Fundamentals of Polymerization:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Singapore
World Scientific
2012
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| Schlagworte: | |
| Online-Zugang: | FAW01 FAW02 Volltext |
| Beschreibung: | Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and di Includes bibliographical references and index Ch. 1. Introduction. 1.1. Nomenclature. 1.2. Structural and repeating (or repeat) units. 1.3. Classification. 1.4. Functionality. 1.5. Designed branched polymers. 1.6. Physical state. 1.7. Structure-property relationship. 1.8. Thermodynamics of polymerization. 1.9. Polymerizability of internal olefins. 1.10. Molecular weights and molecular weight distributions -- ch. 2. Step polymerization. 2.1. Principle of equal reactivity of functional groups and kinetics of polymerization. 2.2. Ring vs. chain formation. 2.3. Intermolecular interchange reactions. 2.4. Degree of polymerization. 2.5. Molecular weight distribution. 2.6. Prediction of gel point in polyfunctional polycondensation. 2.7. Thermosetting resins. 2.8. Engineering plastics. 2.9. High performance polymers. 2.10. Nonconventional step polymerization -- - ch. 3. Radical polymerization. 3.1. General features. 3.2. Kinetics of homogeneous radical polymerization. 3.3. Reaction orders in initiator and monomer. 3.4. Initiators. 3.5. Determination of polymer end groups. 3.6. Initiator efficiency. 3.7. Thermal polymerization and its kinetics. 3.8. Kinetic chain length, degree of polymerization, and chain transfer. 3.9. Inhibition and retardation of polymerization. 3.10. Rate constants of propagation and termination. 3.11. The course of polymerization and gel effect. 3.12. Popcorn polymerization. 3.13. Dead end polymerization. 3.14. Molecular weight distribution. 3.15. Living radical polymerization (LRP) -- ch. 4. Anionic polymerization. 4.1. Living anionic polymerization -- ch. 5. Coordination polymerization. 5.1. Ziegler-Natta catalysts. 5.2. Metallocene catalysts. 5.3. Late transition metal catalysts. 5.4. Living polymerization of alkenes -- - ch. 6. Cationic polymerization. 6.1. The nucleophilicity and electrophilicity scales. 6.2. Bronsted acids as initiators. 6.3. Lewis acids as coinitiators. 6.4. End functionalized polymers. 6.5. Photoinitiated cationic polymerization. 6.6. Propagation rate constants -- ch. 7. Ring-opening polymerization and ring-opening metathesis polymerization. 7.1. General features. 7.2. Cyclic ethers. 7.3. Cyclic acetals. 7.4. Cyclic esters. 7.5. Lactams. 7.6. N-carboxy-[symbol]-aminoacid anhydrides. 7.7. Oxazolines (cyclic imino ethers). 7.8. Cyclic amines. 7.9. Cyclic sulfides. 7.10. Cyclosiloxanes. 7.11. Cyclotriphosphazenes. 7.12. Cyclic olefins -- ch. 8. Chain copolymerization. 8.1. Terminal model of copolymerization. 8.2. Penultimate model of copolymerization. 8.3. Living radical copolymerization -- - ch. 9. Heterophase polymerization. 9.1. Particle stabilization mechanisms. 9.2. Suspension polymerization. 9.3. Emulsion polymerization. 9.4. Inverse emulsion polymerization. 9.5. Miniemulsion polymerization. 9.6. Microemulsion polymerization. 9.7. Dispersion polymerization. 9.8. Heterophase living radical polymerization |
| Beschreibung: | 1 Online-Ressource (468 pages) |
| ISBN: | 1283899957 9781283899956 9789814322461 9789814322850 9814322466 9814322857 |
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| 500 | |a Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and di | ||
| 500 | |a Includes bibliographical references and index | ||
| 500 | |a Ch. 1. Introduction. 1.1. Nomenclature. 1.2. Structural and repeating (or repeat) units. 1.3. Classification. 1.4. Functionality. 1.5. Designed branched polymers. 1.6. Physical state. 1.7. Structure-property relationship. 1.8. Thermodynamics of polymerization. 1.9. Polymerizability of internal olefins. 1.10. Molecular weights and molecular weight distributions -- ch. 2. Step polymerization. 2.1. Principle of equal reactivity of functional groups and kinetics of polymerization. 2.2. Ring vs. chain formation. 2.3. Intermolecular interchange reactions. 2.4. Degree of polymerization. 2.5. Molecular weight distribution. 2.6. Prediction of gel point in polyfunctional polycondensation. 2.7. Thermosetting resins. 2.8. Engineering plastics. 2.9. High performance polymers. 2.10. Nonconventional step polymerization -- | ||
