P-stereogenic ligands in enantioselective catalysis:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Cambridge
Royal Society of Chemistry
c2011
|
| Schriftenreihe: | RSC catalysis series
|
| Schlagworte: | |
| Online-Zugang: | FAW01 FAW02 Volltext |
| Beschreibung: | P-stereogenic ligands were among the first to be used in asymmetric catalysis but synthetic difficulties and prejudices have hampered their development. However, continuous screening for new chiral ligands means that they can no longer be ignored and this rigorous reference source reflects their renaissance.The book is filled with many examples from recent primary literature. The synthetic chemist will easily be able to follow the preparation methods which are accompanied by a description of the challenges and limitations. Those working in homogenous catalysis, and wanting to increase their repertoire of ligands, will be able to establish which have already been used in each reaction and their performance.This book provides comprehensive coverage of the application of P-stereogenic ligands in homogeneous catalysis. It begins with a brief chapter on generalities of P-stereogenic compounds: history, configurational stability, and interconversions among them.The book then goes on to describe the main preparative methods, from resolution of racemates to enantioselective catalysis, before focusing on the catalytic applications of P-stereogenic ligands. Chapter 7 describes the use of the ligands in catalytic hydrogenation and related reactions whereas chapter 8 deals with other reactions, mainly C-C bond forming reactions. The aim of these two final chapters is to give an outline of the usefulness of the ligands in homogeneous catalysis Introduction -- Resolution of racemic and diastereomeric mixtures -- P-stereogenic heterocycles -- P-stereogenic compounds derived from enantiopure heterocycles -- P-stereogenic phosphines prepared by enantioselective deprotonation -- Prepared by enantioselective catalysis -- Hydrogenation and related reactions -- Miscellaneous reactions |
| Beschreibung: | 1 Online-Ressource (xvii, 501 p.) |
| ISBN: | 1849731233 1849732701 9781849731232 9781849732703 |
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| 500 | |a P-stereogenic ligands were among the first to be used in asymmetric catalysis but synthetic difficulties and prejudices have hampered their development. However, continuous screening for new chiral ligands means that they can no longer be ignored and this rigorous reference source reflects their renaissance.The book is filled with many examples from recent primary literature. The synthetic chemist will easily be able to follow the preparation methods which are accompanied by a description of the challenges and limitations. Those working in homogenous catalysis, and wanting to increase their repertoire of ligands, will be able to establish which have already been used in each reaction and their performance.This book provides comprehensive coverage of the application of P-stereogenic ligands in homogeneous catalysis. It begins with a brief chapter on generalities of P-stereogenic compounds: history, configurational stability, and interconversions among them.The book then goes on to describe the main preparative methods, from resolution of racemates to enantioselective catalysis, before focusing on the catalytic applications of P-stereogenic ligands. Chapter 7 describes the use of the ligands in catalytic hydrogenation and related reactions whereas chapter 8 deals with other reactions, mainly C-C bond forming reactions. The aim of these two final chapters is to give an outline of the usefulness of the ligands in homogeneous catalysis | ||
| 500 | |a Introduction -- Resolution of racemic and diastereomeric mixtures -- P-stereogenic heterocycles -- P-stereogenic compounds derived from enantiopure heterocycles -- P-stereogenic phosphines prepared by enantioselective deprotonation -- Prepared by enantioselective catalysis -- Hydrogenation and related reactions -- Miscellaneous reactions | ||
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Datensatz im Suchindex
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| author | Grabulosa, Arnald |
| author_facet | Grabulosa, Arnald |
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| building | Verbundindex |
| bvnumber | BV043064064 |
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| dewey-full | 547.12242 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.12242 |
| dewey-search | 547.12242 |
| dewey-sort | 3547.12242 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Electronic eBook |
