Organic nanoreactors: from molecular to supramolecular organic compounds
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam
Elsevier, Academic Press
[2016]
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| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | xiv, 569 Seiten Illustrationen, Diagramme |
Internformat
MARC
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| 020 | |z 9780128017135 |c pbk. |9 978-0-12-801713-5 | ||
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| 100 | 1 | |a Sadjadi, Samahe |e Verfasser |0 (DE-588)1097414477 |4 aut | |
| 245 | 1 | 0 | |a Organic nanoreactors |b from molecular to supramolecular organic compounds |c Samahe Sadjadi, Gas Conversion Department, Iran Polymer Petrochemical Institute, Faculty of Petrochemicals, Tehran, Iran |
| 264 | 1 | |a Amsterdam |b Elsevier, Academic Press |c [2016] | |
| 264 | 4 | |c © 2016 | |
| 300 | |a xiv, 569 Seiten |b Illustrationen, Diagramme | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
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Datensatz im Suchindex
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| adam_text |
Titel: Organic nanoreactors
Autor: Sadjadi, Samahe
Jahr: 2016
Contents
List of Contributors xiii
1. Introduction to Nanoreactors
Samahe Sadjadi
1 Approaches to Artificial Enzymes 1
2 Nanoreactors 3
2.1 Nanoreactor Definition 3
2.2 Encapsulation Effects 3
2.3 Reaction Kinetics Inside Nanoreactors 4
2.4 Product Inhibition 6
2.5 Nanoreactor Classification 6
3 Nanoreactor Potential Applications 7
3.1 Catalysis 7
3.2 Protection and Stabilization 8
3.3 Templating and Stabilizing of Nanomaterials 9
3.4 Polymer Science 9
3.5 Development of Nanomedicines 10
3.6 Sensors 10
4 Conclusions 10
References 10
2. Cyclodextrins as Porous Material for Catalysis
Jolanta Rousseau, St^phane Menuel, Cyril Rousseau,
Frederic Hapiot, Eric Monflier
1 Cyclodextrins: A Brief Overview 15
1.1 Structure and Supramolecular Properties 15
1.2 CD-Based Polymers 16
1.3 Applications of CDs 18
2 CD-Based Polymers as Mass-Transfer Promoters 20
2.1 Ester Hydrolysis 20
2.2 Nucleophilic Substitution 22
2.3 Oxidation 22
2.4 Aldol Condensation 23
2.5 Organometallic Catalysis 24
v
vi Contents
3 Imprinted CD-Based Polymers for Catalysis 26
3.1 Wacker Oxidation 29
3.2 Oxidative Coupling 31
4 CD-Based Nanosponges 34
5 Conclusions 38
References 39
3. The Use of Cucurbit[r7]urils as Organic Nanoreactors
Brian D. Wagner
1 Introduction 43
2 Physical Properties of Cucurbit[n]urils 46
3 Host Properties of Cucurbit[n]urils 49
3.1 Cationic Guests 52
3.2 Neutral Guests 53
3.3 Other Guests 55
4 Effects of Cucurbit[n]uril Hosts on Guest Physical
and Structural Properties 56
4.1 Effects of CB[n] Hosts on Guest Solubility 56
4.2 Effects of CBjn] Hosts on Guest Spectroscopic Properties 57
4.3 Effects of CB[n] Hosts on Guest Structure
and Isomerization 58
4.4 Effects of CB(n] Hosts on Guest Aggregation 60
5 Effects of Cucurbit[n]urils on Guest Reactivity
and Chemical Properties 61
5.1 CB[r?) Nanoreactor Control of Guest Acidity 62
5.2 CB|n] Nanoreactor Control of Guest Electrochemical
Properties 64
5.3 CB[n] Nanoreactors for Enhanced Reactant
Solubility and Stability 64