| 500 | |a - ch. 3. Radical polymerization. 3.1. General features. 3.2. Kinetics of homogeneous radical polymerization. 3.3. Reaction orders in initiator and monomer. 3.4. Initiators. 3.5. Determination of polymer end groups. 3.6. Initiator efficiency. 3.7. Thermal polymerization and its kinetics. 3.8. Kinetic chain length, degree of polymerization, and chain transfer. 3.9. Inhibition and retardation of polymerization. 3.10. Rate constants of propagation and termination. 3.11. The course of polymerization and gel effect. 3.12. Popcorn polymerization. 3.13. Dead end polymerization. 3.14. Molecular weight distribution. 3.15. Living radical polymerization (LRP) -- ch. 4. Anionic polymerization. 4.1. Living anionic polymerization -- ch. 5. Coordination polymerization. 5.1. Ziegler-Natta catalysts. 5.2. Metallocene catalysts. 5.3. Late transition metal catalysts. 5.4. Living polymerization of alkenes -- | ||
| 500 | |a - ch. 6. Cationic polymerization. 6.1. The nucleophilicity and electrophilicity scales. 6.2. Bronsted acids as initiators. 6.3. Lewis acids as coinitiators. 6.4. End functionalized polymers. 6.5. Photoinitiated cationic polymerization. 6.6. Propagation rate constants -- ch. 7. Ring-opening polymerization and ring-opening metathesis polymerization. 7.1. General features. 7.2. Cyclic ethers. 7.3. Cyclic acetals. 7.4. Cyclic esters. 7.5. Lactams. 7.6. N-carboxy-[symbol]-aminoacid anhydrides. 7.7. Oxazolines (cyclic imino ethers). 7.8. Cyclic amines. 7.9. Cyclic sulfides. 7.10. Cyclosiloxanes. 7.11. Cyclotriphosphazenes. 7.12. Cyclic olefins -- ch. 8. Chain copolymerization. 8.1. Terminal model of copolymerization. 8.2. Penultimate model of copolymerization. 8.3. Living radical copolymerization -- | ||
| 500 | |a - ch. 9. Heterophase polymerization. 9.1. Particle stabilization mechanisms. 9.2. Suspension polymerization. 9.3. Emulsion polymerization. 9.4. Inverse emulsion polymerization. 9.5. Miniemulsion polymerization. 9.6. Microemulsion polymerization. 9.7. Dispersion polymerization. 9.8. Heterophase living radical polymerization | ||
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| 650 | 0 | 7 | |a Polymerisation |0 (DE-588)4046704-1 |2 gnd |9 rswk-swf |
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Datensatz im Suchindex
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|---|---|
| any_adam_object | |
| author | Mandal, Broja Mohan |
| author_facet | Mandal, Broja Mohan |
| author_role | aut |
| author_sort | Mandal, Broja Mohan |
| author_variant | b m m bm bmm |
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| bvnumber | BV043082249 |
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| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.28 |
| dewey-search | 547.28 |
| dewey-sort | 3547.28 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Electronic eBook |
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| id | DE-604.BV043082249 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T07:16:53Z |
| institution | BVB |
| isbn | 1283899957 9781283899956 9789814322461 9789814322850 9814322466 9814322857 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-028506441 |
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| physical | 1 Online-Ressource (468 pages) |
