Introduction to applied colloid and surface chemistry:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Chichester, West Sussex
Wiley
[2016]
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Index Seite 358-367 |
| Beschreibung: | xix, 367 Seiten Illustrationen, Diagramme |
| ISBN: | 9781118881187 |
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| 245 | 1 | 0 | |a Introduction to applied colloid and surface chemistry |c Georgios M. Kontogeorgis and Søren Kiil, Department of Chemical and Biochemical Engineering, Technical University of Denmark, Denmark |
| 264 | 1 | |a Chichester, West Sussex |b Wiley |c [2016] | |
| 300 | |a xix, 367 Seiten |b Illustrationen, Diagramme | ||
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Datensatz im Suchindex
| _version_ | 1804176224220610560 |
|---|---|
| adam_text | Contents
A
Preface xi
Useful Constants xvi
Symbols and Some Basic Abbreviations xvii
About the Companion Web Site xx
1 Introduction to Colloid and Surface Chemistry 1
1.1 What are the colloids and interfaces? Why are they important? Why do we study
them together? 1
1.1.1 Colloids and interfaces 3
1.2 Applications 4
1.3 Three ways of classifying the colloids 5
1.4 How to prepare colloid systems 6
1.5 Key properties of colloids 7
1.6 Concluding remarks 7
Appendix 1.1 8
Problems 9
References 10
2 Intermolecular and Interparticle Forces 11
2.1 Introduction - Why and which forces are of importance in colloid and surface chemistry? 11
2.2 Two important long-range forces between molecules 12
2.3 The van der Waals forces 15
2.3.1 Van der Waals forces between molecules 15
2.3.2 Forces between particles and surfaces 16
2.3.3 Importance of the van der Waals forces 21
2.4 Concluding remarks 25
Appendix 2.1 A note on the uniqueness of the water molecule and some of the recent debates
on water structure and peculiar properties 26
References for the Appendix 2.1 28
Problems 29
References 33
34
34
34
39
39
43
44
45
46
48
50
51
52
57
59
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61
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67
72
74
74
74
74
77
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86
89
90
91
91
93
95
96
96
99
Contents
Surface and Interfacial Tensions - Principles and Estimation Methods
3.1 Introduction
3.2 Concept of surface tension - applications
3.3 Interfacial tensions, work of adhesion and spreading
3.3.1 Interfacial tensions
3.3.2 Work of adhesion and cohesion
3.3.3 Spreading coefficient in liquid-liquid interfaces
3.4 Measurement and estimation methods for surface tensions
3.4.1 The parachor method
3.4.2 Other methods
3.5 Measurement and estimation methods for interfacial tensions
3.5.1 “Direct” theories (Girifalco-Good and Neumann)
3.5.2 Early “surface component” theories (Fowkes, Owens-Wendt, Hansen/Skaarup)
3.5.3 Acid-base theory of van Oss-Good (van Oss et al, 1987) - possibly the best
theory to-date
3.5.4 Discussion
3.6 Summary
Appendix 3.1 Hansen solubility parameters (HSP) for selected solvents
Appendix 3.2 The ‘ty” parameter of the Girifalco-Good equation (Equation 3.16) for
liquid-liquid interfaces. Data from Girifalco and Good (1957, 1960)
Problems
References
Fundamental Equations in Colloid and Surface Science
4.1 Introduction
4.2 The Young equation of contact angle
4.2.1 Contact angle, spreading pressure and work of adhesion for solid-liquid interfaces
4.2.2 Validity of the Young equation
4.2.3 Complexity of solid surfaces and effects on contact angle
4.3 Young-Laplace equation for the pressure difference across a curved surface
4.4 Kelvin equation for the vapour pressure, P, of a droplet (curved surface) over the “ordinary”
vapour pressure Psat for a flat surface
4.4.1 Applications of the Kelvin equation
4.5 The Gibbs adsorption equation
4.6 Applications of the Gibbs equation (adsorption, monolayers, molecular weight of proteins)
4.7 Monolayers
4.8 Conclusions
Appendix 4.1 Derivation of the Young-Laplace equation
Appendix 4.2 Derivation of the Kelvin equation
Appendix 4.3 Derivation of the Gibbs adsorption equation
Problems
References
Surfactants and Self-assembly. Detergents and Cleaning
5.1 Introduction to surfactants - basic properties, self-assembly and critical packing
parameter (CPP)
5.2 Micelles and critical micelle concentration (CMC)
Contents vii
5.3 Micellization - theories and key parameters 106
5.4 Surfactants and cleaning (detergency) 112
5.5 Other applications of surfactants 113
5.6 Concluding remarks 114
Appendix 5.1 Useful relationships from geometry 115
Appendix 5.2 The Hydrophilic-Lipophilic Balance (HLB) 116
Problems 117
References 119
6 Wetting and Adhesion 121
6.1 Introduction 121
