Half a century of free radical chemistry:
This book describes the experience over 25 years of the senior author with the chemistry of organic free radicals. It begins with a mechanistic study of industrial importance on the pyrolysis of chlorinated alkanes. It continues with a theory on the biosynthesis of phenolate derived alkaloids involv...
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Cambridge
Cambridge University Press
1993
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| Schriftenreihe: | Lezioni lincee
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| Schlagworte: | |
| Online-Zugang: | BSB01 FHN01 Volltext |
| Zusammenfassung: | This book describes the experience over 25 years of the senior author with the chemistry of organic free radicals. It begins with a mechanistic study of industrial importance on the pyrolysis of chlorinated alkanes. It continues with a theory on the biosynthesis of phenolate derived alkaloids involving phenolate radical coupling. There follows 20 years of practical work to prove the theory correct, especially in the case of morphine alkaloids. The book then describes the work on nitrile photolysis (Barton reaction) which involved the invention of new radical chemistry leading to a simple synthesis of the important hormone, aldosterone. There follows a description of the invention of an important new method for the deoxygenation of biologically important molecules, especially sugars and nucleosides, using radical chemistry applied to thiocarbonyl derivatives. Some years later, in a logical extension to carboxylic acids, another new reaction was invented which provides carbon, nitrogen, oxygen and other radicals under mild conditions. A final chapter summarizes recent applications of thiocarbonyl group derived radical reactions by other authors |
| Beschreibung: | Title from publisher's bibliographic system (viewed on 05 Oct 2015) |
| Beschreibung: | 1 online resource (xi, 164 pages) |
| ISBN: | 9780511564383 |
| DOI: | 10.1017/CBO9780511564383 |
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| 520 | |a This book describes the experience over 25 years of the senior author with the chemistry of organic free radicals. It begins with a mechanistic study of industrial importance on the pyrolysis of chlorinated alkanes. It continues with a theory on the biosynthesis of phenolate derived alkaloids involving phenolate radical coupling. There follows 20 years of practical work to prove the theory correct, especially in the case of morphine alkaloids. The book then describes the work on nitrile photolysis (Barton reaction) which involved the invention of new radical chemistry leading to a simple synthesis of the important hormone, aldosterone. There follows a description of the invention of an important new method for the deoxygenation of biologically important molecules, especially sugars and nucleosides, using radical chemistry applied to thiocarbonyl derivatives. Some years later, in a logical extension to carboxylic acids, another new reaction was invented which provides carbon, nitrogen, oxygen and other radicals under mild conditions. A final chapter summarizes recent applications of thiocarbonyl group derived radical reactions by other authors | ||
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Datensatz im Suchindex
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| author | Barton, Derek 1918-1998 |
| author_GND | (DE-588)119068281 |
| author_facet | Barton, Derek 1918-1998 |
| author_role | aut |
| author_sort | Barton, Derek 1918-1998 |
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| building | Verbundindex |
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| classification_rvk | VK 6000 |
| collection | ZDB-20-CBO |
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| dewey-full | 547 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547 |
| dewey-search | 547 |
| dewey-sort | 3547 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| doi_str_mv | 10.1017/CBO9780511564383 |
| format | Electronic eBook |
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| institution | BVB |
| isbn | 9780511564383 |
| language | English |
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| spelling | Barton, Derek 1918-1998 Verfasser (DE-588)119068281 aut Half a century of free radical chemistry Derek H.R. Barton, in collaboration with Shyamal I. Parekh Cambridge Cambridge University Press 1993 1 online resource (xi, 164 pages) txt rdacontent c rdamedia cr rdacarrier Lezioni lincee Title from publisher's bibliographic system (viewed on 05 Oct 2015) This book describes the experience over 25 years of the senior author with the chemistry of organic free radicals. It begins with a mechanistic study of industrial importance on the pyrolysis of chlorinated alkanes. It continues with a theory on the biosynthesis of phenolate derived alkaloids involving phenolate radical coupling. There follows 20 years of practical work to prove the theory correct, especially in the case of morphine alkaloids. The book then describes the work on nitrile photolysis (Barton reaction) which involved the invention of new radical chemistry leading to a simple synthesis of the important hormone, aldosterone. There follows a description of the invention of an important new method for the deoxygenation of biologically important molecules, especially sugars and nucleosides, using radical chemistry applied to thiocarbonyl derivatives. Some years later, in a logical extension to carboxylic acids, another new reaction was invented which provides carbon, nitrogen, oxygen and other radicals under mild conditions. A final chapter summarizes recent applications of thiocarbonyl group derived radical reactions by other authors Free radical reactions Organic compounds / Synthesis Chemische Reaktion (DE-588)4009853-9 gnd rswk-swf Chemie (DE-588)4009816-3 gnd rswk-swf Freies Radikal (DE-588)4137149-5 gnd rswk-swf 1\p (DE-588)4143413-4 Aufsatzsammlung gnd-content Freies Radikal (DE-588)4137149-5 s Chemische Reaktion (DE-588)4009853-9 s DE-604 Chemie (DE-588)4009816-3 s 2\p DE-604 Parekh, Shyamal Ĭ. Sonstige oth Erscheint auch als Druckausgabe 978-0-521-44005-9 Erscheint auch als Druckausgabe 978-0-521-44580-1 https://doi.org/10.1017/CBO9780511564383 Verlag URL des Erstveröffentlichers Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Barton, Derek 1918-1998 Half a century of free radical chemistry Free radical reactions Organic compounds / Synthesis Chemische Reaktion (DE-588)4009853-9 gnd Chemie (DE-588)4009816-3 gnd Freies Radikal (DE-588)4137149-5 gnd |
| subject_GND | (DE-588)4009853-9 (DE-588)4009816-3 (DE-588)4137149-5 (DE-588)4143413-4 |
| title | Half a century of free radical chemistry |
| title_auth | Half a century of free radical chemistry |
| title_exact_search | Half a century of free radical chemistry |
| title_full | Half a century of free radical chemistry Derek H.R. Barton, in collaboration with Shyamal I. Parekh |
| title_fullStr | Half a century of free radical chemistry Derek H.R. Barton, in collaboration with Shyamal I. Parekh |
| title_full_unstemmed | Half a century of free radical chemistry Derek H.R. Barton, in collaboration with Shyamal I. Parekh |
| title_short | Half a century of free radical chemistry |
| title_sort | half a century of free radical chemistry |
| topic | Free radical reactions Organic compounds / Synthesis Chemische Reaktion (DE-588)4009853-9 gnd Chemie (DE-588)4009816-3 gnd Freies Radikal (DE-588)4137149-5 gnd |
| topic_facet | Free radical reactions Organic compounds / Synthesis Chemische Reaktion Chemie Freies Radikal Aufsatzsammlung |
| url | https://doi.org/10.1017/CBO9780511564383 |
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