Determination of complex reaction mechanisms: analysis of chemical, biological, and genetic networks
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Oxford
Oxford University Press
2006
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| Schlagworte: | |
| Online-Zugang: | FAW01 FAW02 Volltext |
| Beschreibung: | Includes bibliographical references and index In a chemical system with many chemical species several questions can be asked: what species react with other species: in what temporal order: and with what results? These questions have been asked for over one hundred years about simple and complex chemical systems, and the answers constitute the macroscopic reaction mechanism. In "Determination of Complex Reaction Mechanisms", authors John Ross, Igor Schreiber, and Marcel Vlad present several systematic approaches for obtaining information on the causal connectivity of chemical species, on correlations of chemical species, on the reaction pathway, and on the reaction mechanism. Basic pulse theory is demonstrated and tested in an experiment on glycolysis. In a second approach, measurements on time series of concentrations are used to construct correlation functions and a theory is developed which shows that from these functions information may be inferred on the reaction pathway, the reaction mechanism, and the centers of control in that mechanism.; A third approach is based on application of genetic algorithm methods to the study of the evolutionary development of a reaction mechanism, to the attainment given goals in a mechanism, and to the determination of a reaction mechanism and rate coefficients by comparison with experiment. Responses of non-linear systems to pulses or other perturbations are analyzed, and mechanisms of oscillatory reactions are presented in detail. The concluding chapters give an introduction to bioinformatics and statistical methods for determining reaction mechanisms |
| Beschreibung: | 1 Online-Ressource (ix, 226 pages, [2] pages of plates) |
| ISBN: | 1280428414 1423734882 9781280428418 9781423734888 |
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Datensatz im Suchindex
| _version_ | 1804175481872842752 |
|---|---|
| any_adam_object | |
| author | Ross, John |
| author_facet | Ross, John |
| author_role | aut |
| author_sort | Ross, John |
| author_variant | j r jr |
| building | Verbundindex |
| bvnumber | BV043085741 |
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| dewey-full | 541/.394 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541/.394 |
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| discipline | Chemie / Pharmazie |
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| id | DE-604.BV043085741 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T07:16:59Z |
| institution | BVB |
| isbn | 1280428414 1423734882 9781280428418 9781423734888 |
| language | English |
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| spelling | Ross, John Verfasser aut Determination of complex reaction mechanisms analysis of chemical, biological, and genetic networks John Ross, Igor Schreiber, Marcel O. Vlad ; with contributions from Adam Arkin, Peter J. Oefner and Nicola Zamboni Oxford Oxford University Press 2006 1 Online-Ressource (ix, 226 pages, [2] pages of plates) txt rdacontent c rdamedia cr rdacarrier Includes bibliographical references and index In a chemical system with many chemical species several questions can be asked: what species react with other species: in what temporal order: and with what results? These questions have been asked for over one hundred years about simple and complex chemical systems, and the answers constitute the macroscopic reaction mechanism. In "Determination of Complex Reaction Mechanisms", authors John Ross, Igor Schreiber, and Marcel Vlad present several systematic approaches for obtaining information on the causal connectivity of chemical species, on correlations of chemical species, on the reaction pathway, and on the reaction mechanism. Basic pulse theory is demonstrated and tested in an experiment on glycolysis. In a second approach, measurements on time series of concentrations are used to construct correlation functions and a theory is developed which shows that from these functions information may be inferred on the reaction pathway, the reaction mechanism, and the centers of control in that mechanism.; A third approach is based on application of genetic algorithm methods to the study of the evolutionary development of a reaction mechanism, to the attainment given goals in a mechanism, and to the determination of a reaction mechanism and rate coefficients by comparison with experiment. Responses of non-linear systems to pulses or other perturbations are analyzed, and mechanisms of oscillatory reactions are presented in detail. The concluding chapters give an introduction to bioinformatics and statistical methods for determining reaction mechanisms SCIENCE / Chemistry / Physical & Theoretical bisacsh Chemical kinetics fast Chemical reaction, Conditions and laws of fast Reaction mechanisms (Chemistry) fast Chemie Chemical kinetics Reaction mechanisms (Chemistry) Chemical reaction, Conditions and laws of Experiment (DE-588)4015999-1 gnd rswk-swf Reaktionsmechanismus (DE-588)4177123-0 gnd rswk-swf Reaktionskinetik (DE-588)4048655-2 gnd rswk-swf Reaktionskinetik (DE-588)4048655-2 s Reaktionsmechanismus (DE-588)4177123-0 s Experiment (DE-588)4015999-1 s 1\p DE-604 Schreiber, Igor Sonstige oth Vlad, Marcel O. Sonstige oth Erscheint auch als Druck-Ausgabe, Hardcover 0-19-517868-8 Erscheint auch als Druck-Ausgabe, Hardcover 978-0-19-517868-5 http://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&db=nlabk&AN=143333 Aggregator Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Ross, John Determination of complex reaction mechanisms analysis of chemical, biological, and genetic networks SCIENCE / Chemistry / Physical & Theoretical bisacsh Chemical kinetics fast Chemical reaction, Conditions and laws of fast Reaction mechanisms (Chemistry) fast Chemie Chemical kinetics Reaction mechanisms (Chemistry) Chemical reaction, Conditions and laws of Experiment (DE-588)4015999-1 gnd Reaktionsmechanismus (DE-588)4177123-0 gnd Reaktionskinetik (DE-588)4048655-2 gnd |
| subject_GND | (DE-588)4015999-1 (DE-588)4177123-0 (DE-588)4048655-2 |
| title | Determination of complex reaction mechanisms analysis of chemical, biological, and genetic networks |
| title_auth | Determination of complex reaction mechanisms analysis of chemical, biological, and genetic networks |
| title_exact_search | Determination of complex reaction mechanisms analysis of chemical, biological, and genetic networks |
| title_full | Determination of complex reaction mechanisms analysis of chemical, biological, and genetic networks John Ross, Igor Schreiber, Marcel O. Vlad ; with contributions from Adam Arkin, Peter J. Oefner and Nicola Zamboni |
| title_fullStr | Determination of complex reaction mechanisms analysis of chemical, biological, and genetic networks John Ross, Igor Schreiber, Marcel O. Vlad ; with contributions from Adam Arkin, Peter J. Oefner and Nicola Zamboni |
| title_full_unstemmed | Determination of complex reaction mechanisms analysis of chemical, biological, and genetic networks John Ross, Igor Schreiber, Marcel O. Vlad ; with contributions from Adam Arkin, Peter J. Oefner and Nicola Zamboni |
| title_short | Determination of complex reaction mechanisms |
| title_sort | determination of complex reaction mechanisms analysis of chemical biological and genetic networks |
| title_sub | analysis of chemical, biological, and genetic networks |
| topic | SCIENCE / Chemistry / Physical & Theoretical bisacsh Chemical kinetics fast Chemical reaction, Conditions and laws of fast Reaction mechanisms (Chemistry) fast Chemie Chemical kinetics Reaction mechanisms (Chemistry) Chemical reaction, Conditions and laws of Experiment (DE-588)4015999-1 gnd Reaktionsmechanismus (DE-588)4177123-0 gnd Reaktionskinetik (DE-588)4048655-2 gnd |
| topic_facet | SCIENCE / Chemistry / Physical & Theoretical Chemical kinetics Chemical reaction, Conditions and laws of Reaction mechanisms (Chemistry) Chemie Experiment Reaktionsmechanismus Reaktionskinetik |
| url | http://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&db=nlabk&AN=143333 |
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