Modern Nucleophilic Aromatic Substitution:
This book provides a comprehensive overview of nucleophilic aromatic substitutions, focusing on the mechanistic and synthetic features that govern these reactions. The first chapter presents a detailed mechanistic analysis of the factors determining the feasibility of SNAr substitutions, providing d...
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Somerset
John Wiley & Sons, Incorporated
2013
|
| Ausgabe: | 1st ed |
| Schlagworte: | |
| Zusammenfassung: | This book provides a comprehensive overview of nucleophilic aromatic substitutions, focusing on the mechanistic and synthetic features that govern these reactions. The first chapter presents a detailed mechanistic analysis of the factors determining the feasibility of SNAr substitutions, providing decisive information to predict regioselectivity of many reactions and to define the conditions for concerted SNAr processes. Reflecting the key role played by these species as intermediates in most SNAr reactions, chapter 2 then discusses the chemistry of anionic sigma-complexes. Chapter 3 describes the concept of superelectrophilicity in SNAr substitutions, as it has recently emerged from the reactivity of strongly electron-deficient aromatic and heteroaromatic structures. The numerous synthetic applications are considered in depth in the chapters 4 and 5 that follow on intermolecular and intramolecular nucleophilic aromatic substitutions. Then, chapter 6 focuses on substitutions proceeding formally through displacement of a hydride ion, a hot topic in the field. The final chapter brings together concise yet comprehensive discussions surrounding SNAr photosubstitutions, radical substitutions, and ANRORC substitutions. Authored by a highly respected chemist who has contributed greatly to the field over the past two decades, this is a valuable information source for all organic chemists working in academia or the pharmaceutical and agrochemical industries |
| Beschreibung: | Description based on publisher supplied metadata and other sources |
| Beschreibung: | 1 online resource (528 pages) |
| ISBN: | 9783527656165 9783527318612 |
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| 500 | |a Description based on publisher supplied metadata and other sources | ||
| 520 | |a This book provides a comprehensive overview of nucleophilic aromatic substitutions, focusing on the mechanistic and synthetic features that govern these reactions. The first chapter presents a detailed mechanistic analysis of the factors determining the feasibility of SNAr substitutions, providing decisive information to predict regioselectivity of many reactions and to define the conditions for concerted SNAr processes. Reflecting the key role played by these species as intermediates in most SNAr reactions, chapter 2 then discusses the chemistry of anionic sigma-complexes. Chapter 3 describes the concept of superelectrophilicity in SNAr substitutions, as it has recently emerged from the reactivity of strongly electron-deficient aromatic and heteroaromatic structures. The numerous synthetic applications are considered in depth in the chapters 4 and 5 that follow on intermolecular and intramolecular nucleophilic aromatic substitutions. Then, chapter 6 focuses on substitutions proceeding formally through displacement of a hydride ion, a hot topic in the field. The final chapter brings together concise yet comprehensive discussions surrounding SNAr photosubstitutions, radical substitutions, and ANRORC substitutions. Authored by a highly respected chemist who has contributed greatly to the field over the past two decades, this is a valuable information source for all organic chemists working in academia or the pharmaceutical and agrochemical industries | ||
| 650 | 4 | |a Naturwissenschaft | |
| 650 | 4 | |a Aromatic compounds | |
| 650 | 4 | |a Organic compounds -- Synthesis | |
| 650 | 4 | |a Science | |
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Datensatz im Suchindex
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| any_adam_object | |
| author | Terrier, Francois |
| author_facet | Terrier, Francois |
| author_role | aut |
| author_sort | Terrier, Francois |
| author_variant | f t ft |
| building | Verbundindex |
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| dewey-full | 547.6 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.6 |
| dewey-search | 547.6 |
| dewey-sort | 3547.6 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| edition | 1st ed |
| format | Electronic eBook |
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| spelling | Terrier, Francois Verfasser aut Modern Nucleophilic Aromatic Substitution 1st ed Somerset John Wiley & Sons, Incorporated 2013 © 2013 1 online resource (528 pages) txt rdacontent c rdamedia cr rdacarrier Description based on publisher supplied metadata and other sources This book provides a comprehensive overview of nucleophilic aromatic substitutions, focusing on the mechanistic and synthetic features that govern these reactions. The first chapter presents a detailed mechanistic analysis of the factors determining the feasibility of SNAr substitutions, providing decisive information to predict regioselectivity of many reactions and to define the conditions for concerted SNAr processes. Reflecting the key role played by these species as intermediates in most SNAr reactions, chapter 2 then discusses the chemistry of anionic sigma-complexes. Chapter 3 describes the concept of superelectrophilicity in SNAr substitutions, as it has recently emerged from the reactivity of strongly electron-deficient aromatic and heteroaromatic structures. The numerous synthetic applications are considered in depth in the chapters 4 and 5 that follow on intermolecular and intramolecular nucleophilic aromatic substitutions. Then, chapter 6 focuses on substitutions proceeding formally through displacement of a hydride ion, a hot topic in the field. The final chapter brings together concise yet comprehensive discussions surrounding SNAr photosubstitutions, radical substitutions, and ANRORC substitutions. Authored by a highly respected chemist who has contributed greatly to the field over the past two decades, this is a valuable information source for all organic chemists working in academia or the pharmaceutical and agrochemical industries Naturwissenschaft Aromatic compounds Organic compounds -- Synthesis Science Nucleophile Substitution (DE-588)4271538-6 gnd rswk-swf Aromaten (DE-588)4143049-9 gnd rswk-swf 1\p (DE-588)4143413-4 Aufsatzsammlung gnd-content Aromaten (DE-588)4143049-9 s Nucleophile Substitution (DE-588)4271538-6 s 2\p DE-604 Erscheint auch als Druck-Ausgabe Terrier, Francois Modern Nucleophilic Aromatic Substitution 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Terrier, Francois Modern Nucleophilic Aromatic Substitution Naturwissenschaft Aromatic compounds Organic compounds -- Synthesis Science Nucleophile Substitution (DE-588)4271538-6 gnd Aromaten (DE-588)4143049-9 gnd |
| subject_GND | (DE-588)4271538-6 (DE-588)4143049-9 (DE-588)4143413-4 |
| title | Modern Nucleophilic Aromatic Substitution |
| title_auth | Modern Nucleophilic Aromatic Substitution |
| title_exact_search | Modern Nucleophilic Aromatic Substitution |
| title_full | Modern Nucleophilic Aromatic Substitution |
| title_fullStr | Modern Nucleophilic Aromatic Substitution |
| title_full_unstemmed | Modern Nucleophilic Aromatic Substitution |
| title_short | Modern Nucleophilic Aromatic Substitution |
| title_sort | modern nucleophilic aromatic substitution |
| topic | Naturwissenschaft Aromatic compounds Organic compounds -- Synthesis Science Nucleophile Substitution (DE-588)4271538-6 gnd Aromaten (DE-588)4143049-9 gnd |
| topic_facet | Naturwissenschaft Aromatic compounds Organic compounds -- Synthesis Science Nucleophile Substitution Aromaten Aufsatzsammlung |
| work_keys_str_mv | AT terrierfrancois modernnucleophilicaromaticsubstitution |