Emulsions: formation, stability, industrial applications
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin
De Gruyter
[2016]
|
| Schriftenreihe: | De Gruyter graduate
|
| Schlagworte: | |
| Online-Zugang: | http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110452174&searchTitles=true Inhaltsverzeichnis |
| Beschreibung: | XV, 225 Seiten Illustrationen, Diagramme (teilweise farbig) |
| ISBN: | 9783110452174 |
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| 245 | 1 | 0 | |a Emulsions |b formation, stability, industrial applications |c Tharwat F. Tadros |
| 264 | 1 | |a Berlin |b De Gruyter |c [2016] | |
| 264 | 4 | |c © 2016 | |
| 300 | |a XV, 225 Seiten |b Illustrationen, Diagramme (teilweise farbig) | ||
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Datensatz im Suchindex
| _version_ | 1804176118194896896 |
|---|---|
| adam_text | CONTENTS
THERMODYNAMICS OF EMULSION FORMATION AND BREAKDOWN * 9
THE INTERFACE (GIBBS DIVIDING LINE)
*
9
THERMODYNAMICS OF EMULSION FORMATION AND BREAKDOWN _ 1 1
3 INTERACTION FORCES BETWEEN .M ULSION DROPLETS * 15
3.1 VAN DER WAALS ATTRACTION * 15
3.2 ELECTROSTATIC REPULSION * 17
3.3 STERIC REPULSION * 21
3.3.1 MIXING INTERACTION
GMIX
*
23
3.3.2 ELASTIC INTERACTION
GEL
* 24
3.3.3 TOTAL ENERGY OFLNTERACTION * 25
3.3.4 CRITERIA FOR EFFECTIVE STERLE STABILIZATION * 2 *
4 ADSORPTION OF SURFACTANTS AT THE OIL/W ATER INTERFACE * 29
4.1 INTRODUCTION * 29
4.2 THE GIBBS ADSORPTION ISOTHERM * 29
4.3 EQUATION OF STATE PPPROACH * 32
4.4 THE LANGMUIR, SZYSZKOWSKI AND FRUMKIN EQUATIONS* 3 4
4.5 EFFECTIVENESS OF SURFACTANT ADSORPTION
AT THE LIQUID/LIQUID INTERFACE * 35
4.6 EFFICIENCY OF AD O P TIO N OF SURFACTO^
AT THE L*QUID/L*QU*D INTPRFARP * *
4.7 ADSORPTION FROM MIXTURES OF TWO SURFACTANTS * 37
4.8 ADSORPTION OF MACROMOLECULES * 38
PREFECE * V
1 EMULSIONS: FORMATION, STABILITY. INDUSTRIAL A P P L I C A O N S - L
1.1 GENERAL INTRODUCTION *
1
1
1.2 NATURE OF THE EMULSIFIER* 1
1.3 STRUCTURE OF THE SYSTEM * 2
1.4 BREAKDOWN PROCESSES IN EMULSIONS * 3
1.5 CREAMING AND SEDIMENTATION * 4
1.6 FLOCCULATION * 4
1.7 OSTWALD RIPENING(DISPROPORTLONATION)-
*
4
1.8 COALESCENCE * 5
1.9 PHASE INVERSION * 5
1.10 INDUSTRIAL APPLICATIONS OF EMULSIONS * S
1.11 BOOKOUTLINE * 6
2
2
.:
2
.:
4*9
4.9.1
4.9.2
4.9.3
4.9.4
4.9.5
4.9.6
5
5.1
5.2
5.3
5.3.1
5.3.2
6
6.1
6.2
6.2.1
6.2.2
6.2.3
6.3
6.3.1
6.32
6.7;
6.5
7.1
7.2
7.3
7.4
7.5
7.6
8
8.1
8.2
8.2.1
8.2.2
8.2.3
INTERFACIAL TENSION MEASUREMENTS * 40
THE WILHELMY PLATE METHOD
*
40
THE PENDENT DROP METHOD * 41
SESSILE DROP METHOD * 42
THE DU NOUY RING METHOD * 43
THE DROP VOLUME (WEIGHT) METHOD
*
43
THE SPINNING DROP METHOD * 44
MECHANISM OF EMULSIFICATION AND THE ROLE OF THE EM ULSIFIER- 4 7
INTRODUCTION * 47