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| spelling | Mandal, Broja Mohan Verfasser aut Fundamentals of Polymerization Singapore World Scientific 2012 1 Online-Ressource (468 pages) txt rdacontent c rdamedia cr rdacarrier Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and di Includes bibliographical references and index Ch. 1. Introduction. 1.1. Nomenclature. 1.2. Structural and repeating (or repeat) units. 1.3. Classification. 1.4. Functionality. 1.5. Designed branched polymers. 1.6. Physical state. 1.7. Structure-property relationship. 1.8. Thermodynamics of polymerization. 1.9. Polymerizability of internal olefins. 1.10. Molecular weights and molecular weight distributions -- ch. 2. Step polymerization. 2.1. Principle of equal reactivity of functional groups and kinetics of polymerization. 2.2. Ring vs. chain formation. 2.3. Intermolecular interchange reactions. 2.4. Degree of polymerization. 2.5. Molecular weight distribution. 2.6. Prediction of gel point in polyfunctional polycondensation. 2.7. Thermosetting resins. 2.8. Engineering plastics. 2.9. High performance polymers. 2.10. Nonconventional step polymerization -- - ch. 3. Radical polymerization. 3.1. General features. 3.2. Kinetics of homogeneous radical polymerization. 3.3. Reaction orders in initiator and monomer. 3.4. Initiators. 3.5. Determination of polymer end groups. 3.6. Initiator efficiency. 3.7. Thermal polymerization and its kinetics. 3.8. Kinetic chain length, degree of polymerization, and chain transfer. 3.9. Inhibition and retardation of polymerization. 3.10. Rate constants of propagation and termination. 3.11. The course of polymerization and gel effect. 3.12. Popcorn polymerization. 3.13. Dead end polymerization. 3.14. Molecular weight distribution. 3.15. Living radical polymerization (LRP) -- ch. 4. Anionic polymerization. 4.1. Living anionic polymerization -- ch. 5. Coordination polymerization. 5.1. Ziegler-Natta catalysts. 5.2. Metallocene catalysts. 5.3. Late transition metal catalysts. 5.4. Living polymerization of alkenes -- - ch. 6. Cationic polymerization. 6.1. The nucleophilicity and electrophilicity scales. 6.2. Bronsted acids as initiators. 6.3. Lewis acids as coinitiators. 6.4. End functionalized polymers. 6.5. Photoinitiated cationic polymerization. 6.6. Propagation rate constants -- ch. 7. Ring-opening polymerization and ring-opening metathesis polymerization. 7.1. General features. 7.2. Cyclic ethers. 7.3. Cyclic acetals. 7.4. Cyclic esters. 7.5. Lactams. 7.6. N-carboxy-[symbol]-aminoacid anhydrides. 7.7. Oxazolines (cyclic imino ethers). 7.8. Cyclic amines. 7.9. Cyclic sulfides. 7.10. Cyclosiloxanes. 7.11. Cyclotriphosphazenes. 7.12. Cyclic olefins -- ch. 8. Chain copolymerization. 8.1. Terminal model of copolymerization. 8.2. Penultimate model of copolymerization. 8.3. Living radical copolymerization -- - ch. 9. Heterophase polymerization. 9.1. Particle stabilization mechanisms. 9.2. Suspension polymerization. 9.3. Emulsion polymerization. 9.4. Inverse emulsion polymerization. 9.5. Miniemulsion polymerization. 9.6. Microemulsion polymerization. 9.7. Dispersion polymerization. 9.8. Heterophase living radical polymerization Polymerization Polymers SCIENCE / Chemistry / Organic bisacsh Polymerization fast Chemie Polymerisation (DE-588)4046704-1 gnd rswk-swf Polymerisation (DE-588)4046704-1 s 1\p DE-604 http://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&db=nlabk&AN=516994 Aggregator Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Mandal, Broja Mohan Fundamentals of Polymerization Polymerization Polymers SCIENCE / Chemistry / Organic bisacsh Polymerization fast Chemie Polymerisation (DE-588)4046704-1 gnd |
| subject_GND | (DE-588)4046704-1 |
| title | Fundamentals of Polymerization |
| title_auth | Fundamentals of Polymerization |
| title_exact_search | Fundamentals of Polymerization |
| title_full | Fundamentals of Polymerization |
| title_fullStr | Fundamentals of Polymerization |
| title_full_unstemmed | Fundamentals of Polymerization |
| title_short | Fundamentals of Polymerization |
| title_sort | fundamentals of polymerization |
| topic | Polymerization Polymers SCIENCE / Chemistry / Organic bisacsh Polymerization fast Chemie Polymerisation (DE-588)4046704-1 gnd |
| topic_facet | Polymerization Polymers SCIENCE / Chemistry / Organic Chemie Polymerisation |
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| work_keys_str_mv | AT mandalbrojamohan fundamentalsofpolymerization |