Physical chemistry and acid-base properties of surfaces:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London
ISTE
2015
|
| Series: | Focus series
|
| Subjects: | |
| Online Access: | Klappentext Inhaltsverzeichnis |
| Physical Description: | x, 156 Seiten |
| ISBN: | 9781848218437 |
Staff View
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Record in the Search Index
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|---|---|
| adam_text | FOCUS SERIES in MATERIALS SCIENCE
The study of the wettability of surfaces is widely used in technological
applications such as metal-polymer interfaces, water management in fuel
cells, the problems of adsorption in microelectronics as well as the
applications of electrowettability.
After a reminder of the properties of ideal and real surfaces, this book
presents an analysis of the different components involved in the
expression of interfacial tension, especially of the solid-liquid or
iquid-vapor type.
Several methods for measuring wettability are then presented and
illustrated using examples leading to the determination of the different
components of the substrate surface energy.
A review of the different experimental methods allowing us to determine
the acid-base properties of the surfaces is proposed, with emphasis put
on the most frequently used methods in the case of flat surfaces.
Electrowettability and its different applications are then developed in
detail, thus highlighting the importance of electric charges on the solid-
liquid interfacial tension.
Jean-Charles Joud is Emeritus Professor at Grenoble INP Phelma, in
France and a specialist in the thermodynamics and physical chemistry of
surfaces.
Marie-Geneviève Barthés-Labrousse is CNRS Research Director at the
Institut de Chimie Moléculaire et des Matériaux d Orsay in France and a
specialist in surface reactivity.
Wiley
www.iste.co.uk
Contents
A
Introduction............................................................. ix
Chapter 1. Wettability of an Ideal Surface: Overview................. 1
LI. Wetting angle..................................................... 1
1.2. Adhesion effect.................................................. 4
1.3. Surface tension and free surface energy ......................... 5
Chapter 2. Real Surfaces.................................................. 9
2.1. Wenzel’s model - topological defects............................ 9
2.2. Cassie-Baxter model: chemical defects........................... 11
2.3. Superhydrophilic surfaces....................................... 12
2.4. Superhydrophobic surfaces.................................... 16
2.5. Application.................................................... 20
Chapter 3. Components of the Surface Energy.......................... 23
3.1. Overview........................................................ 23
3.2. Molecular interactions and components of the energy......... 26
3.3. The hydrogen bond............................................... 28
3.4. Lewis acid-base interactions.................................... 28
3.5. The effective components of the interaction energy.......... 31
3.6. Application.................................................... 32
Chapter 4. The Acid-Base Component
in the Work of Adhesion.................................................. 37
4.1. Overview........................................................ 37
4.2. Use of the acid-base component.................................. 38
vi Physical Chemistry and Acid-Base Properties of Surfaces
4.3. The Owens-Wendt approximation................................. 39
4.4. Van Oss-Good description...................................... 40
Chapter 5. Experimental Determination
through Wettability Measurements.......................................... 45
5.1. One liquid method.................................................. 46
5.2. Two liquid method. Surfaces with
high surface energy..................................................... 48
5.3. Applications of the two liquid method......................... 49
5.4. Comparison between Owens-Wendt
and van Oss-Good methods................................................ 55
Chapter 6. Acid-Base Properties of Surfaces:
Experimental Approaches.................................................... 61
6.1. Overview........................................................... 61
6.2. General methods.................................................... 61
6.2.1. Wettability.................................................. 61
6.2.2. Electrokinetic method......................................... 62
6.2.3. Scanning probe microscopies................................... 68
6.2.4. Inverse gas chromatography at infinite
dilution conditions................................................... 73
6.2.5. X-ray photoelectron spectroscopy (XPS) ....................... 78
6.2.6. Other methods.................................................. 85
6.3. Local methods..................................................... 86
6.3.1. Infrared spectroscopy........................................ 87
6.3.2. X-ray photoelectron spectroscopy (XPS) ........................ 91
6.3.3. Other methods................................................. 93
6.4. Application examples ........................................... 94
6.4.1. Bonding ability of aluminum sheets............................ 94
6.4.2. Mechanism of formation of the interphase
in metal-polymer joints.............................................. 96
6.4.3. Heterogeneous catalysis....................................... 98
Chapter 7, Oxide-Solution Interfaces:
Surface Charges........................................................... 99
7.1. Brensted acidity and basicity..................................... 100
7.2. Point of zero charge (PZC) ....................................... 101
7.3. The oxide-solution interface.......................... ....... 103
7.4. Electrocapillarity in the oxide-solution interface................ 109
7.4.1. Evolution of the interfacial tension.......................... 110
Contents vii
Chapter 8. Electrocapiliarity Applications.................................. 117
8.1. Study based on the pH of the oxide surfaces.................... 117
8.2. Study of the stability of a liquid film on an oxide surface.... 123
8.2.1. Case of a flat surface......................................... 123
8.2.2. Case of a rough surface........................................ 125
8.3. Modification of the contact angle by an
imposed potential (Electrowetting)...................................... 132
Conclusion.................................................................. 141
Bibliography................................................................ 143
Index....................................................................... 153
|
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| author_role | aut aut |
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| id | DE-604.BV043011138 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T07:14:59Z |
| institution | BVB |
| isbn | 9781848218437 |
| language | English |
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| physical | x, 156 Seiten |
| publishDate | 2015 |
| publishDateSearch | 2015 |
| publishDateSort | 2015 |
| publisher | ISTE |
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| series2 | Focus series |
| spelling | Joud, Jean-Charles Verfasser aut Physical chemistry and acid-base properties of surfaces Jean-Charles Joud, Marie-Geneviève Barthés-Labrousse London ISTE 2015 x, 156 Seiten txt rdacontent n rdamedia nc rdacarrier Focus series Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf Säure (DE-588)4051266-6 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 s DE-604 Säure (DE-588)4051266-6 s Barthés-Labrousse, Marie-Geneviève Verfasser aut Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028436083&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Klappentext Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028436083&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Joud, Jean-Charles Barthés-Labrousse, Marie-Geneviève Physical chemistry and acid-base properties of surfaces Oberflächenchemie (DE-588)4126166-5 gnd Säure (DE-588)4051266-6 gnd |
| subject_GND | (DE-588)4126166-5 (DE-588)4051266-6 |
| title | Physical chemistry and acid-base properties of surfaces |
| title_auth | Physical chemistry and acid-base properties of surfaces |
| title_exact_search | Physical chemistry and acid-base properties of surfaces |
| title_full | Physical chemistry and acid-base properties of surfaces Jean-Charles Joud, Marie-Geneviève Barthés-Labrousse |
| title_fullStr | Physical chemistry and acid-base properties of surfaces Jean-Charles Joud, Marie-Geneviève Barthés-Labrousse |
| title_full_unstemmed | Physical chemistry and acid-base properties of surfaces Jean-Charles Joud, Marie-Geneviève Barthés-Labrousse |
| title_short | Physical chemistry and acid-base properties of surfaces |
| title_sort | physical chemistry and acid base properties of surfaces |
| topic | Oberflächenchemie (DE-588)4126166-5 gnd Säure (DE-588)4051266-6 gnd |
| topic_facet | Oberflächenchemie Säure |
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