MECHANISM OF EMULSIFICATION _ 47
ROLE OF SURFACTANTS *N EMULSION FORMATION * 50
ROLE OF SURFACTANTS IN REDUCTION OF DROPLET SIZE * 50
ROLE OF SURFACTANTS IN DROPLET DEFORMATION
*
53
METHODS OF
OM ILLC IFIRA TIN N * 59
INTRODUCTION * 59
ROTOR-STATOR MIXERS * 59
TOOTHED DEVICES * 59
BATCH RADIAL DISCHARGE MIXERS
*
60
DESIGN AND ARRANGEMENT * 61
FLOW REGIMES * 63
LAMINAR FLOW * 64
TURBULENT STOW * 66
MEMBRANE EMULSIFICATION _ 69
FORMULATION VARIABLES AND COMPARISON OF VARIOUS EMULSIFICATION
METHODS * 70
SELECTION OF EMULSIFIERS * 73
INTRODUCTION * 73
THE HYDROPH*UC-UPOPH*LE BALANCE (HLB) CONCEPT * 76
THE PHASE INVERSION TEMPERATURE (PIT) CONCEPT * 82
THE COHESIVE ENERGY RAFIO (CER) CONCEPT * 85
THE CRITICAL PACKING PARAMETER (CPP) FOR EMULSION SELECTION _ 86
STABILISATION BY SOLID PARTICLES (PICKERING EMULSIONS) * 89
CREAMING/SEDIMENTATION OF EMULSIONS AND !TS PREVENTION 95
INTRODUCTION * 95
CREAMING OR SEDIMENTATION RATES * 96
VERY DILUTE EMULSIONS (*
*
0 .0 1 )*
MODERATELY CONCENTRATED EMULSIONS
(0 .2
*
*
*
0.1)
* 97
CONCENTRATED EMULSIONS
(* 0 .2 )
* 98
8.3 PROPERTIES OF A CREAMED LAYER * 98
8.4 PREVENTION OF CREAMING OR SEDIMENTATION *
**
8.4.1 MATCHING DENSITY OF OIL AND AQUEOUS PHASES * 99
8.4.2 REDUCTION OF DROPLET SIZE * 99
8.4.3 U S E O F*THICKENERS*
*
100
8.4.4 REDUCTION OF CREAMING/SEDIMENTATION OF EMULSIONS
USING ASSOCIATIVE THICKENERS * 103
8.4.5 CONTROLLED FLOCCULATION _ 1 0 6
8.4.6 DEPLETION FLOCCULATION * 107
* 7 USE OF *INERT* FINE PARTICLES * 109
8.4.8 USE OF MIXTURES OF POLYMERS AND FINELY DIVIDED PARTICULATE S O LID
S _ 1 1 0
8.4.9 USE OF LIQUID CRYSTALLINE PHASES* 111
Q FLOCCULATION OF EMULSIONS * 113
Q1
INTRODUCTION
9.2 MECHANISM OFEMULSION FLOCCULATION * 113
9.2.1 FLOCCULATION OF ELECTROSTATICALLY STABILISED EMULSIONS *
9.2.2 FLOCCULATION OF STERICALLY STABILISED EMULSIONS* 1 1 8
9.2.3 WEAK FLOCCULATION OF STERICALLY STABILISED EMULSIONS *
1
122
9.2.4 DEPLETION FLOCCULATION* 123
9.2.5 BR*DGINGSLOCCULAT*ON BY POLYMERSAND POLYELECTROLYTES * 124
9 ? GENERAL RULES FOR REDUCING (ELIMINATING) FLOCCULATION * 127
9.3.1 CHARGE STABILISED EMULSIONS, E.G. USING IONIC SURFACTANTS * 127
9.3.2 STENCAUY STABILISED EMULSIONS * 127
10 OSTWALD RIPENING IN EMULSIONS AND ITS PREVENTION * 129
10.1 DRIVINGFORCE FOR OSWALD RIPENING * 129
10.2 KINETICS OF OSTWALD RIPENING * 130
10.3 REDUCTION OF OSTWALD RIPENING * 134
10.3.1 ADDITION OFASM ALL PROPORTION OF HIGHLY INSOLUBLE OIL * 134
10.3.2 MODIFICATION OFTHE INTERFACIAL LAYER FOR REDUCTION OF OSTWALD
RIPENING * 136
10.4 INFLUENCE OF INITIAL DROPLET SIZE OF EMULSIONS
ON THE OSTWALD RIPENING RATE * 137
11 EMULSION COALESCENCE AND ITS PREVENTION*.1 4 1
1 1 1 IN TM H IIR TIN N * 1* 1
11.2 FORCES ACROSS LIQUID FILMS * 141
