Photochromic materials: preparation, properties and applications
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| Format: | Buch |
| Sprache: | English |
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Weinheim
Wiley-VCH Verlag GmbH Co. KGaA
[2016]
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| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIV, 421 Seiten Illustrationen, Diagramme |
| ISBN: | 9783527337798 9783527683734 |
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| 245 | 1 | 0 | |a Photochromic materials |b preparation, properties and applications |c edited by He Tian and Junji Zhang |
| 264 | 1 | |a Weinheim |b Wiley-VCH Verlag GmbH Co. KGaA |c [2016] | |
| 264 | 4 | |c © 2016 | |
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Datensatz im Suchindex
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|---|---|
| adam_text | CONTENTS
LIST OF CONTRIBUTORS XI
1 INTRODUCTION: ORGANIC PHOTOCHROMIE MOLECULES 1
KEITARO NAKATAN%, JONATHAN PIARD, PE
**
YU, AND REMI *
*
AET VIER
1.1 PHOTOCHROMIE SYSTEMS 1
1.1.1 GENERAL INTRODUCTION 1
1.1.2 BASIC PRINCIPLES 4
1.1.3 PHOTOCHROMIE * LECU LES: SOME HISTORY 5
1.2 ORGANIC PHOTOCHROMIE MOLECULES MAIN FAMILIES 8
1.2.1 PROTON TRANSFER 9
1.2.2 TRANS-CISPHOTDSOM ERIZATION 12
1.2.3 HOMOLYTIC CLEAVAGE 13
1.2.4 CYCLIZATION REACTION 14
1.2.4.1 SPIROPYRANS, SPIROOXAZINES
*
AND CHROMENES 14
1.2.4.2 FULGIDES AND FULGIMIDES 17
1.2.4.3 DIARYLETHENES 18
1.3 MOLECULAR DESIGN TO IMPROVE THE PERFORMANCE 20
1.3.1 FIGURES OF MERIT 20
1.3.2 FATIGUE RESISTANCE: INCREASING THE NUMBER OF OPERATING CYCLES 21
1.3.3 BISTABILITY: AVOIDING UNWANTED D E RM A L BACK-REACTION IN THE
DARK 23
1.3.3.1 INFLUENCE OF ETHENIC BRIDGE ON THE D E RM A L STABILITY OF THE B
FORM 24
1.3.3.2 IMPACT OF THE HETEROARYL SUBSTITUENTS ON THE D E RM A L
STABILITY OF THE
B FORM 24
1.3.4 FAST PHOTOCHROMIE SYSTEMS: REVERTING BACK SPONTANEOUSLY TO THE
COLORLESS STATE IN A GLANCE 25
1.3.5 GAINING EFFICIENCY OF THE PHOTOREACTION: THE EXAMPLE OF
DIARYLETHENES 26
CONCLUSION 31
IRRADIATION AT A SPECIFIC WAVELENGTH: ISOSBESTIC POINT 32
14
PHOTOSWITCHABLE SUPRAMOLECULAR SYSTEMS 109
GUANGLEI LV, LIANG CHEN, HAICHUANG LAN. ANDTAOYI
INTRODUCTION 109
PHOTOREVERSIBLE AMPHIPHILIC SYSTEMS 110
PHOTOREVERSIBLE DIARYLETHENE-BASED AMPHIPHILIC SYSTEM 110
PHOTOREVERSIBLE AZOBENZENE-BASED AMPHIPHILIC SYSTEM 110
PHOTOREVERSIBLE SPIROPYRAN-BASED AMPHIPHILIC SYSTEM 119
PHOTOSWITCHABLEHOST-GUEST SYSTEMS 122
