Materials under extreme conditions: molecular crystals at high pressure
Gespeichert in:
| Hauptverfasser: | , |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
London
Imperial College Press
[2014]
|
| Schlagworte: | |
| Online-Zugang: | Klappentext Inhaltsverzeichnis |
| Beschreibung: | Enthält Literaturangaben und Index (Seite 261-354) |
| Beschreibung: | xvii, 354 Seiten Illustrationen, Diagramme (teilweise farbig) |
| ISBN: | 9781848163058 1848163053 |
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Datensatz im Suchindex
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| adam_text | MATERIALS UNDER EXTREME CINBITI8MS
High-pressure materials research has been revolutionized in the past few years due to technological breakthroughs in the diamond anvil cell (DAC), shock wave compression and molecular dynamic simulation (MD) methods. The application of high pressure, especially together with high temperature, has revealed exciting modifications of physical and chemical properties even in the simplest molecular materials.
Besides the fundamental importance of these studies to understand the composition and the dynamics of heart and planets’ interior, new materials possessing peculiar characteristics of hardness and composition have been synthesized at very high pressure, while unexpected chemical reactions of simple molecules to polymers and amorphous compounds have been found at milder conditions.
The variety of the phenomena observed in these extreme conditions and of the materials involved provides a common ground bridging scientific communities with different cultural and experimental backgrounds. This monograph will provide a timely opportunity to report on recent progress in the field.
ISBN 978-1-84816-305-8
Contents
H
Preface vii
Foreword ix
Acknowledgments xiii
1. Introduction 1
2. Historical Survey 15
3. Elasticity and Equation of State 23
3.1 Stress and strain........................................ 24
3.2 Elasticity and anisotropy in molecular crystals...... 31
3.2.1 Elastic constants................................. 31
3.2.2 Temperature and pressure dependence of the
elastic constants................................. 47
3.2.3 Single crystals and poly crystals ......... 53
3.2.4 Variation of crystal parameters with pressure ... 55
3.3 Parametric equations of state............................ 70
4. High-pressure Technical Survey 79
4.1 The piston-cylinder device............................... 80
4.1.1 Large volume piston-cylinder apparatus............ 85
4.2 The opposed anvil devices................................ 86
4.3 Multi-anvil devices...................................... 89
4.4 The diamond anvil cell................................... 93
4.4.1 Diamonds ................................• • • * 102
XV
xvi Materials Under Extreme Conditions: Molecular Crystals at High Pressure
4.4.2 Gasket............................................ 109
4.4.3 Loading techniques................................ 113
4.4.4 Compression media................................. 116
4.5 High- and low-temperature techniques.................. 118
4.5.1 Low-temperature devices........................... 119
4.5.2 Resistive heating................................. 121
4.5.3 Laser heating .................................... 123
4.6 Pressure measurement.................................. 128
4.7 Probing techniques based on electromagnetic radiation . . 140
4.7.1 Optical spectroscopy ............................. 141
4.7.2 X-ray diffraction . .............................. 149
4.7.3 Neutron diffraction . ............................ 155
4.7.4 Nuclear magnetic resonance ....................... 157
5. Principles of Chemical Reactivity Under Pressure 159
5.1 Pressure effects on chemical equilibria............... 160
5.2 Pressure effects on reaction rates.................... 165
5.3 Environmental effects at high pressure................ 177
5.4 Effects of high pressure on the electronic structure .... 185
6. Chemical Reactions in Molecular Crystals 193
6.1 Reversible reactions .................................... 196
6.1.1 Solid nitrogen at high pressure: the archetypal
energetic material................................ 196
6.1.2 Red oxygen........................................ 201
6.1.3 Carbon dioxide: a multiform solid................. 203
6.1.4 Formic acid ...................................... 208
6.1.5 Sulphur. Polymeric and molecular phases........... 209
6.1.6 Symmetry breaking and ionization at
high pressures.................................... 211
6.1.7 Metallization at high pressures................... 214
6.2 Irreversible reactions................................ 217
6.2.1 Unsaturated hydrocarbons.......................... 218
6.2.2 Aromatics and heteroaromatics .......... 225
6.2.3 Miscellanea....................................... 232
6.2.4 Energetic materials............................... 241
6.2.5 Photochemistry at high pressures.................. 245
