Descriptive inorganic chemistry:
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| Sprache: | English |
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Amsterdam ; Boston ; Heidelberg ; London ; New York ; Oxford ; Paris ; San Diego ; Singapore ; Sydney ; Tokyo
Elsevier
[2016]
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| Ausgabe: | Third edition |
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| Beschreibung: | xi, 428 Seiten Illustrationen |
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| 100 | 1 | |a House, James E. |d 1936- |e Verfasser |0 (DE-588)1081633735 |4 aut | |
| 245 | 1 | 0 | |a Descriptive inorganic chemistry |c James E. House, professor emeritus, Illinois State University, Normal, Illinois; Kathleen A. House, Illinois Wesleyan University, Boomington, Illinois |
| 250 | |a Third edition | ||
| 264 | 1 | |a Amsterdam ; Boston ; Heidelberg ; London ; New York ; Oxford ; Paris ; San Diego ; Singapore ; Sydney ; Tokyo |b Elsevier |c [2016] | |
| 264 | 4 | |c © 2016 | |
| 300 | |a xi, 428 Seiten |b Illustrationen | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
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| 689 | 0 | 0 | |a Anorganische Chemie |0 (DE-588)4002145-2 |D s |
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| 700 | 1 | |a House, Kathleen Ann |d 1966- |e Verfasser |0 (DE-588)1081634154 |4 aut | |
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Datensatz im Suchindex
| _version_ | 1804175830910238720 |
|---|---|
| adam_text | Titel: Descriptive inorganic chemistry
Autor: House, James E
Jahr: 2016
Contents
Preface to the Third Edition xi
1. Where It All Comes From 1
1.1. The Structure of the Earth 1
1.2. Com position of the Earth s Crust 2
1.3. Rocks and Minerals 3
1.4. Weathering 3
1.5. Obtaining Metals 4
1.6. Some Metals Today 6
1.7. Nonmetallic Inorganic
Minerals 7
References for Further Reading 9
Problems 9
2. Atomic Structure and Properties 11
2.1. Atomic Structure 11
2.1.1. Quantum Numbers 11
2.1.2. Hydrogen-Like Orbitals 13
2.2. Properties of Atoms 14
2.2.1. Electron Configurations 15
2.2.2. lonization Energy 17
2.2.3. Electron Affinity 18
2.2.4. Electronegativity 19
References for Further Reading 21
Problems 21
3. Covalent Bonding and Molecular
Structure 23
3.1. Molecular Structure 23
3.1.1. Molecular Orbitals 23
3.1.2. Orbital Overlap 26
3.1.3. Polar Molecules 28
3.1.4. Geometry of Molecules Having
Single Bonds 29
3.1.5. Valence Shell Electron Pair
Repulsion (VSEPR) 32
3.1.6. Some Subtle Influences
on Bonds 33
3.1.7. Bond Angles and Inversion 34
3.2. Symmetry 35
3.3. Resonance 41
References for Further Reading 45
Problems 45
4. lonic Bonding, Crystals, and
Intermolecular Forces 47
4.1. lonic Bonds 47
4.1.1. Energetics of the lonic Bond 47
4.1.2. Radius Ratio Effects 50
4.1.3. Crystal Structures 53
4.2. Intermolecular Interactions 56
4.2.1. Dipole—Dipole
Forces 57
4.2.2. Dipole-Induced Dipole
Forces 57
4.2.3. London Dispersion Forces 58
4.2.4. Hydrogen Bonding 58
4.2.5. Solubility Parameters 62
References for Further Reading 64
Problems 65
5. Reactions and Energy
Relationships 67
5.1. Thermodynamic Considerations 67
5.1.1. The Boltzmann Distribution
Law 67
5.1.2. Reactions and AG° 70
5.1.3. Relationship between AG
and T 72
5.1.4. Bond Enthalpies 73
5.2. Combination Reactions 75
5.3. Decomposition Reactions 77
5.4. Redox Reactions 78
5.5. Flydrolysis Reactions 79
5.6. Replacement Reactions 79
5.7. Metathesis 80
5.8. Neutralization Reactions 82
References for Further Reading 83
Problems 83
vi
Contents
6. Acids, Bases, and Nonaqueous
Solvents