11.2.1 DISJOINING PRESSURE APPROACH * 143
11.2.2 INTERFACIAL TENSION OF LIQUID FILMS I * 143
11.3 FILM RUPTURE* 1 4 4
11.4 RATE OF COALESCENCE BETWEEN
DROPLETS*
I * A 6
XIV
**
CONTENTS
11 *
REDUCTION OF COALESCENCE
*
151
11.5.1 USE OF MIXED SURFACTANT FILMS *
1
151
12 PHASE INVERSION AND ITS PREVENTION * 161
12.1 INTRODUCTION * 161
12.2 CATASTROPHE INVERSION * 161
12.3 TRANSITIONAL INVERSION * 163
12.4 THE PHASE INVERSION TEMPERATURE
(****
1 6 5
13 CHARACTERIZATION OF EMULSIONS AND ASSESSMENT OF THEIR STABILITY 173
13.1 INTRODUCTION * 173
13.2 ASSESSMENT OF THE STRUCTURE OF THE L*
*
U*D/LIQU*D INTERFACE * 17*
13.2.1 DOUBLE *AYER INVESTIGATION * 174
13.2.2 MEASUREMENT OF SURFACTANT AND POLYMER ADSORPTION * 176
13.3 ASSESSMENT OFCREAMLNG/SEDIMENTATLON OF EMULSIONS * 177
13.4 ASSESSMENT OF FLOCCULATION, OSTWALD RIPENING AND COALESCENCE * 180
13.4.1 OPTICAL MICROSCOPY * 180
13.4.2 ELECTRON MICROSCOPY * 182
13.4.3 CONFOCAL LASER SCANNING MICROSCOPY (CLSM) * 184
13.5 SCATTERING TECHNIQUES * 184
13.5.1 LIGHT-SCATTERING TECHNIQUES * 184
13.5.2 TURBIDITY MEASUREMENTS * 185
13.5.3 LIGHT DIFFRACTION TECHNIQUES * 186
13.5.4 DYNAMIC LIGHTSCATTERING- PHOTON CORRELATION
SPECTROSCOPY (PCS) * 188
13.5.5 B ACK-SCATTER*N GTECHN *QU ES_191
13.6 MEASUREMENT OF THE RATE OF CREAMING OR SEDIMENTATION * 191
13.7 MEASUREMENT OF RATE OF FLOCCULATION* 1 9 2
13.8 MEASUREMENT OF INCIPIENT STOCCULATION _ 1 3
*
13.9 MEASUREMENT OF OSTWALD RIPENING** 193
13.10 MEASUREMENT OF THE RATE OF C O
13.11 BULK PROPERTIES OF EMULSIONS EQUILIBRIUM CREAM OR SEDIMENT VOLUME
(OR HEIGHT) * 194
14 INDUSTRIAL APPLICATIONS OF EMULSIONS * 197
14.1 INTRODUCTION * 197
14.2 FNNRI PM IIKINNC* 1 0 7
14.2.1 FOOD GRADE SURFACTANTS *
*
198
14.2.2 SURFACTANT ASSOCIATION STRUCTURES, MICRO-EMULSIONS AND EMULSIONS
*N FOOD * 207
14.3 EMULSIONSLNCOSMETICSANDPE^^^^
14.4 EMULSIONS IN PHARMACY* 2 1 7
14.5
14.6
INDEX
EMULSIONS IN AGROCHEMICALS * 219
ROLLING OK AND LUBRICANT EM ULSIONS-
223
220
|
| any_adam_object | 1 |
| author | Tadros, Tharwat F. 1937-2018 |
| author_GND | (DE-588)129740837 |
| author_facet | Tadros, Tharwat F. 1937-2018 |
| author_role | aut |
| author_sort | Tadros, Tharwat F. 1937-2018 |
| author_variant | t f t tf tft |
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| bvnumber | BV043490374 |
| classification_rvk | VE 7080 |
| ctrlnum | (OCoLC)951066726 (DE-599)DNB1078859906 |
| dewey-full | 660 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 660 - Chemical engineering |
| dewey-raw | 660 |
| dewey-search | 660 |
| dewey-sort | 3660 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie |
| format | Book |
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| genre_facet | Lehrbuch |
