Fuel cell fundamentals:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, New Jersey
Wiley
[2016]
|
| Ausgabe: | Third edition |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | xx, 580 Seiten Illustrationen, Diagramme |
| ISBN: | 9781119113805 |
Internformat
MARC
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| 245 | 1 | 0 | |a Fuel cell fundamentals |c Ryan O'Hayre, Department of Metallurgical and Materials Engineering, Colorado School of Mines (PHD, Materials Science and Engineering, Stanford University) [und weitere] |
| 250 | |a Third edition | ||
| 264 | 1 | |a Hoboken, New Jersey |b Wiley |c [2016] | |
| 264 | 4 | |c © 2016 | |
| 300 | |a xx, 580 Seiten |b Illustrationen, Diagramme | ||
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| 337 | |b n |2 rdamedia | ||
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Datensatz im Suchindex
| _version_ | 1804176148059389952 |
|---|---|
| adam_text | CONTENTS
R
PREFACE xi
ACKNOWLEDGMENTS xiii
NOMENCLATURE xvii
1 FUEL CELL PRINCIPLES
1 Introduction 3
1.1 What Is a Fuel Cell? / 3
1.2 A Simple Fuel Cell / 6
1.3 Fuel Cell Advantages / 8
1.4 Fuel Cell Disadvantages /II
1.5 Fuel Cell Types / 12
1.6 Basic Fuel Cell Operation / 14
1.7 Fuel Cell Performance / 18
1.8 Characterization and Modeling / 20
1.9 Fuel Cell Technology / 21
1.10 Fuel Cells and the Environment / 21
1.11 Chapter Summary / 22
Chapter Exercises / 23
v
CONTENTS
2 Fuel Cell Thermodynamics
2.1 Thermodynamics Review / 25
2.2 Heat Potential of a Fuel: Enthalpy of Reaction / 34
2.3 Work Potential of a Fuel: Gibbs Free Energy / 37
2.4 Predicting Reversible Voltage of a Fuel Cell under Non-Standard-State
Conditions / 47
2.5 Fuel Cell Efficiency / 60
2.6 Thermal and Mass Balances in Fuel Cells / 65
2.7 Thermodynamics of Reversible Fuel Cells / 67
2.8 Chapter Summary / 71
Chapter Exercises / 72
3 Fuel Cell Reaction Kinetics
3.1 Introduction to Electrode Kinetics / 77
3.2 Why Charge Transfer Reactions Have an Activation Energy / 82
3.3 Activation Energy Determines Reaction Rate / 84
3.4 Calculating Net Rate of a Reaction / 85
3.5 Rate of Reaction at Equilibrium: Exchange Current Density / 86
3.6 Potential of a Reaction at Equilibrium: Galvani Potential / 87
3.7 Potential and Rate: Butler-Volmer Equation / 89
3.8 Exchange Currents and Electrocatalysis: How to Improve Kinetic
Performance / 94
3.9 Simplified Activation Kinetics: Tafel Equation / 97
3.10 Different Fuel Cell Reactions Produce Different Kinetics / 100
3.11 Catalyst-Electrode Design / 103
3.12 Quantum Mechanics: Framework for Understanding
Catalysis in Fuel Cells / 104
3.13 The Sabatier Principle for Catalyst Selection / 107
3.14 Connecting the Butler-Volmer and Nemst Equations (Optional) / 108
3.15 Chapter Summary / 112
Chapter Exercises / 113
4 Fuel Cell Charge Transport
4.1 Charges Move in Response to Forces / 117
4.2 Charge Transport Results in a Voltage Loss / 121
4.3 Characteristics of Fuel Cell Charge Transport Resistance / 124
4.4 Physical Meaning of Conductivity / 128
4.5 Review of Fuel Cell Electrolyte Classes / 132
CONTENTS
vii
4.6 More on Diffusivity and Conductivity (Optional) / 153
4.7 Why Electrical Driving Forces Dominate Charge Transport (Optional) / 160
4.8 Quantum Mechanics-Based Simulation of Ion Conduction in Oxide
Electrolytes (Optional) / 161
4.9 Chapter Summary / 163
Chapter Exercises / 164
5 Fuel Cell Mass Transport 167
5.1 Transport in Electrode versus Flow Structure / 168
5.2 Transport in Electrode: Diffusive Transport / 170
5.3 Transport in Flow Structures: Convective Transport / 183
5.4 Chapter Summary / 199
Chapter Exercises / 200
6 Fuel Cell Modeling
6.1 Putting It All Together: A Basic Fuel Cell Model / 203
6.2 A ID Fuel Cell Model / 206
6.3 Fuel Cell Models Based on Computational Fluid Dynamics (Optional)
6.4 Chapter Summary / 230
Chapter Exercises / 231
7 Fuel Cell Characterization 237
7.1 What Do We Want to Characterize? / 238
7.2 Overview of Characterization Techniques / 239
7.3 In Situ Electrochemical Characterization Techniques / 240
7.4 Ex Situ Characterization Techniques / 265
7.5 Chapter Summary / 268
Chapter Exercises / 269
203
/ 227
II FUEL CELL TECHNOLOGY
8 Overview of Fuel Cell Types 273
8.1 Introduction / 273
8.2 Phosphoric Acid Fuel Cell / 274
8.3 Polymer Electrolyte Membrane Fuel Cell / 275
8.4 Alkaline Fuel Cell / 278
