Microstructured reactors with integrated metallic membranes for on-site production of pure hydrogen:
Gespeichert in:
1. Verfasser: | |
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Format: | Abschlussarbeit Buch |
Sprache: | English |
Veröffentlicht: |
Berlin
mbv
2015
|
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis Inhaltsverzeichnis |
Beschreibung: | xviii, 254 Seiten Ill., graph. Darst. 21 cm |
ISBN: | 9783863876098 3863876091 |
Internformat
MARC
LEADER | 00000nam a2200000 c 4500 | ||
---|---|---|---|
001 | BV043051955 | ||
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035 | |a (OCoLC)936762860 | ||
035 | |a (DE-599)DNB1077269781 | ||
040 | |a DE-604 |b ger |e rda | ||
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100 | 1 | |a Böltken, Tim |d 1985- |e Verfasser |0 (DE-588)1074776879 |4 aut | |
245 | 1 | 0 | |a Microstructured reactors with integrated metallic membranes for on-site production of pure hydrogen |c von Tim Böltken |
264 | 1 | |a Berlin |b mbv |c 2015 | |
300 | |a xviii, 254 Seiten |b Ill., graph. Darst. |c 21 cm | ||
336 | |b txt |2 rdacontent | ||
337 | |b n |2 rdamedia | ||
338 | |b nc |2 rdacarrier | ||
502 | |b Dissertation |c Karlsruher Institut für Technologie, Karlsruhe |d 2015 | ||
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650 | 0 | 7 | |a Membranreaktor |0 (DE-588)4555095-5 |2 gnd |9 rswk-swf |
650 | 0 | 7 | |a Mikroreaktor |0 (DE-588)4786310-9 |2 gnd |9 rswk-swf |
650 | 0 | 7 | |a Katalysator |0 (DE-588)4029919-3 |2 gnd |9 rswk-swf |
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650 | 0 | 7 | |a Poröse Membran |0 (DE-588)4237727-4 |2 gnd |9 rswk-swf |
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689 | 0 | 1 | |a Membran |g Verfahrenstechnik |0 (DE-588)7749014-9 |D s |
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689 | 0 | 5 | |a Katalysator |0 (DE-588)4029919-3 |D s |
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Datensatz im Suchindex
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adam_text |
TABLE OF CONTENTS
ABSTRACT III
KURZFASSUNG VII
DANKSAGUNG XI
1 INTRODUCTION 1
2 FUNDAMENTALS OF CATALYTIC STEAM REFORMING OF NATURAL GAS FOR
HYDROGEN PRODUCTION 5
2.1 CHEMICAL REACTIONS AND THERMODYNAMICS 5
2.2 CATALYSTS AND REACTION KINETICS 9
2.3 INDUSTRIAL (CENTRALIZED) HYDROGEN PRODUCTION AND PURIFICATI
ON PROCESSES 16
3 CONCEPTS FOR DISTRIBUTED HYDROGEN PRODUCTION 21
3.1 SMALL-SCALE REFORMER UNITS 21
3.2 PALLADIUM-BASED MEMBRANES FOR HYDROGEN SEPARATION . 23
3.2.1 TERMINOLOGY 23
3.2.2 THE PALLADIUM-HYDROGEN SYSTEM 24
3.2.3 SOLUTION-DIFFUSION MECHANISM 26
3.3 MEMBRANE REACTORS FOR ON-SITE HYDROGEN PRODUCTION . 29
3.3.1 STATE-OF-THE-ART 32
3.3.2 LABORATORY SCALE 38
3.3.3 NEW MEMBRANE REACTOR CONCEPTS 43
3.4 GOALS OF THIS PROJECT 51
4 CATALYST PREPARATION AND TESTING FOR METHANE STEAM REFORMING
AND WATER GAS SHIFT 55
4.1 LITERATURE OVERVIEW 55
4.2 EXPERIMENTAL SET-UP AND GAS ANALYSIS 58
XV
HTTP://D-NB.INFO/1077269781
TABLE OF CONTENTS
4.2.1 TEST RIG 58
4.2.2 GAS CHROMATOGRAPHY 60
4.2.3 MICROSTRUCTURED REACTOR 60
4.2.4 MICROSTRUCTURED FOILS 61
4.3 PREPARATION OF CATALYTIC WALL COATINGS FOR MICROCHANNELS . . 62
4.3.1 MANUAL IMPREGNATION 63
4.3.2 INKJET PRINTING OF CATALYST LAYERS 63
4.4 CATALYST CHARACTERIZATION TECHNIQUES 65
4.4.1 ELECTRON PROBE MICROANALYZER 65
4.4.2 TRANSMISSION ELECTRON MICROSCOPY 65
4.4.3 PHYSI- AND CHEMISORPTION 65
4.4.4 DEFINITIONS 67
4.5 RESULTS OF CATALYST CHARACTERIZATION 68
4.5.1 CATALYST LAYER MORPHOLOGY 69
4.5.2 PORE STRUCTURE 71
4.5.3 ACTIVE SURFACE AREA 76
4.6 ACTIVITY TESTS 80