6.2 Wetting and adhesion via the Zisman plot and theories for interfacial tensions 122
6.2.1 Zisman plot 122
6.2.2 Combining theories of interfacial tensions with Young equation and work of
adhesion for studying wetting and adhesion 124
6.2.3 Applications of wetting and solid characterization 130
6.3 Adhesion theories 141
6.3.1 Introduction - adhesion theories 141
6.3.2 Adhesive forces 144
6.4 Practical adhesion: forces, work of adhesion, problems and protection 147
6.4.1 Effect of surface phenomena and mechanical properties 147
6.4.2 Practical adhesion - locus of failure 148
6.4.3 Adhesion problems and some solutions 149
6.5 Concluding remarks 154
Problems 155
References 160
7 Adsorption in Colloid and Surface Science - A Universal Concept 161
7.1 Introduction - universality of adsorption - overview 161
7.2 Adsorption theories, two-dimensional equations of state and surface tension-concentration
trends: a clear relationship 161
7.3 Adsorption of gases on solids 162
7.3.1 Adsorption using the Langmuir equation 163
7.3.2 Adsorption of gases on solids using the BET equation 164
7.4 Adsorption from solution 168
7.4.1 Adsorption using the Langmuir equation 168
7.4.2 Adsorption from solution - the effect of solvent and concentration on adsorption 171
7.5 Adsorption of surfactants and polymers 173
7.5.1 Adsorption of surfactants and the role of CPP 173
7.5.2 Adsorption of polymers 174
7.6 Concluding remarks 179
Problems 180
References 184
8 Characterization Methods of Colloids - Part I: Kinetic Properties and Rheology 185
8.1 Introduction - importance of kinetic properties 185
8.2 Brownian motion 185
187
187
188
190
191
193
193
193
194
194
196
198
198
201
202
202
202
204
206
207
209
210
210
210
211
211
213
214
215
217
219
219
222
223
225
228
229
230
233
233
234
235
Contents
8.3 Sedimentation and creaming (Stokes and Einstein equations)
8.3.1 Stokes equation
8.3.2 Effect of particle shape
8.3.3 Einstein equation
8.4 Kinetic properties via the ultracentrifuge
8.4.1 Molecular weight estimated from kinetic experiments (1 = medium and
2 = particle or droplet)
8.4.2 Sedimentation velocity experiments (1 = medium and 2 = particle or droplet)
8.5 Osmosis and osmotic pressure
8.6 Rheology of colloidal dispersions
8.6.1 Introduction
8.6.2 Special characteristics of colloid dispersions’ rheology
8.7 Concluding remarks
Problems
References
Characterization Methods of Colloids - Part II: Optical Properties (Scattering,
Spectroscopy and Microscopy)
9.1 Introduction
9.2 Optical microscopy
9.3 Electron microscopy
9.4 Atomic force microscopy
9.5 Light scattering
9.6 Spectroscopy
9.7 Concluding remarks
Problems
References
Colloid Stability - Part I: The Major Players (van der Waals and Electrical Forces)
10.1 Introduction - key forces and potential energy plots - overview
10.1.1 Critical coagulation concentration
10.2 van der Waals forces between particles and surfaces - basics
30.3 Estimation of effective Hamaker constants
10.4 vdW forces for different geometries - some examples
10.4.1 Complex fluids
10.5 Electrostatic forces: the electric double layer and the origin of surface charge
10.6 Electrical forces: key parameters (Debye length and zeta potential)
10.6.1 Surface or zeta potential and electrophoretic experiments
10.6.2 The Debye length
10.7 Electrical forces
10.7.1 Effect of particle concentration in a dispersion
10.8 Schulze-Hardy rule and the critical coagulation concentration (CCC)
10.9 Concluding remarks on colloid stability, the vdW and electric forces
10.9.1 vdW forces
10.9.2 Electric forces
Appendix 10.1 A note on the terminology of colloid stability
Contents ix
Appendix 10.2 Gouy-Chapman theory of the diffuse electrical double-layer 236
Problems 238
References 242
11 Colloid Stability - Part II: The DLVO Theory - Kinetics of Aggregation 243
11.1 DLVO theory - a rapid overview 243
11.2 DLVO theory - effect of various parameters 244
11.3 DLVO theory - experimental verification and applications 245
11.3.1 Critical coagulation concentration and the Hofmeister series 245
11.3.2 DLVO, experiments and limitations 247
11.4 Kinetics of aggregation 255
11.4.1 General - the Smoluchowski model 255
11.4.2 Fast (diffusion-controlled) coagulation 255
11.4.3 Stability ratio W 255
11.4.4 Structure of aggregates 257
11.5 Concluding remarks 264
Problems 265
References 268
12 Emulsions 269
12.1 Introduction 269
12.2 Applications and characterization of emulsions 269
12.3 Destabilization of emulsions 272
12.4 Emulsion stability 273
12.5 Quantitative representation of the steric stabilization 275
12.5.1 Temperature-dependency of steric stabilization 276
12.5.2 Conditions for good stabilization 277
12.6 Emulsion design 278