5.4 CB[n] Nanoreactors for Reactant Geometry
And Stereochemistry Control 66
5.5 CB[n] Nanoreactors for Reaction Templating 67
5.6 CB[n] Nanoreactors for Reaction Catalysis 72
6 Conclusions 75
References 76
4. Systems Based on Calixarenes as the Basis for the
Creation of Catalysts and Nanocontainers
Ivan I. Stoikov, Luidmila S. Yakimova, Joshua B. Puplampu,
AlenaA. Vavilova
1 Introduction 85
2 Synthesis and Structure of Calixarenes 85
2.1 Calixarenes and Thiacalixarenes 86
2.2 Calix[4]resorcinarenes and Pyrogallolarenes 88
3 Macromolecular Catalysts Based on Macrocyclic Receptors 89
4 Supramolecular Catalysis by Calixarenes 91
Contents vii
5 Supramolecular Catalysis by Metal Complexes Based
On Calixarenes 94
6 Supramolecular Systems for Controlled Binding/Isolation
of Organic Molecules and Biosubstrates 102
7 Conclusions 103
References 103
5. Carbon Nanotube Nanoreactors for Chemical
Transformations
M. Rosa Axet, Philippe Serp
1 Introduction 111
2 Confinement Effects Inside Carbon Nanotubes 112
2.1 Electronic Effects 112
2.2 Surface and Cavity Effects 118
2.3 Combination of Effects 124
3 Characterization of Confined Species in Carbon Nanotubes 125
4 Synthesis of Confined Metal Nanoparticles in
Carbon Nanotubes 128
4.1 Wet Chemistry Method 129
4.2 Use of Melted Compounds 132
4.3 Use of Volatile Compounds 132
4.4 Use of Supercritical Medium 134
4.5 Simultaneous Growth of CNTs and Filling of the Inner Cavity 134
5 Chemical Transformations Inside Carbon Nanotubes 135
5.1 Noncatalytic Chemical Reactions 136
5.2 Catalytic Chemical Reaction 138
6 Summary 145
References 146
6. Dendrimers as Nanoreactors
Samahe Sadjadi
1 Introduction to Dendrimers 159
1.1 Dendrimers 159
1.2 Metallodendrimers 161
2 Nanoreactors 161
3 Dendrimers as Nanoreactors 162
3.1 Dendrimer Cavity 162
3.2 Periphery of Dendrimers 163
4 Dendritic Hosts 167
5 Dendritic Nanoreactor Effects of Guest(s) 170
5.1 Dendritic Nanoreactor Effect on Solubility of Guest(s) 170
5.2 Dendritic Nanoreactor Effect on Biocompatibility of Guest(s) 173
5.3 Dendritic Nanoreactor Effect on Fluoresces of Guest(s) 174
5.4 Dendritic Nanoreactor and Guest Isomerization 174
6 Dendritic Nanoreactors as Templating and Stabilizing Agent 176
6.1 Stabilization and Templating of Metallic Nanoparticles 178
6.2 Stabilization and Templating of Quantum Dots 182
vili Contents
7 Dendritic Nanoreactor in Catalysis
7.1 Representative Examples of Dendritic Catalysts
8 Dendritic Nanoreactor in Energy Sector
9 Conclusions
References
7. Catalysis Within the Self-Assembled
Resorcin[4]arene Hexamer
Giuseppe Borsato, Alessandro Scarso
1 Catalysis Within Cavities
1.1 Hexamer of Resorcin[4]arene: Synthesis and Properties
2 Hexameric Capsule as an Inhibitor
3 Hexameric Capsule as a Supramolecular Nanoreactor
3.1 Effects on Product Selectivity
3.2 Effects on Substrate Selectivity
4 Hexameric Capsule as a Catalyst
4.1 Hydrolysis and Hydration Reactions
4.2 C—C Bond-Forming Reactions
4.3 C-heteroatom Bond-Forming Reactions
4.4 Cyclization Reactions
5 Conclusions and Future Perspectives
References
8. The Varied Supramolecular Chemistry
of PyrogallolI4]arenes
Saeedeh Negin, George W. Gokel
1 Introduction 235
2 Pyrogallol[4]arene Capsules 238
