Photodissociation dynamics: spectroscopy and fragmentation of small polyatomic molecules
Photodissociation induced by the absorption of single photons permits the detailed study of molecular dynamics such as the breaking of bonds, internal energy transfer and radiationless transitions. The availability of powerful lasers operating over a wide frequency range has stimulated rapid develop...
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Cambridge
Cambridge University Press
1993
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| Schriftenreihe: | Cambridge monographs on atomic, molecular, and chemical physics
1 |
| Schlagworte: | |
| Online-Zugang: | BSB01 FHN01 Volltext |
| Zusammenfassung: | Photodissociation induced by the absorption of single photons permits the detailed study of molecular dynamics such as the breaking of bonds, internal energy transfer and radiationless transitions. The availability of powerful lasers operating over a wide frequency range has stimulated rapid development of new experimental techniques which make it possible to analyse photodissociation processes in unprecedented detail. This text elucidates the achievements in calculating photodissociation cross-sections and fragment state distributions from first principles, starting from multi-dimensional potential energy surfaces and the Schrödinger equation of nuclear motion. Following an extended introduction in which the various types of observables are outlined, the book summarises the basic theoretical tools, namely the time-independent and the time-dependent quantum mechanical approaches as well as the classical picture of photodissociation. The discussions of absorption spectra, diffuse vibrational structures, the vibrational and rotational state distributions of the photofragments form the core of the book. More specific topics such as the dissociation of vibrationally excited molecules, emission during dissociation, or nonadiabatic effects are also discussed. It will be of interest to graduate students and senior scientists working in molecular physics, spectroscopy, molecular collisions and molecular kinetics |
| Beschreibung: | Title from publisher's bibliographic system (viewed on 05 Oct 2015) |
| Beschreibung: | 1 online resource (xv, 417 pages) |
| ISBN: | 9780511586453 |
| DOI: | 10.1017/CBO9780511586453 |
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| 520 | |a Photodissociation induced by the absorption of single photons permits the detailed study of molecular dynamics such as the breaking of bonds, internal energy transfer and radiationless transitions. The availability of powerful lasers operating over a wide frequency range has stimulated rapid development of new experimental techniques which make it possible to analyse photodissociation processes in unprecedented detail. This text elucidates the achievements in calculating photodissociation cross-sections and fragment state distributions from first principles, starting from multi-dimensional potential energy surfaces and the Schrödinger equation of nuclear motion. Following an extended introduction in which the various types of observables are outlined, the book summarises the basic theoretical tools, namely the time-independent and the time-dependent quantum mechanical approaches as well as the classical picture of photodissociation. The discussions of absorption spectra, diffuse vibrational structures, the vibrational and rotational state distributions of the photofragments form the core of the book. More specific topics such as the dissociation of vibrationally excited molecules, emission during dissociation, or nonadiabatic effects are also discussed. It will be of interest to graduate students and senior scientists working in molecular physics, spectroscopy, molecular collisions and molecular kinetics | ||
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Datensatz im Suchindex
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| dewey-ones | 541 - Physical chemistry |
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| discipline | Chemie / Pharmazie Physik |
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| illustrated | Not Illustrated |
| indexdate | 2024-07-10T07:39:16Z |
| institution | BVB |
| isbn | 9780511586453 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-029350883 |
| oclc_num | 849795326 |
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| owner_facet | DE-12 DE-92 |
| physical | 1 online resource (xv, 417 pages) |
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| publishDate | 1993 |
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| publisher | Cambridge University Press |
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| series2 | Cambridge monographs on atomic, molecular, and chemical physics |
| spelling | Schinke, Reinhard Verfasser aut Photodissociation dynamics spectroscopy and fragmentation of small polyatomic molecules Reinhard Schinke Cambridge Cambridge University Press 1993 1 online resource (xv, 417 pages) txt rdacontent c rdamedia cr rdacarrier Cambridge monographs on atomic, molecular, and chemical physics 1 Title from publisher's bibliographic system (viewed on 05 Oct 2015) Photodissociation induced by the absorption of single photons permits the detailed study of molecular dynamics such as the breaking of bonds, internal energy transfer and radiationless transitions. The availability of powerful lasers operating over a wide frequency range has stimulated rapid development of new experimental techniques which make it possible to analyse photodissociation processes in unprecedented detail. This text elucidates the achievements in calculating photodissociation cross-sections and fragment state distributions from first principles, starting from multi-dimensional potential energy surfaces and the Schrödinger equation of nuclear motion. Following an extended introduction in which the various types of observables are outlined, the book summarises the basic theoretical tools, namely the time-independent and the time-dependent quantum mechanical approaches as well as the classical picture of photodissociation. The discussions of absorption spectra, diffuse vibrational structures, the vibrational and rotational state distributions of the photofragments form the core of the book. More specific topics such as the dissociation of vibrationally excited molecules, emission during dissociation, or nonadiabatic effects are also discussed. It will be of interest to graduate students and senior scientists working in molecular physics, spectroscopy, molecular collisions and molecular kinetics Photodissociation Molecular dynamics Molekulardynamik (DE-588)4170370-4 gnd rswk-swf Photodissoziation (DE-588)4131114-0 gnd rswk-swf Photodissoziation (DE-588)4131114-0 s Molekulardynamik (DE-588)4170370-4 s 1\p DE-604 Erscheint auch als Druckausgabe 978-0-521-38368-4 Erscheint auch als Druckausgabe 978-0-521-48414-5 https://doi.org/10.1017/CBO9780511586453 Verlag URL des Erstveröffentlichers Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Schinke, Reinhard Photodissociation dynamics spectroscopy and fragmentation of small polyatomic molecules Photodissociation Molecular dynamics Molekulardynamik (DE-588)4170370-4 gnd Photodissoziation (DE-588)4131114-0 gnd |
| subject_GND | (DE-588)4170370-4 (DE-588)4131114-0 |
| title | Photodissociation dynamics spectroscopy and fragmentation of small polyatomic molecules |
| title_auth | Photodissociation dynamics spectroscopy and fragmentation of small polyatomic molecules |
| title_exact_search | Photodissociation dynamics spectroscopy and fragmentation of small polyatomic molecules |
| title_full | Photodissociation dynamics spectroscopy and fragmentation of small polyatomic molecules Reinhard Schinke |
| title_fullStr | Photodissociation dynamics spectroscopy and fragmentation of small polyatomic molecules Reinhard Schinke |
| title_full_unstemmed | Photodissociation dynamics spectroscopy and fragmentation of small polyatomic molecules Reinhard Schinke |
| title_short | Photodissociation dynamics |
| title_sort | photodissociation dynamics spectroscopy and fragmentation of small polyatomic molecules |
| title_sub | spectroscopy and fragmentation of small polyatomic molecules |
| topic | Photodissociation Molecular dynamics Molekulardynamik (DE-588)4170370-4 gnd Photodissoziation (DE-588)4131114-0 gnd |
| topic_facet | Photodissociation Molecular dynamics Molekulardynamik Photodissoziation |
| url | https://doi.org/10.1017/CBO9780511586453 |
| work_keys_str_mv | AT schinkereinhard photodissociationdynamicsspectroscopyandfragmentationofsmallpolyatomicmolecules |