6.1. Acid—Base Chemistry
6.1.1. Factors Affecting Acid Strength
6.1.2. Factors Affecting Base Strength
6.1.3. Acids and Bases from Oxides
6.1.4. Molten Salt Protonic Acids
6.1.5. Lewis Theory
6.1.6. HSAB Principle
6.1.7. Applications of the Hard—Soft
Interaction Principle
6.2. Nonaqueous Solvents
6.2.1. The Solvent Concept
6.2.2. The Coordination Model
6.2.3. Liquid Ammonia
6.2.4. Reactions in Liquid Ammonia
6.2.5. Liquid HF
6.2.6. Liquid Sulfur Dioxide
6.3. Superacids
References for Further Reading
Problems
7. Hydrogen
7.1. Elemental and Positive
Hydrogen
7.2. Occurrence and Properties
7.3. Hydrides
7.3.1. lonic Hydrides
7.3.2. Interstitial Hydrides
7.3.3. Covalent Hydrides
References for Further Reading
Problems
8. The Group IA and IIA Metals
8.1. General Characteristics
8.2. Oxides and Hydroxides
8.3. Halides
8.4. Sulfides
8.5. Nitrides and Phosphides
8.6. Carbides, Cyanides, Cyanamides, and
Amides
8.7. Carbonates, Nitrates, Sulfates, and
Phosphates
8.8. Organic Derivatives
8.9. Zintl Compounds
References for Further Reading
Problems
9. Boron
9.1. Elemental Boron
9.2. Bonding in Boron Compounds
87
87
89
91
91
92
93
95
97
99
99
101
102
102
105
106
107
108
108
111
111
114
115
115
117
117
120
120
123
123
127
129
130
130
131
9.3. Boron Compounds
9.3.1. Borides
9.3.2. Boron Halides
9.3.3. Boron Hydrides
9.3.4. Boron Nitrides
9.3.5. Polyhedral Boranes
References for Further Reading
Problems
10.
11.
12. Silicon, Germanium, Tin, and
141
141
141
142
144
146
149
150
Aluminum, Gallium, Indium, and
Thallium
151
10.1.
The Elements
151
10.2.
Oxides
153
10.3.
Hydrides
155
10.4.
Halides
156
10.5.
Other Compounds
157
10.6.
Organometallic Compounds
158
References for Further Reading
161
Problems
161
Carbon
163
11.1.
The Element
163
11.1.1. Graphite
163
11.1.2. Graphene
164
11.1.3. Diamond
165
11.1.4. Fullerenes
165
11.2.
Industrial Uses of Carbon
166
11.2.1. Advanced Composites
166
11.2.2. Manufactured Carbon
167
11.2.3. Chemical Uses of Carbon
167
11.3.
Carbon Compounds
168
11.3.1. lonic Carbides
168
11.3.2. Covalent Carbides
169
11.3.3. Interstitial Carbides
169
11.3.4. Oxides of Carbon
169
11.3.5. Carbon Halides
173
11.3.6. Carbon Nitrides
173
11.3.7. Carbon Sulfides
174
References for Further Reading
175
Problems
175
132
Lead
177
132
12.1.
The Elements
177
134
12.2.
Hydrides of the Group IVA
135
Elements
179
136
12.3.
Oxides of the Group IVA Elements
12.3.1. The +2 Oxides
180
180
139
12.3.2. The+4 Oxides
181
139
140
12.3.3. Glass
182
12.4.
Silicates
184
12.5.
Zeolites
187
Contents
12.6.
12.7.
12.8.
Halides of the Croup IV Elements
12.6.1. The+2 Halides
12.6.2. The +4 Halides
Organic Compounds
Miscellaneous Compounds
References for Further Reading
Problems
13. Nitrogen
13.1.
13.2.
13.3.
13.4.
13.5.
13.6.
Elemental Nitrogen
Nitrides
Ammonia and Aquo Compounds
Hydrogen Compounds
13.4.1. Ammonia
13.4.2. Hydrazine, N2H4
13.4.3. Diimine, N2H2
13.4.4. Hydrogen Azide, HN3
Nitrogen Halides
13.5.1. NX3 Compounds
13.5.2. Difluorodiazine, N2F2
13.5.3. Oxyhalides
Nitrogen Oxides
13.6.1. Nitrous Oxide, N2O
13.6.2. Nitric Oxide, NO
13.6.3. Dinitrogen Trioxide, N2O3
13.6.4. Nitrogen Dioxide, NO2 and
N204
13.6.5. Dinitrogen Pentoxide, N2Os
Oxyacids
13.7.1. Hyponitrous Acid, H2N2O2
13.7.2. Nitrous Acid, HNO2
13.7.3. Nitric Acid, HNO3
Nitrogen in the Environment
13.8.1. Nitrogen Fixation
Nitrification
Denitrification
Human Influences in the
Nitrogen Cycle
References for Further Reading
Problems
14. Phosphorus, Arsenic,
Antimony, and Bismuth
Occurrence
Preparation and Properties of the
Elements
Hydrides
Oxides
14.4.1. The +3 Oxides
14.4.2. The +5 Oxides
Sulfides
13.7.