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| id | DE-604.BV043064064 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T07:16:20Z |
| institution | BVB |
| isbn | 1849731233 1849732701 9781849731232 9781849732703 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-028488256 |
| oclc_num | 745906584 |
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| owner_facet | DE-1046 DE-1047 |
| physical | 1 Online-Ressource (xvii, 501 p.) |
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| publishDate | 2011 |
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| publisher | Royal Society of Chemistry |
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| series2 | RSC catalysis series |
| spelling | Grabulosa, Arnald Verfasser aut P-stereogenic ligands in enantioselective catalysis Arnald Grabulosa Cambridge Royal Society of Chemistry c2011 1 Online-Ressource (xvii, 501 p.) txt rdacontent c rdamedia cr rdacarrier RSC catalysis series P-stereogenic ligands were among the first to be used in asymmetric catalysis but synthetic difficulties and prejudices have hampered their development. However, continuous screening for new chiral ligands means that they can no longer be ignored and this rigorous reference source reflects their renaissance.The book is filled with many examples from recent primary literature. The synthetic chemist will easily be able to follow the preparation methods which are accompanied by a description of the challenges and limitations. Those working in homogenous catalysis, and wanting to increase their repertoire of ligands, will be able to establish which have already been used in each reaction and their performance.This book provides comprehensive coverage of the application of P-stereogenic ligands in homogeneous catalysis. It begins with a brief chapter on generalities of P-stereogenic compounds: history, configurational stability, and interconversions among them.The book then goes on to describe the main preparative methods, from resolution of racemates to enantioselective catalysis, before focusing on the catalytic applications of P-stereogenic ligands. Chapter 7 describes the use of the ligands in catalytic hydrogenation and related reactions whereas chapter 8 deals with other reactions, mainly C-C bond forming reactions. The aim of these two final chapters is to give an outline of the usefulness of the ligands in homogeneous catalysis Introduction -- Resolution of racemic and diastereomeric mixtures -- P-stereogenic heterocycles -- P-stereogenic compounds derived from enantiopure heterocycles -- P-stereogenic phosphines prepared by enantioselective deprotonation -- Prepared by enantioselective catalysis -- Hydrogenation and related reactions -- Miscellaneous reactions SCIENCE / Chemistry / Organic bisacsh Enantioselective catalysis fast Ligands fast Chemie Ligands Enantioselective catalysis Asymmetrische Synthese (DE-588)4135603-2 gnd rswk-swf Phosphorverbindungen (DE-588)4174454-8 gnd rswk-swf Phosphorverbindungen (DE-588)4174454-8 s Asymmetrische Synthese (DE-588)4135603-2 s 1\p DE-604 http://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&db=nlabk&AN=519335 Aggregator Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Grabulosa, Arnald P-stereogenic ligands in enantioselective catalysis SCIENCE / Chemistry / Organic bisacsh Enantioselective catalysis fast Ligands fast Chemie Ligands Enantioselective catalysis Asymmetrische Synthese (DE-588)4135603-2 gnd Phosphorverbindungen (DE-588)4174454-8 gnd |
| subject_GND | (DE-588)4135603-2 (DE-588)4174454-8 |
| title | P-stereogenic ligands in enantioselective catalysis |
| title_auth | P-stereogenic ligands in enantioselective catalysis |
| title_exact_search | P-stereogenic ligands in enantioselective catalysis |
| title_full | P-stereogenic ligands in enantioselective catalysis Arnald Grabulosa |
| title_fullStr | P-stereogenic ligands in enantioselective catalysis Arnald Grabulosa |
| title_full_unstemmed | P-stereogenic ligands in enantioselective catalysis Arnald Grabulosa |
| title_short | P-stereogenic ligands in enantioselective catalysis |
| title_sort | p stereogenic ligands in enantioselective catalysis |
| topic | SCIENCE / Chemistry / Organic bisacsh Enantioselective catalysis fast Ligands fast Chemie Ligands Enantioselective catalysis Asymmetrische Synthese (DE-588)4135603-2 gnd Phosphorverbindungen (DE-588)4174454-8 gnd |
| topic_facet | SCIENCE / Chemistry / Organic Enantioselective catalysis Ligands Chemie Asymmetrische Synthese Phosphorverbindungen |
| url | http://search.ebscohost.com/login.aspx?direct=true&scope=site&db=nlebk&db=nlabk&AN=519335 |
| work_keys_str_mv | AT grabulosaarnald pstereogenicligandsinenantioselectivecatalysis |