Organometallic chemistry: Volume 33
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Format: Elektronisch E-Book
Sprache:English
Veröffentlicht: Cambridge Royal Society of Chemistry 2007
Schriftenreihe:Specialist periodical report v. 33
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Beschreibung:Groups 1 and 11: The Alkali and Coinage Metals-- 1 Alkali Metals-- 1.1 Introduction-- 1.2 Alkyl Derivatives-- 1.3 Alkenyl, Allyl, Vinyl, Alkynyl and Related Derivatives-- 1.4 Aryl Derivatives-- 1.5 Cyclopentadienyl and Related Derivatives-- 2 Copper, Silver and Gold-- 2.1 Introduction-- 2.2 Copper Compounds-- 2.3 Silver Compounds-- 2.4 Gold Compounds-- References-- Group 2 (Be-Ba) and Group 12 (Zn-Hg)-- 1 Scope and Organisation of the Review-- 2 Group 2-- 3 Group 12-- References-- Scandium, Yttrium and the Lanthanides-- 1 Introduction-- 2 Hydrocarbyls of Various Kinds-- 3 Half Sandwich Cyclopentadienyl Complexes-- 4 Metallocene Derivatives-- 5 Ansa Metallocene Ligand Chemistry-- 6 Indenyl and Fluorenyl Complexes-- 7 Functionalized Cyclopentadienyls and Related Ligands-- 7.1 Functional Groups with Nitrogen Donors-- 7.2 Functional Groups with Group 16 Donors-- 8 Hydride Complexes-- 9 Allyls-- 10 Cyclo-Octatetraenyl Complexes-- 11 Nitrogen-Donor Ancillaries--
- 11.1 Ketiminate Chemistry-- 11.2 Amido Ancillary Groups-- 12 Organophosphorus Supporting Ligands-- 13 Aryloxide Ancillaries-- 14 Compounds with Boron-Based Ligands-- 15 Materials Chemistry-- 16 Applications in Organic Synthesis-- 16.1 Stoichiometric Reactions-- 16.2 Catalysis-- 17 Polymerization Catalysis-- 17.1 Neutral Olefins and Dienes-- 17.2 Acrylate and Polar Monomer Polymerization-- 18 Theoretical and Computational Studies-- 18.1 Structure and Bonding-- 18.3 Agostic Interactions-- 18.4 Interaction of Small Molecules-- 18.5 Calculating Chemical Reactivity-- 18.6 Pretend Molecules-- 19 Spectroscopic Studies-- References-- Carboranes, Including Their Metal Complexes-- 1 Introduction-- 2 Theoretical and Computational Studies-- 3 Heteroboranes, Carboranes and Heterocarboranes-- 3.1 {B3 and B4}-- 3.2 {B8, B9 and B10}-- 3.3 {B12}-- 3.4 {PCB8}-- 3.5 {SB8}-- 3.6 {CB6, CB7, CB8, CB9}-- 3.7 {CB11}-- 3.8 {NC2B7}-- 3.9 {As2C2B7}-- 3.10 {C2B9}-- 3.11 {C2B10}-- 3.12 {C2B11}--
- 4 Metallaboranes and Metallacarboranes-- 4.1 {MB3 and MB4}-- 4.2 {MB5}-- 4.3 {MB6 and MB8}-- 4.4 {MCB8}-- 4.5 {MCB9}-- 4.6 {MCB10}-- 4.7 {MC2B4}-- 4.8 {C2B8}-- 4.9 {MC2B9}-- 4.10 {MC2B10}-- 4.11 {MPC2B8}-- 4.12 {M2C3B8}-- 4.13 {exo-C2B9}-- 5 Biological Carborane Chemistry and BNCT-- 6 Weakly Coordinating Anions and Catalysis-- 7 Crystal Engineered Supramolecular and Polymeric (Metalla)carborane Materials-- References-- Group III -- B, Al, Ga, In, Tll-- 1 General-- 2 Boron-- 2.1 B(C6F5)3 and Related Boranes-- 2.2 Borate Anions-- 2.3 Ligand Systems Based Around a Tri- or Tetra-Coordinate Boron Centre-- 2.4 Boron Hydrides-- 2.5 Boron-Based Ligand Systems-- 2.6 Boratabenzenes and Related Systems-- 2.7 Boron-Containing Materials and Sensors-- 2.8 Boronic Acids/Esters and Suzuki Type Coupling Reactions-- 2.9 Boron Functionalized Cyclopentadienyl Ligands-- 2.10 Miscellaneous-- 3 Aluminium-- 3.1 Hydrides-- 3.2 Aluminate Complexes--