13.8.
13.8.2.
13.8.3.
13.8.4.
14.1.
14.2.
14.3.
14.4.
14.5.
189
190
191
191
193
195
195
197
197
198
198
199
199
201
202
202
203
203
204
204
205
205
206
207
207
208
209
209
209
210
212
212
212
212
212
213
213
215
215
215
216
217
218
218
219
14.6.
14.7.
14.8.
14.9.
vii
Halides
220
14.6.1. Halides of the Type E2X4
220
14.6.2. Trihalides
220
14.6.3. Pentahalides and
Oxyhalides
222
Phosphazine (Phosphonitrilic)
Compounds
225
Acids and Their Salts
226
14.8.1. Phosphorous Acid and
Phosphites
227
14.8.2. Phosphoric Acids and
Phosphates
228
Phosphorus in the Environment
231
14.9.1. Phosphorus in Soaps and
Detergents
231
14.9.2. Fertilizer Production
231
References for Further Reading
233
Problems
233
15. Oxygen
15.1. Elemental Oxygen, O2
15.2. Ozone, O3
15.3. Preparation of Oxygen
15.4. Binary Compounds of Oxygen
15.4.1. lonic (Metallic) Oxides
15.4.2. Covalent Oxides
15.4.3. Amphoteric Oxides
15.4.4. Peroxides and Superoxides
15.5. Positive Oxygen
References for Further Reading
Problems
16. Sulfur, Selenium, and Tellurium
16.1.
16.2.
16.3.
16.4.
16.5.
16.6.
16.7.
16.8.
16.9.
16.10.
Occurrence of Sulfur
Occurrence of Selenium and
Tellurium
Elemental Sulfur
Elemental Selenium and Tellurium
Reactions of Elemental
Selenium and Tellurium
Hydrogen Compounds
Oxides of Sulfur, Selenium, and
Tellurium
16.7.1. Dioxides
16.7.2. Trioxides
Halogen Compounds
Nitrogen Compounds
Oxyhalides of Sulfur and
Selenium
16.10.1. Oxidation State+4
16.10.2. Oxidation State+6
235
235
236
237
238
238
239
240
241
242
243
243
245
245
246
247
248
249
250
251
251
252
253
256
257
258
259
viii
Contents
16.11. Oxyacids of Sulfur, Seleniurn,
and Tellurium
16.11.1. Sulfurous Acid and Sulfites
16.11.2. Dithionous Acid and
Dithionites
16.11.3. Dithionic Acid and
Dithionates
16.11.4. Peroxydisulfuric Acid and
Peroxydisulfates
16.11.5. Oxyacids of Seleniurn and
Tellurium
16.12. Sulfuric Acid
16.12.1. Preparation of Sulfuric
Acid
16.12.2. Physical Properties of
Sulfuric Acid
16.12.3. Chemical Properties of
Sulfuric Acid
16.12.4. Uses of Sulfuric Acid
References for Further Reading
Problems
17. Halogens
17.1. Occurrence
17.2. The Elements
17.3. Interhalogens
17.3.1. Type XX
17.3.2. Type XX3
17.3.3. Type XX 5
17.3.4. Type XX 7
17.3.5. Structures
17.3.6. Chemical Properties
17.4. Polyatomic Cations
and Anions
17.4.1. Polyatomic Halogen Cations
17.4.2. Interhalogen Cations
17.4.3. Polyatomic Halogen Anions
17.5. Hydrogen Halides
17.5.1. Physical Properties
17.5.2. Preparation
17.6. Oxides
17.6.1. Oxygen Fluorides
17.6.2. Chlorine Oxides
17.6.3. Bromine Oxides
17.6.4. lodine Oxides
17.6.5. Oxyfluorides of the
Heavier Halogens
17.7. Oxyacids and Oxyanions
1 7.7.1. Hypohalous Acids and
Hypohalites
1 7.7.2. Halous Acids and Halites
17.7.3. Halic Acids and Halates
17.7.4. Perhalic Acids and Perhalates
References for Further Reading
Problems
18.