12.7 PIT - Phase inversion temperature of emulsion based on non-ionic emulsifiers 279
12.8 Concluding remarks 279
Problems 280
References 282
13 Foams 283
13.1 Introduction 283
13.2 Applications of foams 283
13.3 Characterization of foams 285
13.4 Preparation of foams 287
13.5 Measurements of foam stability 287
13.6 Destabilization of foams 288
13.6.1 Gas diffusion 289
13.6.2 Film (lamella) rupture 290
13.6.3 Drainage of foam by gravity 291
13.7 Stabilization of foams 293
13.7.1 Changing surface viscosity 293
13.7.2 Surface elasticity 293
x Contents
13.7.3 Polymers and foam stabilization 295
13.7.4 Additives 296
13.7.5 Foams and DLVO theory 296
13.8 How to avoid and destroy foams 296
13.8.1 Mechanisms of antifoaming/defoaming 297
13.9 Rheology of foams 299
13.10 Concluding remarks 300
Problems 301
References 302
14 Multicomponent Adsorption 303
14.1 Introduction 303
14.2 Langmuir theory for multicomponent adsorption 304
14.3 Thermodynamic (ideal and real) adsorbed solution theories (IAST and RAST) 306
14.4 Multicomponent potential theory of adsorption (MPTA) 312
14.5 Discussion. Comparison of models 315
14.5.1 IAST - literature studies 315
14.5.2 IAST versus Langmuir 315
14.5.3 MPTA versus IAST versus Langmuir 317
14.6 Conclusions 317
Acknowledgments 319
Appendix 14.1 Proof of Equations 14.10a,b 319
Problems 319
References 320
15 Sixty Years with Theories for Interfacial Tension - Quo Vadis? 321
15.1 Introduction 321
15.2 Early theories 321
15.3 van Oss-Good and Neumann theories 331
15.3.1 The two theories in brief 331
15.3.2 What do van Oss-Good and Neumann say about their own theories? 333
15.3.3 What do van Oss-Good and Neumann say about each other’s theories? 334
15.3.4 What do others say about van Oss-Good and Neumann theories? 335
15.3.5 What do we believe about the van Oss-Good and Neumann theories? 338
15.4 A new theory for estimating interfacial tension using the partial solvation parameters
(Panayiotou) 339
15.5 Conclusions - Quo Vadis? 344
Problems 345
References 349
16 Epilogue and Review Problems 352
Review Problems in Colloid and Surface Chemistry 353
Index
358
|
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| spelling | Kontogeorgis, Georgios M. Verfasser (DE-588)1100696202 aut Introduction to applied colloid and surface chemistry Georgios M. Kontogeorgis and Søren Kiil, Department of Chemical and Biochemical Engineering, Technical University of Denmark, Denmark Chichester, West Sussex Wiley [2016] xix, 367 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Index Seite 358-367 Surface chemistry Colloids Kolloidchemie (DE-588)4134420-0 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Oberflächenchemie (DE-588)4126166-5 s DE-604 Kolloidchemie (DE-588)4134420-0 s Kiil, Søren Verfasser (DE-588)1100697136 aut Erscheint auch als Online-Ausgabe, PDF 978-1-118-88121-7 Erscheint auch als Online-Ausgabe, EPUB 978-1-118-88120-0 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028972064&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kontogeorgis, Georgios M. Kiil, Søren Introduction to applied colloid and surface chemistry Surface chemistry Colloids Kolloidchemie (DE-588)4134420-0 gnd Oberflächenchemie (DE-588)4126166-5 gnd |
| subject_GND | (DE-588)4134420-0 (DE-588)4126166-5 (DE-588)4123623-3 |
| title | Introduction to applied colloid and surface chemistry |
| title_auth | Introduction to applied colloid and surface chemistry |
| title_exact_search | Introduction to applied colloid and surface chemistry |
| title_full | Introduction to applied colloid and surface chemistry Georgios M. Kontogeorgis and Søren Kiil, Department of Chemical and Biochemical Engineering, Technical University of Denmark, Denmark |
| title_fullStr | Introduction to applied colloid and surface chemistry Georgios M. Kontogeorgis and Søren Kiil, Department of Chemical and Biochemical Engineering, Technical University of Denmark, Denmark |
| title_full_unstemmed | Introduction to applied colloid and surface chemistry Georgios M. Kontogeorgis and Søren Kiil, Department of Chemical and Biochemical Engineering, Technical University of Denmark, Denmark |
| title_short | Introduction to applied colloid and surface chemistry |
| title_sort | introduction to applied colloid and surface chemistry |
| topic | Surface chemistry Colloids Kolloidchemie (DE-588)4134420-0 gnd Oberflächenchemie (DE-588)4126166-5 gnd |
| topic_facet | Surface chemistry Colloids Kolloidchemie Oberflächenchemie Lehrbuch |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028972064&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT kontogeorgisgeorgiosm introductiontoappliedcolloidandsurfacechemistry AT kiilsøren introductiontoappliedcolloidandsurfacechemistry |