4.6.1 COMMENTS REGARDING THE CATALYTIC ACTIVITY DURING
START-UP 81
4.6.2 REACTION EXPERIMENTS WITH THE INKJET PRINTED CATA
LYSTS CIP 84
4.6.3 REACTION EXPERIMENTS WITH THE MANUALLY COATED CA
TALYST CM 86
4.7 KINETIC MODELING 88
4.7.1 REGRESSION METHOD FOR PARAMETER ESTIMATION . 92
4.7.2 RESULTS OF PARAMETER ESTIMATION 95
4.8 SUMMARY AND CONCLUSIONS 100
5 PREPARATION AND TESTING OF PLANAR PALLADIUM (COMPOSITE) MEM
BRANES 103
5.1 CHARACTERIZATION OF POROUS MEMBRANE SUPPORTS 106
5.2 EXPERIMENTAL SETUP FOR NITROGEN AND HYDROGEN PERMEATION
EXPERIMENTS 111
5.3 ELECTROLESS PLATING OF PALLADIUM 113
5.3.1 EXPERIMENTAL 114
5.3.2 ANALYSIS OF PD MEMBRANES PREPARED BY ELECTROLESS
PLATING 116
5.3.3 RESULTS OF N
2
AND H
2
PERMEATION EXPERIMENTS . 117
XVI
TABLE OF CONTENTS
5.4 SUSPENSION PLASMA SPAYING (SPS) OF PALLADIUM NANOPAR-
TICLES 122
5.4.1 EXPERIMENTAL 123
5.4.2 RESULTS OF THERMAL SPRAYING TESTS OF PD SUSPENSION 124
5.4.3 ANALYSIS OF PD MEMBRANES PREPARED BY SUSPENSI
ON PLASMA SPRAYING 127
5.4.4 NITROGEN AND HYDROGEN PERMEATION OF PD MEMBRA
NES PREPARED BY SPS 130
5.5 SUMMARY AND CONCLUDING REMARKS 134
6 PROTOTYPE MICROCHANNEL MEMBRANE MODULE 137
6.1 PALLADIUM FOILS PREPARED BY MAGNETRON SPUTTERING AND COLD
ROLLING 137
6.2 MEMBRANE INTEGRATION BY LASER WELDING 139
6.3 MICROCHANNEL PROTOTYPE CONCEPT MODULE 142
6.4 SINGLE GAS PERMEATION EXPERIMENTS 149
6.5 THE CONCEPT OF THE FILM EFFECTIVENESS FACTOR 157
6.6 HYDROGEN SEPARATION FROM GAS MIXTURES 162
6.7 SUMMARY AND CONCLUSIONS 167
7 PROTOTYPE MICROCHANNEL MEMBRANE REACTOR 169
7.1 DESIGN OF THE ^-EN//
2
ANCER 169
7.2 TEST RIG, REACTION CONDITIONS AND DEFINITIONS 171
7.3 RESULTS 174
7.3.1 MEMBRANE INTEGRATION 174
7.3.2 EXPERIMENTAL RESULTS ON METHANE STEAM REFORMING . 176
7.3.3 COMPARISON TO MEMBRANE REACTOR PERFORMANCE RE
PORTED IN LITERATURE 181
7.3.4 SCALE UP AND SYSTEM DESIGN 185
8 SUMMARY AND CONCLUSIONS 193
A APPENDIX 197
A.1 THERMODYNAMIC ANALYSIS 197
A.2 MEMBRANE CLASSIFICATIONS 199
A.3 OVERVIEW OF LABORATORY-SCALE TUBULAR MEMBRANE REACTORS . 201
A.4 GAS CHROMATOGRAPHY 203
A.5 ESTIMATION OF HEAT AND MASS TRANSPORT LIMITATIONS 204
XVII
TABLE OF CONTENTS
A.5.1 EXTERNAL MASS TRANSPORT LIMITATION 204
A.5.2 INTERNAL MASS TRANSPORT LIMITATION 207
A.5.3 EXTERNAL AND INTERNAL HEAT TRANSPORT 209
A.6 CORRELATION FOR KINETIC MODEL JAKOBSEN AND CATALYST CM . . 211
A.7 IMPROVED SEALING CONCEPT FOR PLANAR COMPOSITE PD MEM
BRANES 213
LITERATURVERZEICHNIS 229
XVIII |
any_adam_object | 1 |
author | Böltken, Tim 1985- |
author_GND | (DE-588)1074776879 |
author_facet | Böltken, Tim 1985- |
author_role | aut |
author_sort | Böltken, Tim 1985- |
author_variant | t b tb |
building | Verbundindex |
bvnumber | BV043051955 |
ctrlnum | (OCoLC)936762860 (DE-599)DNB1077269781 |
dewey-full | 660.2832 |
dewey-hundreds | 600 - Technology (Applied sciences) |
dewey-ones | 660 - Chemical engineering |
dewey-raw | 660.2832 |
dewey-search | 660.2832 |
dewey-sort | 3660.2832 |
dewey-tens | 660 - Chemical engineering |
discipline | Chemie / Pharmazie |
format | Thesis Book |
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genre_facet | Hochschulschrift |
id | DE-604.BV043051955 |
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indexdate | 2024-10-28T13:01:10Z |
institution | BVB |
isbn | 9783863876098 3863876091 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-028476267 |
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physical | xviii, 254 Seiten Ill., graph. Darst. 21 cm |
publishDate | 2015 |