PHOTOCONTROLLED SUPRAMOLECULAR SELF-ASSEMBLY 123
CASE A: WHEN THE D E RM A L BACK-REACTION IS NEGLIGIBLE COMPARED TO
THE PHOTOCHEMICAL REACTION (TYPICALLY P*TYPE) 33
CASE B: WHEN THE D E RM A L BACK*REACTION IS MORE EFFICIENT THAN THE
PHOTOCHEMICALB4HA REACTION (TYPICALLY TYPE) 34
REFERENCES 34
2 PHOTOCHROMIE TRANSITIONAL METAL COMPLEXES FOR
PHOTOSENSITIZATION 47
CH -CH
*
KO AND VIVIAN WING-WAH YAM
2.1 INTRODUCTION 47
2.2 PHOTOSENSITIZATION OF STILBENE- AND AZO-CONTAINING LIGANDS 48
2.3 PHOTOSENSITIZATION OF SPIROOXAZINE-CONTAINING LIGANDS SI
2.4 PHOTOSENSITIZATION OF DIARYLETHENE-CONTAINING LIGANDS 54
2.5 PHOTOSENSITIZATION OF PHOTOCHROMIE NAC*CHELATE
ORGANOBORANES 63
2.6 CONCLUSION 65
REFERENCES 66
3 MULTI-ADDRESSABLE PHOTOCHROMIES 71
SHANGJURI CHEN, WENLONG LI/ AND WEIHONGZHU
3.1 * LE C U LA R LOGIC GATES 71
3.1.1 TWO-INPUT LOGIC GATES 71
3.1.2 COMBINATORIAL LOGIC SYSTEMS 74
3.1.2.1 HALF-ADDER AND HALF-SUBTRACTOR 74
3.1.2.2 KEYPAD LOCKS 77
3.1.2.3 DIGITAL ENCODER AND DECODER 82
3.2 DATA STORAGE AND MOLECULAR MEMORY 84
3.2.1 FLUORESCENCE SPECTROSCOPY 85
3.2.2 INFRARED SPECTROSCOPY 90
3.2.3 OPTICAL ROTATION 92
3.3 GATED PHOTOCHROMORES 95
3.3.1 HYDROGEN BONDING 95
3.3.2 COORDINATION 98
3.3.3 CHEMICAL REACTION 99
REFERENCES 105
1
2
3
H
1
2
2
2
2
3
3
4
4
4
4
4
4
4
4
4.3.2
4.3.3
4.3.4
4.4
4.4.1
4.4.2
4.4.3
4.4.4
4.5
4.6
5
5.1
5.2
5.3
5.3.1
5.3.2
5.3.3
5.3.4
5.4
5.4.1
5.4.2
5.5
*
6.1
6
.
1.1
6
.
1.2
6
.
1
.
2.1
6
.
1
.
2.2
6.1.2.3
6.1.2.4
6.2
6
.
2.1
6
.
2
.
1.1
6
.
2
.
1.2
6
.
2.2
6
.
2
.
2.1
PHOTOCONTROLLED CAPTURE AND RELEASE OT GUEST MOLECULES 128
FLUORESCENT SWITCHING PROMOTED BY H OST-GUEST INTERACTION 133
PHOTOSWITCHABLE MOLECULAR DEVICES 137
PHOTOCHROMIE METAL COMPLEXES AND SENSORS 141
METAL COMPLEXES WITH AZOBENZENE GROUPS 141
METAL COMPLEXES WITH DIARYLETHENE GROUPS 144
METAL COMPLEXES WITH SPIROCYCLIC GROUPS ISO
METAL COMPLEXES WITH RHODAMINE 152
OTHER LIGHT-MODULATED SUPRAMOLECULAR INTERACTIONS 153
CONCLUSIONS AND OUTLOOK 159
REFERENCES 159
LIGHT-GATED CHEM*CAL REACTIONS AND CATALYTIC PROCESSES 167
ROBERT GOSTL, ANTTI SENF, AND STEFAN HECHT
INTRODUCTION 167
GENERAL DESIGN CONSIDERATIONS 169
PHOTOSWITCHABLE STOICHIOMETRIC PROCESES 171
STARTING MATERIAL CONTROL 172
PRODUCT CONTROL 175
STARTING MATERIAL AND PRODUCT CONTROL 177
TEMPLATE CONTROL 178
PHOTOSWITCHABLE CATALYTIC PROCESSES 182
ACTIVITY CONTROL 182
SELECTIVITY CONTROL 185
OUTLOOK 187
REFERENCES 190
SURFACE AND INTERFACIAL PHOTOSWITCHES 195