| id | DE-604.BV043490374 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:27:06Z |
| institution | BVB |
| isbn | 9783110452174 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-028906923 |
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| owner_facet | DE-11 DE-703 DE-29T DE-634 DE-83 |
| physical | XV, 225 Seiten Illustrationen, Diagramme (teilweise farbig) |
| publishDate | 2016 |
| publishDateSearch | 2016 |
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| publisher | De Gruyter |
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| spelling | Tadros, Tharwat F. 1937-2018 Verfasser (DE-588)129740837 aut Emulsions formation, stability, industrial applications Tharwat F. Tadros Berlin De Gruyter [2016] © 2016 XV, 225 Seiten Illustrationen, Diagramme (teilweise farbig) txt rdacontent n rdamedia nc rdacarrier De Gruyter graduate Emulsion (DE-588)4014626-1 gnd rswk-swf Grenzflächenchemie (DE-588)4246080-3 gnd rswk-swf Fachhochschul-/Hochschulausbildung 1\p (DE-588)4123623-3 Lehrbuch gnd-content Emulsion (DE-588)4014626-1 s Grenzflächenchemie (DE-588)4246080-3 s DE-604 Erscheint auch als Online-Ausgabe, EPUB 978-3-11-045226-6 Erscheint auch als Online-Ausgabe, PDF 978-3-11-045224-2 http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110452174&searchTitles=true Verlag DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028906923&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Tadros, Tharwat F. 1937-2018 Emulsions formation, stability, industrial applications Emulsion (DE-588)4014626-1 gnd Grenzflächenchemie (DE-588)4246080-3 gnd |
| subject_GND | (DE-588)4014626-1 (DE-588)4246080-3 (DE-588)4123623-3 |
| title | Emulsions formation, stability, industrial applications |
| title_auth | Emulsions formation, stability, industrial applications |
| title_exact_search | Emulsions formation, stability, industrial applications |
| title_full | Emulsions formation, stability, industrial applications Tharwat F. Tadros |
| title_fullStr | Emulsions formation, stability, industrial applications Tharwat F. Tadros |
| title_full_unstemmed | Emulsions formation, stability, industrial applications Tharwat F. Tadros |
| title_short | Emulsions |
| title_sort | emulsions formation stability industrial applications |
| title_sub | formation, stability, industrial applications |
| topic | Emulsion (DE-588)4014626-1 gnd Grenzflächenchemie (DE-588)4246080-3 gnd |
| topic_facet | Emulsion Grenzflächenchemie Lehrbuch |
| url | http://www.degruyter.com/search?f_0=isbnissn&q_0=9783110452174&searchTitles=true http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028906923&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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