Pigment processing: physico-chemical principles
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hannover
Vincentz Network
2015
|
| Ausgabe: | 2nd revised edition |
| Schriftenreihe: | European Coatings LIBRARY
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Ausführliche Beschreibung Inhaltsverzeichnis |
| Beschreibung: | 240 Seiten Illustrationen 22.5 cm x 15.5 cm, 550 g |
| ISBN: | 9783866306653 3866306652 |
Internformat
MARC
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| 653 | |a crystal structure | ||
| 653 | |a physical characterisation of pigments | ||
| 653 | |a pigment application | ||
| 653 | |a pigment dispersions | ||
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Datensatz im Suchindex
| _version_ | 1806333015144529920 |
|---|---|
| adam_text |
CONTENTS
INTRODUCTION 11
1 PHYSICAL CHARACTERISATION OF PIGMENTS 13
1.1 PARTICLE MORPHOLOGY 13
1.2 CRYSTAL STRUCTURE 15
1.2.1 CRYSTAL MODIFICATIONS: POLYMORPHISM 15
1.2.2 ISOMORPHISM AND ANISOTROPY 16
1.2.3 X-RAY CRYSTALLOGRAPHY 17
1.3 PARTICLE SIZE MEASUREMENT 20
1.3.1 PARTICLE SIZE DISTRIBUTION 21
1.3.1.1 SIEVE ANALYSIS 21
1.3.1.2 DETERMINATION BY ELECTRON MICROSCOPY 22
1.3.1.3 ANALYSIS BY SEDIMENTATION TECHNIQUES 22
1.3.1.4 OPTICAL METHODS 24
1.3.1.5 ULTRASONIC ATTENUATION SPECTROSCOPY 26
1.3.1.6 ELECTROACOUSTIC METHODS 27
1.3.1.7 THE COULTER COUNTER 27
1.3.1.8 METHODS OF PRESENTING RESULTS 27
1.3.2 SPECIFIC SURFACE AREA 29
1.3.2.1 THE FREUNDLICH ADSORPTION ISOTHERM 29
1.3.2.2 LANGMUIR'S ADSORPTION THEORY 30
1.3.2.3 THE ADSORPTION ISOTHERM
ACCORDING TO BRUNAUER, EMMETT AND TELLER 32
1.3.2.4 DETERMINATION OF THE AVERAGE PARTICLE SIZE 34
1.4 SURFACE CHARACTER 37
1.4.1 POLARITY AND HYDROPHILICITY 37
1.4.2.1 SURFACE TENSION 39
1.4.2.2 CAPILLARITY 45*
1.4.3 ELECTRICAL POLARISABILITY 47
1.4.3.1 POLARISATION OF DIELECTRICS IN AN ELECTRIC FIELD 47
1.4.3.2 POLARISABILITY AND REFRACTIVE INDEX 48
1.4.3.3 POLARISABILITY AND PIGMENT/BINDER-INTERACTION 49
1.4.4 SURFACE TREATMENT 50
HTTP://D-NB.INFO/1078328706
8
CONTENTS
2 OPTICAL PROPERTIES OF PIGMENTED SYSTEMS 53
2.1 REFLECTION, GLOSS AND GLOSS HAZE 54
2.1.1 GLOSS 54
2.1.2 GLOSS HAZE 59
2.2 LIGHT SCATTERING BY COLLOIDAL DISPERSE PARTICLES 60
2.2.1 RAYLEIGH SCATTERI NG 61
2.2.2 MIE THEORY 63
2.3 ABSORPTION AND SCATTERING AS FACTORS IN
THE TINCTORIAL PROPERTIES OF PIGMENTS 69
2.3.1 HIDING POWER, SEMI-TRANSPARENCY AND TRANSPARENCY 69
2.3.2 LIGHTENING POWER 78
2.3.3 TINTING STRENGTH AND DEPTH OF SHADE 79
2.3.4 HUE (OR SHADE) 81
3 RHEOLOGICAL BEHAVIOUR OF PIGMENT DISPERSIONS 85
3.1 INTRODUCTION 85
3.2 NEWTON'S LAW OF VISCOSITY 85
3.3 DEPENDENCE OF VISCOSITY ON TEMPERATURE 88
3.4 FLOW PROPERTIES OF CONCENTRATED
SUSPENSIONS AND MOLECULAR COLLOIDS 90
3.4.1 NEWTONIAN FLOW 91
3.4.2 STRUCTURAL VISCOSITY (PSEUDOPLASTICITY) 92
3.4.3 DILATANCY 94
3.4.4 PLASTICITY 95
3.4.4.1 BINGHAM OR LINEAR-PLASTIC FLOW 96
3.4.4.2 NON-LINEAR PLASTICITY (CASSON VISCOSITY) 97
3.4.4.3 PLASTIC-DILATANT FLOW 100
3.4.5 SHEAR-TIME DEPENDENT FLOW 101
3.4.5.1 THIXOTROPY 101
3.4.5.2 RHEOPEXY 103
3.4.6 VISCOELASTICITY 104
3.4.6.1 EFFECT PRINCIPLES 104