JUNJIZHANG AND HE TIARI
PHOTOCHROMIE SAMS 196
PHOTOCHROMIE ELECTRODE SAMS 196
PHOTOREVERSIBLE FUNCTIONAL SURFACES 198
PHOTOSWITCHABLE SURFACE WETTABILITY 198
PHOTOCONTROLLED CAPTURE-AND-RELEASE SYSTEM 202
SMART PHOTOCHROMIE SURFACE BASED ON SUPRAMOLECULAR
SYSTEMS 203
PHOTOCHROMIE SURFACE FOR MOLECULAR DATA PROCESSING 205
PHOTOREGULATED NANOPARTICLES 206
PHOTOCHROMIE SWITCHES ON TRADITIONAL METAL NANOPARTICLES 208
PHOTOSWITCHING ON THE METAL NANOPARTICLES 208
PHOTOINDUCED REVERSIBLE AGGREGATION OR NANOPARTICLES AND ^ E I R
VERSATILE APPLICATIONS 210
PHOTOCHROMIE SWITCHES ON OTHER NOVEL FUNCTIONAL
NANOPARTICLES 215
PHOTOSWITCHABLE MAGNETIC NANOPARTICLES 215
6
.
2
.
2.2
6.2.2.3
6.2.3
6.2.31
6.2.3.2
6.2.3.3
6 3
6.3.1
6.3.2
7.1
7.1.1
7.2
7.2.1
7.2.2
7.2.3
7.3
7.4
8
8.1
8
.
1.1
8
.
1.2
8.1.3
8.1.4
8.1.5
8
.
1.6
8.2
8
.
2.1
8
.
2.2
8.2.3
8.2.4
PHOTOMANIPULATED QUANTUM DOTS 215
PHOTOCHROMIE WITH UPCONVERSION NANOPARTICLES 218
PHOTOCONTROLLED MESOPOROUS SILICA NANOPARTICLES 220
PHOTO-NANOVALVES 220
PHOTO-NANOIMPELLERS 223
NIR LIGHT-TRIGGERED MSN DRUG DELIVERY AND TE RA P E U TIC
SYSTEMS 224
PHOTOCONTROLLED SURFACE CONDUCTANCE 226
PHOTOCHROMIE CONDUCTANCE SWITCHING BASED ON SAMS 226
PHOTOCHROMIE CONDUCTANCE ON SINGLE-MOLECULE LEVEL 228
REFERENCES 231
HYBRID ORGANIC/PHOTOCHROMIC APPROACHES TO GENERATE
MULTIFUNCTIONAL MATERIALS, INTERFACES,AND DEICES 243
EMANUELE ORGIU AND PAOLO SAMORI
INTRODUCTION 243
TUNING THE CHARGE INJECTION IN ORGANIC-BASED DEVICES BY MEANS OF
PHOTOCHROMIE * LE C U LE S 245
TUNING THE POLARONIC TRANSPORT IN ORGANIC SEMICONDUCTORS BY
MEANS OF PHOTOCHROMIE MOLECULES 251
PHOTOCHROMIE MOLECULES ANA URGANIC SEMICONDUCTORS INCORPORATED
IN DYADS, MULTIADS
*
AND POLYMERS 251
THE MULTILAYER APPROACH 254
THE BLENDING APPROACH 255
PHOTORESPONSIVE DIELECTRIC INTERFACES AND BULK 262
CONCLUSIONS AND FUTURE OUTLOOKS 267
ACKNOWLEDGMENTS 268
REFERENCES 268
PHOTOCHROMIE BULK MATERIALS 281
NAASAKAZU * AOR
**
MOTO, SEIYA KOBATAKE, MASAHIRO LNE, HARI KRISHNA BISOY
***
QUON LI/ SHENG WANG, AND HE TIAN
PHOTOCHROMIE POLYMERS 281
GLASS TRANSITION TEMPERATURE 281
FLUORESCENCE 283
CONDUCTIVITY 287
LIVING RADICAL POLYMERIZATION 288
SURFACE RELIEF GRATING 290
PHOTOMECHANICAL EFFECT *
SINGLE-CRYSTALLINE PHOTOSWITCHES 293
CRYSTALLINE-STATE PHOTOCHROMIE MATERIALS
293
PHOTOCHROMIE DIARYLETHENE SINGLE CRYSTALS 293
IN SITU X-RAY CRYSTALLOGRAPHIC ANALYSIS OF PHOTOISOMERIZATION
REACTION
29S