Contents
XVI1
261
327
Bibliography Appendix A Index
349
|
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| author | Bini, Roberto Schettino, Vincenzo 1939- |
| author_GND | (DE-588)1082386308 (DE-588)1082388998 |
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| dewey-ones | 548 - Crystallography |
| dewey-raw | 548/.842 |
| dewey-search | 548/.842 |
| dewey-sort | 3548 3842 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Geographie |
| format | Book |
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| id | DE-604.BV042923854 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:12:56Z |
| institution | BVB |
| isbn | 9781848163058 1848163053 |
| language | English |
| lccn | 013038985 |
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| physical | xvii, 354 Seiten Illustrationen, Diagramme (teilweise farbig) |
| publishDate | 2014 |
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| publisher | Imperial College Press |
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| spelling | Bini, Roberto Verfasser (DE-588)1082386308 aut Materials under extreme conditions molecular crystals at high pressure Roberto Bini, Vincenzo Schettino London Imperial College Press [2014] © 2014 xvii, 354 Seiten Illustrationen, Diagramme (teilweise farbig) txt rdacontent n rdamedia nc rdacarrier Enthält Literaturangaben und Index (Seite 261-354) High pressure chemistry Materials at high pressures Molecular crystals Molekülkristall (DE-588)4133483-8 gnd rswk-swf Hochdruck (DE-588)4160091-5 gnd rswk-swf Hochdruckmetamorphose (DE-588)4469971-2 gnd rswk-swf Geologie (DE-588)4020227-6 gnd rswk-swf Festkörper (DE-588)4016918-2 gnd rswk-swf Hochdruckphysik (DE-588)4160113-0 gnd rswk-swf Metamorphose Geologie (DE-588)4038932-7 gnd rswk-swf Mineralogie (DE-588)4039457-8 gnd rswk-swf Diamant (DE-588)4012069-7 gnd rswk-swf Molekülkristall (DE-588)4133483-8 s Hochdruck (DE-588)4160091-5 s DE-604 Festkörper (DE-588)4016918-2 s Diamant (DE-588)4012069-7 s Hochdruckmetamorphose (DE-588)4469971-2 s Geologie (DE-588)4020227-6 s Mineralogie (DE-588)4039457-8 s Metamorphose Geologie (DE-588)4038932-7 s Hochdruckphysik (DE-588)4160113-0 s Schettino, Vincenzo 1939- Verfasser (DE-588)1082388998 aut Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028351212&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Klappentext Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028351212&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Bini, Roberto Schettino, Vincenzo 1939- Materials under extreme conditions molecular crystals at high pressure High pressure chemistry Materials at high pressures Molecular crystals Molekülkristall (DE-588)4133483-8 gnd Hochdruck (DE-588)4160091-5 gnd Hochdruckmetamorphose (DE-588)4469971-2 gnd Geologie (DE-588)4020227-6 gnd Festkörper (DE-588)4016918-2 gnd Hochdruckphysik (DE-588)4160113-0 gnd Metamorphose Geologie (DE-588)4038932-7 gnd Mineralogie (DE-588)4039457-8 gnd Diamant (DE-588)4012069-7 gnd |
| subject_GND | (DE-588)4133483-8 (DE-588)4160091-5 (DE-588)4469971-2 (DE-588)4020227-6 (DE-588)4016918-2 (DE-588)4160113-0 (DE-588)4038932-7 (DE-588)4039457-8 (DE-588)4012069-7 |
| title | Materials under extreme conditions molecular crystals at high pressure |
| title_auth | Materials under extreme conditions molecular crystals at high pressure |
| title_exact_search | Materials under extreme conditions molecular crystals at high pressure |
| title_full | Materials under extreme conditions molecular crystals at high pressure Roberto Bini, Vincenzo Schettino |
| title_fullStr | Materials under extreme conditions molecular crystals at high pressure Roberto Bini, Vincenzo Schettino |
| title_full_unstemmed | Materials under extreme conditions molecular crystals at high pressure Roberto Bini, Vincenzo Schettino |
| title_short | Materials under extreme conditions |
| title_sort | materials under extreme conditions molecular crystals at high pressure |
| title_sub | molecular crystals at high pressure |
| topic | High pressure chemistry Materials at high pressures Molecular crystals Molekülkristall (DE-588)4133483-8 gnd Hochdruck (DE-588)4160091-5 gnd Hochdruckmetamorphose (DE-588)4469971-2 gnd Geologie (DE-588)4020227-6 gnd Festkörper (DE-588)4016918-2 gnd Hochdruckphysik (DE-588)4160113-0 gnd Metamorphose Geologie (DE-588)4038932-7 gnd Mineralogie (DE-588)4039457-8 gnd Diamant (DE-588)4012069-7 gnd |
| topic_facet | High pressure chemistry Materials at high pressures Molecular crystals Molekülkristall Hochdruck Hochdruckmetamorphose Geologie Festkörper Hochdruckphysik Metamorphose Geologie Mineralogie Diamant |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028351212&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028351212&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT biniroberto materialsunderextremeconditionsmolecularcrystalsathighpressure AT schettinovincenzo materialsunderextremeconditionsmolecularcrystalsathighpressure |