The
Noble Gases
287
260
261
18.1.
The Elements
287
18.2.
The Xenon Fluorides
289
261
18.3.
Reactions of Xenon
Fluorides
290
262
18.4.
Oxyfluorides and Oxides
292
References for Further Reading
294
263
Problems
294
263
19.
The
Transition Metals
297
264
19.1.
The Metals
297
19.1.1. Structures of Metals
297
264
19.1.2. Alloys
303
19.2.
Oxides
305
264
19.3.
Sulfides
309
19.4.
Halides and Oxyhalides
309
265
19.5.
Miscellaneous Compounds
311
266
19.6.
The Lanthanides
312
267
References for Further Reading
314
267
Problems
314
269
20.
Structure and Bonding in
269
Coordination Compounds
317
269
20.1.
Types of Ligands and Complexes
317
271
20.2.
Naming Coordination Compounds
319
271
20.3.
Isomerism
321
272
20.3.1. Geometrical Isomerism
321
273
20.3.2. Optical Isomerism
323
273
20.3.3. Linkage Isomerism
323
273
20.3.4. lonization Isomerism
324
274
20.3.5. Coordination Isomerism
324
275
20.3.6. Polymerization Isomerism
325
20.3.7. Hydrate Isomerism
325
275
20.4.
Factors Affecting the Stability of
275
Complexes
325
276
20.4.1. The Nature of the Acid—Base
277
Interaction
325
277
20.4.2. The Chelate Effect
326
278
20.4.3. Ring Size and Structure
327
278
20.5.
AValence Bond Approach to Bonding
279
in Complexes
329
279
20.6.
Back Donation
333
280
20.7.
Ligand Field Theory
335
281
20.7.1. Octahedral Fields
335
20.7.2. Tetrahedral, Tetragonal, and
281
Square Planar Fields
336
282
20.7.3. Factors Affecting A
338
20.7.4. Ligand Field Stabilization
282
Energy
339
282
20.8.
Jahn—Teller Distortion
341
283
20.9.
Complexes Having Metal—Metal
283
Bonds
342
284
References for Further Reading
344
285
Problems
344
Contents
21. Synthesis and Reactions of
Coordination Compounds
21.1. Synthesis of Coordination
Compounds
21.1.1. Reaction of a Metal Salt with a
Ligand
21.1.2. Ligand Replacement
Reactions
21.1.3. Reaction of Two Metal
Compounds
21.1.4. Oxidation—Reduction
Reactions
21.1.5. Partial Decomposition
21.1.6. Size and SolubiIity
Relationships
21.1.7. Reactions of Metal Salts with
Amine Salts
21.2. A Survey of Reaction Types
21.2.1. Ligand Substitution
21.2.2. Oxidative Addition (Oxad)
Reactions
21.2.3. Insertion Reactions
21.2.4. Group Transfer Reactions
21.2.5. Electron Transfer Reactions
21.3. A Closer Look at Substitution
Reactions
21.4. Substitution in Square Planar
Complexes
21.4.1. Mechanisms
21.4.2. The Trans Effect
21.4.3. Causes of the Trans Effect
21.5. Substitution in Octahedral
Complexes
21.5.1. Classification Based on Rates
21.5.2. The Effect of LFSE on Rate of
Substitution
21.5.3. The SN1CB
Mechanism
References for Further Reading
Problems
22. Organometallic Compounds
22.1. Structure and Bonding in Metal
Alkyls
22.2. Preparation of Organometallic
Compounds
22.3. Reactions of Metal Alkyls
22.4. Cyclopentadienyl Complexes
(Metallocenes)
22.5. Metal Carbonyl Complexes
22.5.1. Binary Metal Carbonyls
22.5.2. Structures of Metal Carbonyls
22.5.3. Preparation of Metal
Carbonyls
ix
22.5.4. Reactions of Metal Carbonyls 384
22.6. Metal—Olefin Complexes 387
22.6.1. Structure and Bonding 387
22.6.2. Preparation of Metal—Olefin
Complexes 389
22.7. Complexes of Benzene and Related
Aromatics 390
References for Further Reading 391
Problems 391
23. Inorganic Substances in
Biochemical Applications 395
23.1. Therapeutic Aspects of Inorganic
Substances 395
23.1.1. Metal Compounds in
Treatment of Poison Ivy 395
23.1.2. Iran Deficiency in Trees 397
23.1.3. Fluorides 397
23.1.4. Titanium Dioxide 397
23.1.5. Zinc Oxide 398
23.1.6. Hydroxyurea 398
23.1.7. Arsenic Compounds 398
23.1.8. Cisplatin and Other Platinum
Complexes 399
23.1.9. Auranofin 399
23.1.10. Anticancer Compounds
Containing First-Row Metals 400
23.1.11. Ruthenium Compounds in
Cancer Treatment 401
23.1.12. Metal Compounds in
Treatment of Malaria 401
23.2. Biochemical Aspects of Energy
Changes 401