3.4.6.2 EFFECT OF MOLECULAR STRUCTURE 106
3.4.7 FLOW BEHAVIOUR OF WATER-THINNABLE BINDER SYSTEMS 107
3.5 RHEOLOGICAL BEHAVIOUR OF PIGMENTED SYSTEMS IN PRACTICE 108
3.5.1 BASIC ASPECTS 108
3.5.2 PRINTING INKS ILL
3.5.3 PAINTS AND ENAMELS 114
CONTENTS 9
3.5.4 PLASTICS 117
3.6 CLOSING REMARKS 118
4 DISPERSION PROCESS: PHYSICO-CHEMICAL FUNDAMENTALS 119
4.1 INTRODUCTION 119
4.2 STAGES OF THE DISPERSION PROCESS 120
4.2.1 MECHANICAL BREAKDOWN 120
4.2.1.1 FORCES OF INTERACTION BETWEEN THE PIGMENT PARTICLES 120
4.2.1.2 TYPES OF MECHANICAL BREAKDOWN 123
4.2.2.1 ENERGETIC APPROACH 125
4.2.2.2 WETTING KINETICS 128
4.2.3 STABILISATION 130
4.2.3.1 FUNDAMENTAL ASPECTS 130
4.2.3.2 STABILISATION BY STERIC HINDRANCE 130
4.2.3.3 ELECTROSTATIC STABILISATION: DLVO THEORY AND ZETA POTENTIAL.
143
4.2.3.4 MEASURING ZETA POTENTIALS 147
4.3 STABILISATION PROBLEMS WITH PIGMENTED SYSTEMS
AFTER DISPERSION 149
4.3.1 FLOCCULATION 149
4.3.1.1 FUNDAMENTAL ASPECTS 149
4.3.1.2 TESTING AND MEASURING FLOCCULATION BEHAVIOUR 151
4.3.1.3 KINETIC APPROACH TO FLOCCULATION 153
4.3.1.4 COFLOCCULATION 155
4.3.1.5 PREVENTION OF FLOCCULATION 156
4.3.2 FLOODING AND FLOATING 156
4.3.2.1 DISCUSSION AND THEORETICAL EXPLANATION 156
4.3.2.2 TESTING SEPARATION PHENOMENA.
SPRAY-POURING TEST AND RUB-OUT TEST 160
4.3.2.3 METHODS FOR OVERCOMING FLOODING AND FLOATING 161
4.3.3 SHOCK EFFECTS AND SEEDING 164
4.3.3.1 PIGMENT SHOCK 164
4.3.3.2 BINDER SHOCK 165
4.3.3.3 SOLVENT SHOCK 166
4.3.3.4 SEEDING 166
5 DISPERSION PROCESS: METHODS AND MATHEMATICAL MODELS
FOR ASSESSING THE DEGREE OF DISPERSION 169
5.1 INTRODUCTION 169
10
CONTENTS
5.2 DIRECT METHODS 169
5.2.1 FINENESS-OF-GRIND AND DISPERSION CURVE 169
5.2.2 EXAMINATION WITH THE OPTICAL MICROSCOPE 173
5.3 INDIRECT METHODS 174
5.3.1 TINTING STRENGTH DEVELOPMENT 174
5.3.2 ASSESSMENT OF THE STATE OF DISPERSION FROM GLOSS DEVELOPMENT. 181
5.3.3 INCREASE IN LIGHTNESS FLOP 182
5.4 CONCLUDING REMARKS 184
6 DISPERSION PROCESS: MILL BASE OPTIMISATION 185
6.1 GENERAL CONSIDERATIONS 185
6.2 DESCRIPTION OF THE DISPERSION PROCESS
BY A PROBABILITY FUNCTION 188
6.2.1 THEORETICAL PRINCIPLES 188
6.2.2 PRACTICAL CONCLUSIONS FROM THE PROBABILITY
RELATIONSHIP FOR THE DISPERSION PROCESS 192
6.3 DISPERSIBILITY OF PIGMENTS 193
6.3.1 CRITICAL APPROACH TO THE DEFINITION OF PIGMENT DISPERSIBILITY
ACCORDING TO DIN ISO 18451-1 193
6.3.2 TESTING AND STATING THE DISPERSIBILITY AS SPECIFIED IN
DIN EN ISO 8780 AND DIN EN ISO 8781 193
6.3.3 ASSESSMENT OF THE DISPERSIBILITY BY MEANS OF A
HALF-LIFE VALUE 195
6.3.4 PRAGMATIC DEFINITION FOR PIGMENT DISPERSIBILITY 197
6.4 METHODS FOR MILL BASE OPTIMISATION 203
6.4.1 DANIEL FLOW-POINT PROCEDURE 203
6.4.2 GUGGENHEIM FACTOR 205
6.4.3 EFFICIENCY OF THE DISPERSION PROCESS:
NEW CRITERION FOR OPTIMIZING MILL BASES 206
6.4.4 OPTIMISATION OF SEVERAL FACTORS BY MEANS OF AN
EXPERIMENTAL DESIGN ACCORDING TO PLACKETT AND BURMAN 211
6.4.5 OPTIMISATION OF THE COST OF THE DISPERSION PROCESS BY
CONTROLLING ENERGY INPUT 214
APPENDIX 218
LIST OF PHYSICAL SYMBOLS AND CONSTANTS USED 218
LIST OF RELEVANT NORMS 221
REFERENCES 225
INDEX 234 |