3 Pyrogallol[4]arene Capsule-Membrane Interactions 239
4 Pyrogallol[4]arene Membrane Aggregation — Planar
Bilayer Studies 240
5 Pyrogallol[4]arene Membrane Aggregation —Langmuir
Trough Studies 243
6 A Monc-Based Ion Conducting Channel 245
7 Solid-State Structures of Linear and Branched
Pyrogallol[4]arenes 247
8 Pyrogallol[4]arene-Based Nanotubes 248
9 Tetra-3-Pentylpyroga1lo!l4]arene-Mediated Ion Transport 251
10 Conclusions 253
References 254
186
187
195
197
198
203
208
209
21 1
212
214
219
219
220
225
226
230
230
9. Supramolecular Coordination Cages as Nanoreactors
Samahe Sadjadi
1 Introduction 257
2 M4L6Tetrahedral Self-Assembled Capsules 258
2.1 Guest Encapsulation in M4L6 Cages 258
2.2 Guest Exchange Pathway in M4L6 Cages 262
Contents ix
2.3 Protection and Stabilization of Reactive Species 263
2.4 Catalysis by M4L6 Cages 265
3 Self-Assembled Capsules With Two-Dimensional Ligands 273
3.1 Protection and Stabilization 274
3.2 Catalysis 276
4 Giant Self-Assembled MNL2N Spherical Complexes 285
4.1 Guest Encapsulation in Spherical Complexes 291
4.2 Solubility Enhancement by Using Spherical Complexes 292
4.3 Cavity-Templated Synthesis 293
5 Miscellaneous Coordination Cages 297
6 Conclusions 300
References 301
10. Metal Organic Frameworks as Nanoreactors
and Host Matrices for Encapsulation
F.G. Cirujano, F.X. Llabr£s I Xamena
1 Introduction 305
2 Virtues and Limitations of MOFs as Host Matrices
and Nanoreactors 306
3 MOFs as Nanoreactors 308
4 MOFs as Host Matrices for Encapsulation 313
4.1 Methods of Encapsulation 314
4.2 Catalytic Species Encapsulated in MOFs 322
4.3 The Benefits of Encapsulation for Catalysis 329
5 Conclusions and Perspectives 333
References 334
11. Bionanoreactors: From Confined Reaction Spaces
to Artificial Organelles
Viktoriia Postupalenko, Tomaz Einfalt, Mihai Lomora,
lonel A. Dinu, Cornelia G. Palivan
1 Introduction 341
2 Polymers as Building Blocks for Nanoreactors 342
3 3D Polymer Supramolecular Assemblies 345
3.1 Supramolecular Structures as Spaces for the Generation
of Nanoreactors 345
3.2 Accessibility of 3D Polymer Supramolecular Assemblies 351
3.3 Encapsulation/Insertion of Active Compounds: Design
of Bionanoreactors 354
3.4 Activity and Stability of 3D Nanoarchitectures 354
3.5 Multicompartment Structures 357
3.6 Requirements for Various Applications of Nanoreactors 357
4 Applications of Nanoreactors 359
4.1 Diagnostic Applications 359
4.2 Therapeutic Applications 360
5 Conclusions 364
References 364
x Contents
12. Supercritical Fluids in Nanoreactor Technology
Sodeh Sadjadi
1 The Critical Point and Supercritical Fluids 3 73
1.1 Properties of Supercritical Fluids 374
2 Microemulsions 377
2.1 Introduction 377
2.2 SCF-Continuous Microemulsions 377
2.3 SCF-Continuous Microemulsions Applications
as Nanoreactors 379
3 Nanotubes 402
3.1 Introduction 402
3.2 The Potential Benefits of Filling Nanotubes
With Supercritical Fluids 404
3.3 Filling Nanotubes With Different Supercritical Fluids 406
3.4 Nanotubes'Applications as Nanoreactors 407
4 Conclusions 410
References 413
13. Pyrene: The Guest of Honor
Nicolas P.E. Barry, Bruno Therrien
1 Introduction 421
1.1 Scope 421
1.2 Pyrene: Structure and Characterization 422