23.2.1. Production of Energy by ATP 402
23.2.2. Photosynthesis 403
23.3. Oxygen Transport 404
23.3.1. Hemoglobin 404
23.3.2. Metal Ions in Superoxide
Dismutase 406
23.3.3. Zinc in Carbonic
Anhydrase 406
References for Further Reading 408
Problems 408
Appendix A. Ground State Electron
Configurations of Atoms 411
Appendix B. lonization Energies 415
Index 419
347
347
347
348
348
349
349
349
350
350
351
351
353
353
354
356
358
358
360
362
364
364
364
366
368
368
371
371
374
376
378
380
380
381
384
|
| any_adam_object | 1 |
| author | House, James E. 1936- House, Kathleen Ann 1966- |
| author_GND | (DE-588)1081633735 (DE-588)1081634154 |
| author_facet | House, James E. 1936- House, Kathleen Ann 1966- |
| author_role | aut aut |
| author_sort | House, James E. 1936- |
| author_variant | j e h je jeh k a h ka kah |
| building | Verbundindex |
| bvnumber | BV043298082 |
| classification_rvk | VH 5010 |
| ctrlnum | (OCoLC)953578190 (DE-599)BVBBV043298082 |
| discipline | Chemie / Pharmazie |
| edition | Third edition |
| format | Book |
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| genre | (DE-588)4123623-3 Lehrbuch gnd-content |
| genre_facet | Lehrbuch |
| id | DE-604.BV043298082 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:22:32Z |
| institution | BVB |
| isbn | 9780128046975 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-028719030 |
| oclc_num | 953578190 |
| open_access_boolean | |
| owner | DE-11 DE-12 DE-384 DE-19 DE-BY-UBM |
| owner_facet | DE-11 DE-12 DE-384 DE-19 DE-BY-UBM |
| physical | xi, 428 Seiten Illustrationen |
| publishDate | 2016 |
| publishDateSearch | 2016 |
| publishDateSort | 2016 |
| publisher | Elsevier |
| record_format | marc |
| spelling | House, James E. 1936- Verfasser (DE-588)1081633735 aut Descriptive inorganic chemistry James E. House, professor emeritus, Illinois State University, Normal, Illinois; Kathleen A. House, Illinois Wesleyan University, Boomington, Illinois Third edition Amsterdam ; Boston ; Heidelberg ; London ; New York ; Oxford ; Paris ; San Diego ; Singapore ; Sydney ; Tokyo Elsevier [2016] © 2016 xi, 428 Seiten Illustrationen txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie (DE-588)4002145-2 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Anorganische Chemie (DE-588)4002145-2 s DE-604 House, Kathleen Ann 1966- Verfasser (DE-588)1081634154 aut HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028719030&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | House, James E. 1936- House, Kathleen Ann 1966- Descriptive inorganic chemistry Anorganische Chemie (DE-588)4002145-2 gnd |
| subject_GND | (DE-588)4002145-2 (DE-588)4123623-3 |
| title | Descriptive inorganic chemistry |
| title_auth | Descriptive inorganic chemistry |
| title_exact_search | Descriptive inorganic chemistry |
| title_full | Descriptive inorganic chemistry James E. House, professor emeritus, Illinois State University, Normal, Illinois; Kathleen A. House, Illinois Wesleyan University, Boomington, Illinois |
| title_fullStr | Descriptive inorganic chemistry James E. House, professor emeritus, Illinois State University, Normal, Illinois; Kathleen A. House, Illinois Wesleyan University, Boomington, Illinois |
| title_full_unstemmed | Descriptive inorganic chemistry James E. House, professor emeritus, Illinois State University, Normal, Illinois; Kathleen A. House, Illinois Wesleyan University, Boomington, Illinois |
| title_short | Descriptive inorganic chemistry |
| title_sort | descriptive inorganic chemistry |
| topic | Anorganische Chemie (DE-588)4002145-2 gnd |
| topic_facet | Anorganische Chemie Lehrbuch |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028719030&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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