Scorpionates: the coordination chemistry of polypyrazolborate ligands
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Bibliographische Detailangaben
1. Verfasser: Trofimenko, Swiatoslaw (VerfasserIn)
Format: Elektronisch E-Book
Sprache:English
Veröffentlicht: River Edge, NJ Imperial College Press c1999
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Beschreibung:Includes bibliographical references (p. 209-273) and index
Polypyrazolylborates--Scorpionates -- - The Abbreviation System for Scorpionate Ligands -- - Comparison of the Tp and Cp Ligands -- - Historical Development -- - Reviews -- - Synthesis of Scorpionate Ligands -- - List of Known Scorpionate Ligands -- - Analogs of Scorpionate Ligands -- - Homoscorpionates--First Generation -- - Group 1: H, Li, Na, K, Rb and Cs -- - Group 2: Be, Mg, Ca, Sr, Ba -- - Group 3: Sc, Y -- - Group 4: Ti, Zr, Hf -- - Group 5: V, Nb, Ta -- - Group 6: Cr, Mo, W -- - Group 7: Mn, Tc, Re -- - Group 8: Fe, R, Os -- - Group 9: Co, Rh, Ir -- - Group 10: Ni, Pd, Pt -- - Group 11: Cu, Ag, Au -- - Group 12: Zn, Cd, Hg -- - Group 13: B, Al, Ga, In, Tl -- - Group 14: C, Si, Ge, Sn, Pb -- - Group 15: N, P, As, Sb, Bi -- - Lanthanides -- - Actinides -- - Homoscorpionates--Second Generation -- - Regiochemistry in Ligand Synthesis -- - Quantification of Steric Effects in Tp[superscript x] Ligands -- - Ligand Rearrangments -- - Individual Ligands -- - B-substituted Ligands, RTp[superscript x] (R [not equal] pz[superscript x]) -- - 3-Monosubstituted Ligands, Tp[superscript R] -- - 4-Monosubstituted Ligands, Tp[superscript 4R] -- - 5-Monosubstituted Ligands, Tp[superscript 5R] -- - C-Disubstituted Ligands -- - 3,4-Disubstituted Ligands -- - 3,5-Disubstituted Ligands of Type Tp[superscript R2] -- - 3,5-Disubstituted Ligands of Type Tp[superscript R,R'] -- - 4,5-Disubstituted Ligands -- - Trisubstituted Ligands -- - Heteroscorpionates, RR'Bp[superscript x] -- - Specific Ligands -- - Bp[superscript x] Ligands -- - R[subscript 2]Bp[superscript x] Ligands -- - Ligands R(R'Z)Bp[superscript x] -- - Specific Ligands
"This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. The book is intended as a reference work, placing at the researcher's command practically all of the over 1500 references on the subject up to, and into 1999, organized both according to the ligand type and according to the metal or metalloid being coordinated. It acquaints the reader with the special features of this ligand system and permits an assessment of what has been done in a given sub-area, and of which areas remain relatively unexplored. It presents procedures for ligand synthesis, and also covers their use in catalysis and in the modelling of biologically active substances."--BOOK JACKET.
Beschreibung:1 Online-Ressource (x, 282 p.)
ISBN:1848160429
1860941729
9781848160422
9781860941726

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