| any_adam_object | 1 |
| author | Oyarzún, Juan M. |
| author_facet | Oyarzún, Juan M. |
| author_role | aut |
| author_sort | Oyarzún, Juan M. |
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| dewey-full | 660 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 660 - Chemical engineering |
| dewey-raw | 660 |
| dewey-search | 660 |
| dewey-sort | 3660 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie |
| edition | 2nd revised edition |
| format | Book |
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| indexdate | 2024-08-03T02:50:02Z |
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| spelling | Oyarzún, Juan M. Verfasser aut Pigment processing physico-chemical principles Juan M. Oyarzún 2nd revised edition Hannover Vincentz Network 2015 240 Seiten Illustrationen 22.5 cm x 15.5 cm, 550 g txt rdacontent n rdamedia nc rdacarrier European Coatings LIBRARY Pigment (DE-588)4132245-9 gnd rswk-swf Fachhochschul-/Hochschulausbildung Erwachsenenbildung Studierende in beschichtungstechnologischen Fach- und Hochschulstudiengängen<BR>Fachliche Ein- und Umsteiger in der Lackforschung und -Entwicklung<BR>Fachleute (Ingenieure und Chemiker) der betrieblichen Beschichtungspraxis<BR>Laboranten und Techniker in der Lackindustrie<BR> crystal structure physical characterisation of pigments pigment application pigment dispersions Pigment (DE-588)4132245-9 s DE-604 Vincentz Network GmbH & Co. KG (DE-588)6059967-4 pbl X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=f6bc498efd364482bb294451f874f723&prov=M&dok_var=1&dok_ext=htm Inhaltstext X:MVB text/html http://www.european-coatings.com/silver.econtent/catalog/vincentz/european_coatings/buecher/european_coatings_tech_files/pigment_processing Ausführliche Beschreibung DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028671602&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Oyarzún, Juan M. Pigment processing physico-chemical principles Pigment (DE-588)4132245-9 gnd |
| subject_GND | (DE-588)4132245-9 |
| title | Pigment processing physico-chemical principles |
| title_auth | Pigment processing physico-chemical principles |
| title_exact_search | Pigment processing physico-chemical principles |
| title_full | Pigment processing physico-chemical principles Juan M. Oyarzún |
| title_fullStr | Pigment processing physico-chemical principles Juan M. Oyarzún |
| title_full_unstemmed | Pigment processing physico-chemical principles Juan M. Oyarzún |
| title_short | Pigment processing |
| title_sort | pigment processing physico chemical principles |
| title_sub | physico-chemical principles |
| topic | Pigment (DE-588)4132245-9 gnd |
| topic_facet | Pigment |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=f6bc498efd364482bb294451f874f723&prov=M&dok_var=1&dok_ext=htm http://www.european-coatings.com/silver.econtent/catalog/vincentz/european_coatings/buecher/european_coatings_tech_files/pigment_processing http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028671602&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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