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spelling | Böltken, Tim 1985- Verfasser (DE-588)1074776879 aut Microstructured reactors with integrated metallic membranes for on-site production of pure hydrogen von Tim Böltken Berlin mbv 2015 xviii, 254 Seiten Ill., graph. Darst. 21 cm txt rdacontent n rdamedia nc rdacarrier Dissertation Karlsruher Institut für Technologie, Karlsruhe 2015 Wasserstofferzeugung (DE-588)4189271-9 gnd rswk-swf Membranreaktor (DE-588)4555095-5 gnd rswk-swf Mikroreaktor (DE-588)4786310-9 gnd rswk-swf Katalysator (DE-588)4029919-3 gnd rswk-swf Palladium (DE-588)4173139-6 gnd rswk-swf Beschichten (DE-588)4005996-0 gnd rswk-swf Membran Verfahrenstechnik (DE-588)7749014-9 gnd rswk-swf Poröse Membran (DE-588)4237727-4 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Mikroreaktor (DE-588)4786310-9 s Membran Verfahrenstechnik (DE-588)7749014-9 s Poröse Membran (DE-588)4237727-4 s Beschichten (DE-588)4005996-0 s Palladium (DE-588)4173139-6 s Katalysator (DE-588)4029919-3 s DE-604 Membranreaktor (DE-588)4555095-5 s Wasserstofferzeugung (DE-588)4189271-9 s B:DE-101 application/pdf http://d-nb.info/1077269781/04 Inhaltsverzeichnis DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028476267&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | Böltken, Tim 1985- Microstructured reactors with integrated metallic membranes for on-site production of pure hydrogen Wasserstofferzeugung (DE-588)4189271-9 gnd Membranreaktor (DE-588)4555095-5 gnd Mikroreaktor (DE-588)4786310-9 gnd Katalysator (DE-588)4029919-3 gnd Palladium (DE-588)4173139-6 gnd Beschichten (DE-588)4005996-0 gnd Membran Verfahrenstechnik (DE-588)7749014-9 gnd Poröse Membran (DE-588)4237727-4 gnd |
subject_GND | (DE-588)4189271-9 (DE-588)4555095-5 (DE-588)4786310-9 (DE-588)4029919-3 (DE-588)4173139-6 (DE-588)4005996-0 (DE-588)7749014-9 (DE-588)4237727-4 (DE-588)4113937-9 |
title | Microstructured reactors with integrated metallic membranes for on-site production of pure hydrogen |
title_auth | Microstructured reactors with integrated metallic membranes for on-site production of pure hydrogen |
title_exact_search | Microstructured reactors with integrated metallic membranes for on-site production of pure hydrogen |
title_full | Microstructured reactors with integrated metallic membranes for on-site production of pure hydrogen von Tim Böltken |
title_fullStr | Microstructured reactors with integrated metallic membranes for on-site production of pure hydrogen von Tim Böltken |
title_full_unstemmed | Microstructured reactors with integrated metallic membranes for on-site production of pure hydrogen von Tim Böltken |
title_short | Microstructured reactors with integrated metallic membranes for on-site production of pure hydrogen |
title_sort | microstructured reactors with integrated metallic membranes for on site production of pure hydrogen |
topic | Wasserstofferzeugung (DE-588)4189271-9 gnd Membranreaktor (DE-588)4555095-5 gnd Mikroreaktor (DE-588)4786310-9 gnd Katalysator (DE-588)4029919-3 gnd Palladium (DE-588)4173139-6 gnd Beschichten (DE-588)4005996-0 gnd Membran Verfahrenstechnik (DE-588)7749014-9 gnd Poröse Membran (DE-588)4237727-4 gnd |
topic_facet | Wasserstofferzeugung Membranreaktor Mikroreaktor Katalysator Palladium Beschichten Membran Verfahrenstechnik Poröse Membran Hochschulschrift |
url | http://d-nb.info/1077269781/04 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028476267&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT boltkentim microstructuredreactorswithintegratedmetallicmembranesforonsiteproductionofpurehydrogen |
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