Photoluminescence of diamondoids: experiment and theory
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin
epubli GmbH
2015
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | X, 187 S. Ill., graph. Darst. |
| ISBN: | 9783737574648 |
Internformat
MARC
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| 100 | 1 | |a Richter, Robert |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Photoluminescence of diamondoids |b experiment and theory |c Robert Richter |
| 264 | 1 | |a Berlin |b epubli GmbH |c 2015 | |
| 300 | |a X, 187 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a Zugl.: Technische Universität Berlin, Diss., 2015 | ||
| 653 | |a gas phase | ||
| 653 | |a spectroscopy | ||
| 653 | |a fluorescence | ||
| 653 | |a Photoluminescence | ||
| 653 | |a vibrational structure | ||
| 653 | |a large molecules | ||
| 653 | |a laser | ||
| 653 | |a Diamondoids | ||
| 653 | |a electronic strucutre | ||
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
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Datensatz im Suchindex
| _version_ | 1809772357156339712 |
|---|---|
| adam_text |
CONTENTS
1 INTRODUCTION 3
2 DIAMONDOIDS 5
2.1 MOLECULAR STRUCTURE 5
2.2 DIAMONDOID RESEARCH 6
2.3 APPLICATIONS 15
3 MOLECULAR SPECTROSCOPY 17
3.1 THE BORN-OPPENHEIMER APPROXIMATION 17
3.2 GROUP THEORETICAL ASPECTS 21
3.3 SPECTRA OF POLYATOMIC MOLECULES 24
3.4 SPECTRAL LINE BROADENING 29
4 EXPERIMENTAL SECTION 33
4.1 LASER SYSTEM 33
4.2 SYNCHROTRON RADIATION SOURCE 40
4.3 EXPERIMENTAL CHAMBER 44
4.4 SAMPLE CELL 46
4.5 FLUORESCENCE SPECTROMETER 49
IX
HTTP://D-NB.INFO/1078456836
4.6 CCD-CAMERA 51
4.7 MEASURING PROCEDURE 53
5 QUANTUM CHEMICAL CALCULATIONS 55
5.1 DENSITY FUNCTIONAL THEORY 56
5.2 TIME-DEPENDENT DENSITY FUNTIONAL THEORY 56
5.3 FUNCTIONAL 57
5.4 BASIS SETS 59
5.5 CALCULATION OF VIBRATIONALLY RESOLVED ELECTRONIC SPECTRA . 60
6 THERMOCHEMICAL CALCULATIONS 67
6.1 THERMODYNAMIC QUANTITIES OF MOLECULES 68
6.2 TYANSLATIONAL CONTRIBUTIONS 69
6.3 ELECTRONIC CONTRIBUTIONS 70
6.4 VIBRATIONAL CONTRIBUTIONS 71
6.5 ROTATIONAL CONTRIBUTIONS 73
7 RESULTS AND DISCUSSION I: PHOTOLUMINESCENCE 75
7.1 OVERVIEW OF PHOTOLUMINESCENCE SPECTRA 76
7.2 SIZE EFFECTS AND COMPOSITION OF THE VIBRATIONAL SPECTRA . 91
7.3 DETERMINATION OF THE OPTICALLY ACTIVE MODES 98
7.4 GEOMETRICAL EFFECTS 104
7.5 HERZBERG-TELLER COUPLING 112
8 RESULTS AND DISCUSSION II: THERMO-OPTICAL EFFECTS 119
8.1 PHOTOLUMINESCENCE SPECTRA AT HIGH TEMPERATURES 120
X
8.2 NANOCALORIMETRY, 'EXCESS ENERGY TO HEAT' 131
8.3 'EXCESS ENERGY TO HEAT', EXPERIMENTAL EVIDENCE 138
8.4 'EXCESS ENERGY TO HEAT', IMPLICATIONS 142
9 SUMMARY &: OUTLOOK 147
APPENDIX 151
LIST OF FIGURES 170
LIST OF TABLES 171
BIBLIOGRAPHY 183
ACKNOWLEDGEMENTS 185
XI |
| any_adam_object | 1 |
| author | Richter, Robert |
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| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 500 - Natural sciences and mathematics |
| dewey-raw | 500 |
| dewey-search | 500 |
| dewey-sort | 3500 |
| dewey-tens | 500 - Natural sciences and mathematics |
| discipline | Allgemeine Naturwissenschaft |
| format | Thesis Book |
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| spelling | Richter, Robert Verfasser aut Photoluminescence of diamondoids experiment and theory Robert Richter Berlin epubli GmbH 2015 X, 187 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Zugl.: Technische Universität Berlin, Diss., 2015 gas phase spectroscopy fluorescence Photoluminescence vibrational structure large molecules laser Diamondoids electronic strucutre (DE-588)4113937-9 Hochschulschrift gnd-content epubli GmbH (DE-588)106492235X pbl X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4cc3b654bc8648288d1efca5166b5c8a&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028438084&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Richter, Robert Photoluminescence of diamondoids experiment and theory |
| subject_GND | (DE-588)4113937-9 |
| title | Photoluminescence of diamondoids experiment and theory |
| title_auth | Photoluminescence of diamondoids experiment and theory |
| title_exact_search | Photoluminescence of diamondoids experiment and theory |
| title_full | Photoluminescence of diamondoids experiment and theory Robert Richter |
| title_fullStr | Photoluminescence of diamondoids experiment and theory Robert Richter |
| title_full_unstemmed | Photoluminescence of diamondoids experiment and theory Robert Richter |
| title_short | Photoluminescence of diamondoids |
| title_sort | photoluminescence of diamondoids experiment and theory |
| title_sub | experiment and theory |
| topic_facet | Hochschulschrift |
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