- 3.3 Aluminium Derivatives Containing Bonds to Group 15 Donors-- 3.4 Aluminium Derivatives Containing Bonds to Oxygen-- 3.5 Aluminium Organometallics in Organic Synthesis-- 3.6 Miscellaneous Examples-- 4 Gallium-- 4.1 Subvalent Gallium Species and Clusters-- 4.2 Complexes Containing Subvalent Gallium Species as Ligands-- 4.3 Arylgallium Species-- 4.4 Gallium Hydrides-- 4.5 Gallium Derivatives Containing Bonds to Group 15 or Group 16 Elements-- 4.6 Miscellaneous-- 5 Indium-- 5.1 Subvalent Indium and Indium Clusters-- 5.2 Indium Derivatives Containing Bonds to Groups 15 or 16-- 5.3 Miscellaneous Examples-- 6 Thallium-- References-- Group 14: Silicon, Germanium, Tin and Lead-- 1 Overview-- 2 Multiple Bonds in Group 14-- 3 Tetrylenes-- 4 Radicals, Cations and Anions-- 5 Homoaromatics and Other Ring Systems-- 6 Pi-Bonded Complexes-- 7 Group 14 Organometallics as Ligands at Transition Metal Centres-- References--
- Recent Advances in the Chemistry of Phosphaalkynes: Building Blocks for Novel Organophosphorus Compounds-- 1 Introduction-- 2 Synthesis of New Phosphaalkynes-- 3 Phosphagrignard Reagents and Related Compounds-- 4 Synthesis of Four-Membered Rings-- 5 Synthesis of Higher Phosphaalkyne Oligomers-- 6 Synthesis of Cluster Compounds-- 7 Conclusions and Outlook-- References-- Organo-Transition Metal Cluster Complexes-- Abbreviations-- 1 Introduction-- 2 General Reviews-- 3 Spectroscopic Studies-- 4 Theory-- 5 Structural Studies-- 6 High-Nuclearity Clusters-- 6.1 Homonuclear High-Nuclearity Clusters-- 6.2 Heteronuclear High-Nuclearity Clusters-- 7 Group 6-- 8 Group 7-- 9 Group 8-- 9.1 Iron-- 9.2 Ruthenium-- 9.3 Osmium-- 9.4 Mixed-Metal Clusters Containing Only Group 8 Metals-- 9.5 Group 8 Clusters in Catalysis-- 10 Group 9-- 10.1 Cobalt-- 10.2 Rhodium-- 10.3 Iridium-- 10.4 Group 9 Mixed-Metal Clusters-- 11 Group 10-- 12 Group 11-- 13 Mixed-Metal Clusters-- 13.1 Group 5-- 13.2 Group 6--
- 13.3 Group 7-- 13.4 Group 8-- 13.5 Group 9-- 13.6 Group 10-- 13.7 Clusters Containing Three Different Metals-- References-- Complexes Containing Metal-Carbon r-Bonds of the Groups Iron, Cobalt and Nickel, Including Carbenes and Carbynes-- 1 Introduction-- 2 Reviews and Articles of General Interest-- 3 Metal-Carbon s-Bonds Involving Group 8, 9 and 10 Metals-- 3.1 The Iron Triad-- 3.2 The Cobalt Triad-- 3.3 The Nickel Triad-- 4 Carbene and Carbyne Complexes of Group 8, 9 and 10-- References-- Organic Aspects of Organometallic Chemistry-- 1 Introduction-- 2 Methods for C--C Bond Formation-- 3 Methods for C--X Bond Formation-- 4 Metal Mediated Cyclisation and Cycloisomerisation Reactions-- 5 Nicholas and Pauson-Khand Type Reactions-- References--
This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry
Beschreibung:1 Online-Ressource (332 p.)
ISBN:184755850X
9781847558503

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