PHOTOISOMERIZATION QUANTUM YIELDS 296
8.2.5 MULTICOLOR PHOTOCHROMISM OF MULTICOMPONENT CRYSTALS 297
8.2.6 NANOPERIODIC STRUCTURES FABRICATED BY PHOTOCHROMIE
REACTIONS 299
8.2.7 PHOTOINDUCED SHAPE CHANGES AND MECHANICAL PERFORMANCE 301
8.3 PHOTOCHROMIE LIQUID CRYSTALS 305
8.3.1 INTRODUCTION 305
8.3.2 SPIROPYRAN- AND SPIROOXAZINE-BASED PHOTOCHROMIE LIQUID
CRYSTALS 309
8.3.3 DIARYLETHENE-BASED PHOTOCHROMIE LIQUID CRYSTALS 314
8.3.4 AZOBENZENE-BASED PHOTOCHROMIE LIQUID CRYSTALS 320
8.3.5 OTHER PHOTOCHROMIE LIQUID CRYSTALS 327
8.3.6 CONCLUSIONS AND OUTLOOK 328
8.4 PHOTOCHROMIE GELS 329
8.4.1 INTRODUCTION 329
8.4.2 AZOBENZENE GELS 330
8.4.3 SPIROPYRAN AND SPIROOXAZINE GELS 335
8.4.4 DIARYLETHENES GELS 337
8.4.5 NAPHTHOPYRAN GELS 342
8.4.6 OTHER PHOTOCHROMIE GELS 343
8.4.7 CONCLUSION 346
REFERENCES 346
9 PHOTOCHROMIE MATERIALS IN BIOCHEMISTRY 361
DANIELLE WILSON AND NEIL R. BRARTDA
9.1 INTRODUCTION 361
9.2 REVERSIBLE PHOTOCHEMICAL SWITCHING OF BIOMATERIAL FUNCTION 362
9.3 GENERAL DESIGN STRATEGIES AND CONSIDERATIONS 362
9.3.1 PHOTOSWITCHABLE TETHERS 364
9.3.1.1 INCORPORATION METHOD 364
9.3.1.2 CONSIDERATIONS 364
9.3.2 PHOTOSWITCHABLE SMALL MOLECULES 365
9.3.2.1 R EIN CO RP O RARO N METHOD 365
9.3.2.2 CONSIDERATIONS 365
9.3.3 CHROMOPHORE SELECTION 367
9.4 SELECTED EXAMPLES 367
9.4.1 PHOTOSWITCHABLE ENZYMES 367
9.4.1.1 DRUG-INSPIRED SMALL MOLECULE INHIBITORS 367
9.4.1.2 PHOSPHORIBOSYL ISOMERASE INHIBITOR WITH TWO BINDING UNITS 370
9.4.1.3 DIRECT MODIFICATION OF ENZYMES WITH PHOTOCHROMIE GROUPS 372
9.4.2 PHOTOSWITCHABLE PEPTIDES AND PROTEINS 373
9.4.2.1 PEPTIDE CROSS-LINKING 373
9
*
4
*
2.2 CYCLIC ANTIMICROBIAL PEPTIDE 375
9.4.2.3 GENETICALLY ENCODED AMINO ACIDS 376
9.4
*
2
*
4 CONTROL OF MOTOR PROTEIN FUNCTION USING SITE-SELECTIVE
MUTATION 377
9.4.3 PHOTOSWITCHABLE ION CHANNELS ANA RECEPTORS 379
9.4.3.1 PHOTOCONTROL OF CHANNEL ACTIVATION AND DESENSITIZATION WITH A
TETHERED GLUTAMATE 380
9.4.3.2 PHOTOCONTROL OF INSULIN RELEASE USING A SMALL MOLECULAR
SULFONYLUREA 380
9.4.3.3 PHOTOCONTROL OF RECEPTOS USING RED LIGHT 381
9.4.4 PHOTOSWITCHABLE NUCLEOTIDES 382
9.4.4.1 SPIROPYRAN-MODIFIED OLIGONUCLEOTIDE BACKBONES 382
9.4.4.2 CONTROLLING RNA DUPLEX HYBRIDIZATION WITH LIGHT 384
9.4.4.3 DIARYLETHENE-MODIFIEDOLIGONUCLEOTIDES 385
9.5 SUMMARY 386
REFERENCES 386
10 INDUSTRIAL APPLICATIONS AND PERSPECTIVES 393
JUNJI ZHANG AND HETIAN
10.1 INDUSTRIALIZATION AND COMMERCIALIZATION OF ORGANIC PHOTOCHROMIE
MATERIALS .59.5