1.3 Binding Constants in a Nutshell 425
2 Techniques Used to Study Host-Pyrene Interactions
in Solution 426
2.1 Introduction 426
2.2 UV-vis Spectroscopy 427
2.3 Fluorescence Spectroscopy 429
2.4 NMR Spectroscopy and Diffusion Coefficients 431
3 Pyrene and Organic Supramolecular Hosts 434
3.1 A Brief History and Some Examples of Organic
Host Species 434
3.2 Pyrene-Cavitand Interactions 437
3.3 Pyrene-containing Receptors: The Particular
Case of Pillar[n]arenes 439
4 Pyrene and Nanoscale Hosts 443
4.1 Coordination-Driven Self-Assembly and
Metalla-Assemblies 443
4.2 Metal-Based Nanoparticles and Metal Organic
Frameworks 445
4.3 Nanoparticles Made of Polymers and Micelles 447
5 Conclusions and Closing Remarks 452
References 453
Contents xi
14. Nanoreactors Based on Porphyrin-Functionalized
Carbon Compounds
Pietro Tagliatesta, Barbara Floris, Stefano Bellucci
1 Introduction 463
1.1 Craphene-and Graphene Oxide-Porphyrin Nanoreactors 464
1.2 Carbon Nanotubes-Porphyrin Nanoreactors 483
1.3 Fullerene Nanoreactors 495
2 Conclusions 501
References 502
15. Therapeutic Nanoreactors: Toward a Better Blood
Substitute
Agnes Ostafin, Kyu Bum Han
1 Nanoreactors in Biology and Medicine 519
2 Need for Blood Substitutes 520
3 Blood Substitute Materials 520
4 Designing a Better Blood Substitute 520
5 Retrievable Nanoreactor Blood Substitutes 521
6 Performance of Retrievable Nanoreactor Blood Substitutes 523
7 Summary 548
References 549
Subject Index
551 |
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| spelling | Sadjadi, Samahe Verfasser (DE-588)1097414477 aut Organic nanoreactors from molecular to supramolecular organic compounds Samahe Sadjadi, Gas Conversion Department, Iran Polymer Petrochemical Institute, Faculty of Petrochemicals, Tehran, Iran Amsterdam Elsevier, Academic Press [2016] © 2016 xiv, 569 Seiten Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028915425&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Sadjadi, Samahe Organic nanoreactors from molecular to supramolecular organic compounds |
| title | Organic nanoreactors from molecular to supramolecular organic compounds |
| title_auth | Organic nanoreactors from molecular to supramolecular organic compounds |
| title_exact_search | Organic nanoreactors from molecular to supramolecular organic compounds |
| title_full | Organic nanoreactors from molecular to supramolecular organic compounds Samahe Sadjadi, Gas Conversion Department, Iran Polymer Petrochemical Institute, Faculty of Petrochemicals, Tehran, Iran |
| title_fullStr | Organic nanoreactors from molecular to supramolecular organic compounds Samahe Sadjadi, Gas Conversion Department, Iran Polymer Petrochemical Institute, Faculty of Petrochemicals, Tehran, Iran |
| title_full_unstemmed | Organic nanoreactors from molecular to supramolecular organic compounds Samahe Sadjadi, Gas Conversion Department, Iran Polymer Petrochemical Institute, Faculty of Petrochemicals, Tehran, Iran |
| title_short | Organic nanoreactors |
| title_sort | organic nanoreactors from molecular to supramolecular organic compounds |
| title_sub | from molecular to supramolecular organic compounds |
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