8.5 Molten Carbonate Fuel Cell / 280
viii
CONTENTS
8.6 Solid-Oxide Fuel Cell / 282
8.7 Other Fuel Cells / 284
8.8 Summary Comparison / 298
8.9 Chapter Summary / 299
Chapter Exercises / 301
9 PEMFC and SOFC Materials 303
9.1 PEMFC Electrolyte Materials / 304
9.2 PEMFC Electrode/Catalyst Materials / 308
9.3 SOFC Electrolyte Materials / 317
9.4 SOFC Electrode/Catalyst Materials / 326
9.5 Material Stability, Durability, and Lifetime / 336
9.6 Chapter Summary / 340
Chapter Exercises / 342
10 Overview of Fuel Cell Systems 347
10.1 Fuel Cell Subsystem / 348
10.2 Thermal Management Subsystem / 353
10.3 Fuel Delivery/Processing Subsystem / 357
10.4 Power Electronics Subsystem / 364
10.5 Case Study of Fuel Cell System Design: Stationary Combined Heat
and Power Systems / 369
10.6 Case Study of Fuel Cell System Design: Sizing a Portable Fuel Cell / 383
10.7 Chapter Summary / 387
Chapter Exercises / 389
11 Fuel Processing Subsystem Design 393
11.1 Fuel Reforming Overview / 394
11.2 Water Gas Shift Reactors / 409
11.3 Carbon Monoxide Clean-Up / 411
11.4 Reformer and Processor Efficiency Losses / 414
11.5 Reactor Design for Fuel Reformers and Processors / 416
11.6 Chapter Summary / 417
Chapter Exercises / 419
CONTENTS
ix
12 Thermal Management Subsystem Design
12.1 Overview of Pinch Point Analysis Steps / 424
12.2 Chapter Summary / 440
423
Chapter Exercises / 441
13 Fuel Cell System Design
447
13.1 Fuel Cell Design Via Computational Fluid Dynamics / 447
13.2 Fuel Cell System Design: A Case Study / 462
13.3 Chapter Summary / 476
Chapter Exercises / 477
14 Environmental Impact of Fuel Cells
481
14.1 Life Cycle Assessment / 481
14.2 Important Emissions for LCA / 490
14.3 Emissions Related to Global Warming / 490
14.4 Emissions Related to Air Pollution / 502
14.5 Analyzing Entire Scenarios with LCA / 507
14.6 Chapter Summary / 510
Chapter Exercises / 511
A Constants and Conversions 517
B Thermodynamic Data 519
C Standard Electrode Potentials at 25°C 529
D Quantum Mechanics 531
D.l Atomic Orbitals / 533
D.2 Postulates of Quantum Mechanics / 534
D.3 One-Dimensional Electron Gas / 536
D.4 Analogy to Column Buckling / 537
D.5 Hydrogen Atom / 538
D.6 Multielectron Systems / 540
D.7 Density Functional Theory / 540
X
CONTENTS
E Periodic Table of the Elements 543
F Suggested Further Reading 545
G Important Equations 547
H Answers to Selected Chapter Exercises 551
BIBLIOGRAPHY 555
INDEX 565
|
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| spelling | O'Hayre, Ryan P. 1978- Verfasser (DE-588)1066978395 aut Fuel cell fundamentals Ryan O'Hayre, Department of Metallurgical and Materials Engineering, Colorado School of Mines (PHD, Materials Science and Engineering, Stanford University) [und weitere] Third edition Hoboken, New Jersey Wiley [2016] © 2016 xx, 580 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Fuel cells Textbooks Brennstoffzelle (DE-588)4008195-3 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Brennstoffzelle (DE-588)4008195-3 s DE-604 Erscheint auch als Online-Ausgabe, EPUB 978-1-119-11415-4 Erscheint auch als Online-Ausgabe, PDF 978-1-119-11420-8 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028924615&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
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| subject_GND | (DE-588)4008195-3 (DE-588)4123623-3 |
| title | Fuel cell fundamentals |
| title_auth | Fuel cell fundamentals |
| title_exact_search | Fuel cell fundamentals |
| title_full | Fuel cell fundamentals Ryan O'Hayre, Department of Metallurgical and Materials Engineering, Colorado School of Mines (PHD, Materials Science and Engineering, Stanford University) [und weitere] |
| title_fullStr | Fuel cell fundamentals Ryan O'Hayre, Department of Metallurgical and Materials Engineering, Colorado School of Mines (PHD, Materials Science and Engineering, Stanford University) [und weitere] |
| title_full_unstemmed | Fuel cell fundamentals Ryan O'Hayre, Department of Metallurgical and Materials Engineering, Colorado School of Mines (PHD, Materials Science and Engineering, Stanford University) [und weitere] |
| title_short | Fuel cell fundamentals |
| title_sort | fuel cell fundamentals |
| topic | Fuel cells Textbooks Brennstoffzelle (DE-588)4008195-3 gnd |
| topic_facet | Fuel cells Textbooks Brennstoffzelle Lehrbuch |
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