10.1.1 COMMERCIALIZED T*TYPE PHOTOCHROMIE MATERIALS 395
10.1.2 COMMERCIALIZED *-**** PHOTOCHROMIE MATERIALS 398
10.2 PERSPECTIVES FOR ORGANIC PHOTOCHROMIE MATERIALS 399
REFERENCES 409
* * 417
|
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| indexdate | 2024-07-10T07:33:56Z |
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| publisher | Wiley-VCH Verlag GmbH Co. KGaA |
| record_format | marc |
| spelling | Photochromic materials preparation, properties and applications edited by He Tian and Junji Zhang Weinheim Wiley-VCH Verlag GmbH Co. KGaA [2016] © 2016 XIV, 421 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Fotochrome Verbindungen (DE-588)4174479-2 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Fotochrome Verbindungen (DE-588)4174479-2 s DE-604 Tian, He (DE-588)1111819254 edt Zhang, Junjie (DE-588)1030118523 edt Erscheint auch als Online-Ausgabe, EPUB 978-3-527-68372-7 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-68371-0 Erscheint auch als Online-Ausgabe, PDF 978-3-527-68370-3 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029155970&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Photochromic materials preparation, properties and applications Fotochrome Verbindungen (DE-588)4174479-2 gnd |
| subject_GND | (DE-588)4174479-2 (DE-588)4143413-4 |
| title | Photochromic materials preparation, properties and applications |
| title_auth | Photochromic materials preparation, properties and applications |
| title_exact_search | Photochromic materials preparation, properties and applications |
| title_full | Photochromic materials preparation, properties and applications edited by He Tian and Junji Zhang |
| title_fullStr | Photochromic materials preparation, properties and applications edited by He Tian and Junji Zhang |
| title_full_unstemmed | Photochromic materials preparation, properties and applications edited by He Tian and Junji Zhang |
| title_short | Photochromic materials |
| title_sort | photochromic materials preparation properties and applications |
| title_sub | preparation, properties and applications |
| topic | Fotochrome Verbindungen (DE-588)4174479-2 gnd |
| topic_facet | Fotochrome Verbindungen Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=029155970&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT tianhe photochromicmaterialspreparationpropertiesandapplications AT zhangjunjie photochromicmaterialspreparationpropertiesandapplications |