isbn | 9789813148079 9789813148086 |
language | English |
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spelling | Wijeysundera, Nihal E. Verfasser (DE-588)1084611104 aut Engineering thermodynamics with worked examples Nihal E Wijeysundera Second edition New Jersey World Scientific [2017] xvii, 726 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Thermodynamik (DE-588)4059827-5 gnd rswk-swf Lehrbuch (DE-588)4123623-3 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content (DE-588)4144384-6 Beispielsammlung gnd-content (DE-588)4143389-0 Aufgabensammlung gnd-content Lehrbuch (DE-588)4123623-3 s Thermodynamik (DE-588)4059827-5 s 1\p DE-604 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029612119&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029612119&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
spellingShingle | Wijeysundera, Nihal E. Engineering thermodynamics with worked examples Thermodynamik (DE-588)4059827-5 gnd Lehrbuch (DE-588)4123623-3 gnd |
subject_GND | (DE-588)4059827-5 (DE-588)4123623-3 (DE-588)4144384-6 (DE-588)4143389-0 |
title | Engineering thermodynamics with worked examples |
title_auth | Engineering thermodynamics with worked examples |
title_exact_search | Engineering thermodynamics with worked examples |
title_full | Engineering thermodynamics with worked examples Nihal E Wijeysundera |
title_fullStr | Engineering thermodynamics with worked examples Nihal E Wijeysundera |
title_full_unstemmed | Engineering thermodynamics with worked examples Nihal E Wijeysundera |
title_short | Engineering thermodynamics |
title_sort | engineering thermodynamics with worked examples |
title_sub | with worked examples |
topic | Thermodynamik (DE-588)4059827-5 gnd Lehrbuch (DE-588)4123623-3 gnd |
topic_facet | Thermodynamik Lehrbuch Beispielsammlung Aufgabensammlung |
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