Carbon nanomaterials for advanced energy systems: advances in materials synthesis and device applications
"With the proliferation of electronic devices, the world will need to double its energy supply by 2050. This book addresses this challenge and discusses synthesis and characterization of carbon nanomaterials for energy conversion and storage"--
Gespeichert in:
| Weitere Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, New Jersey
Wiley
[2015]
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| Schlagworte: | |
| Online-Zugang: | Cover image Inhaltsverzeichnis Klappentext |
| Zusammenfassung: | "With the proliferation of electronic devices, the world will need to double its energy supply by 2050. This book addresses this challenge and discusses synthesis and characterization of carbon nanomaterials for energy conversion and storage"-- |
| Beschreibung: | XVIII, 448 Seiten Illustrationen |
| ISBN: | 9781118580783 |
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Datensatz im Suchindex
| _version_ | 1804174977418657792 |
|---|---|
| adam_text | CONTENTS
List of Contributors
Preface
PART I SYNTHESIS AND CHARACTERIZATION
OF CARBON NANOMATERIALS
1 Fullerenes, Higher Fullerenes, and Their Hybrids: Synthesis,
Characterization, and Environmental Considerations
1.1 Introduction, 3
1.2 Fullerene, Higher Fullerenes, and Nanohybrids:
Structures and Historical Perspective, 5
1.2.1 C60 Fullerene, 5
1.2.2 Higher Fullerenes, 6
1.2.3 Fullerene-Based Nanohybrids, 7
1.3 Synthesis and Characterization, 7
1.3.1 Fullerenes and Higher Fullerenes, 7
1.3.1.1 Carbon Soot Synthesis, 7
1.3.1.2 Extraction, Separation, and Purification, 10
1.3.1.3 Chemical Synthesis Processes, 11
1.3.1.4 Fullerene-Based Nanohybrids, 12
1.3.2 Characterization, 12
1.3.2.1 Mass Spectroscopy, 12
1.3.2.2 NMR, 13
1.3.2.3 Optical Spectroscopy, 13
vi
CONTENTS
1.3.2.4 HPLC, 14
1.3.2.5 Electron Microscopy, 14
1.3.2.6 Static and Dynamic Light Scattering, 14
1.4 Energy Applications, 17
1.4.1 Solar Cells and Photovoltaic Materials, 17
1.4.2 Hydrogen Storage Materials, 19
1.4.3 Electronic Components (Batteries, Capacitors, and Open-Circuit
Voltage Applications), 20
1.4.4 Superconductivity, Electrical, and Electronic Properties Relevant
to Energy Applications, 20
1.4.5 Photochemical and Photophysical Properties Pertinent
for Energy Applications, 21
1.5 Environmental Considerations for Fullerene Synthesis and Processing, 21
1.5.1 Existing Environmental Literature for C60, 22
1.5.2 Environmental Literature Status for Higher Fullerenes and NHs, 24
1.5.3 Environmental Considerations, 24
1.5.3.1 Consideration for Solvents, 26
1.5.3.2 Considerations for Derivatization, 26
1.5.3.3 Consideration for Coatings, 27
References, 28
2 Carbon Nanotubes 47
2.1 Synthesis of Carbon Nanotubes, 47
2.1.1 Introduction and Structure of Carbon Nanotube, 47
2.1.2 Arc Discharge and Laser Ablation, 49
2.1.3 Chemical Vapor Deposition, 50
2.1.4 Aligned Growth, 52
2.1.5 Selective Synthesis of Carbon Nanotubes, 57
2.1.6 Summary, 63
2.2 Characterization of Nanotubes, 63
2.2.1 Introduction, 63
2.2.2 Spectroscopy, 63
2.2.2.1 Raman Spectroscopy, 63
2.2.2.2 Optical Absorption (UV-Vis-NIR), 66
2.2.2.3 Photoluminescence Spectroscopy, 68
2.2.3 Microscopy, 70
2.2.3.1 Scanning Tunneling Microscopy and Transmission
Electron Microscopy, 70
2.3 Summary, 73
References, 73
3 Synthesis and Characterization of Graphene 85
3.1 Introduction, 85
3.2 Overview of Graphene Synthesis Methodologies, 87
CONTENTS
vii
3.2.1 Mechanical Exfoliation, 90
3.2.2 Chemical Exfoliation, 93
3.2.3 Chemical Synthesis: Graphene from Reduced Graphene Oxide, 97
3.2.4 Direct Chemical Synthesis, 102
3.2.5 CVD Process, 102
3.2.5.1 Graphene Synthesis by CVD Process, 103
3.2.5.2 Graphene Synthesis by Plasma CVD Process, 109
3.2.5.3 Grain and GBs in CVD Graphene, 110
3.2.6 Epitaxial Growth of Graphene on SiC Surface, 111
3.3 Graphene Characteri zations, 113
3.3.1 Optical Microscopy, 114
3.3.2 Raman Spectroscopy, 116
3.3.3 High Resolution Transmission Electron Microscopy, 118
3.3.4 Scanning Probe Microscopy, 119
3.4 Summary and Outlook, 121
References, 122
4 Doping Carbon Nanomaterials with Heteroatoms 133
4.1 Introduction, 133
4.2 Local Bonding of the Dopants, 135
4.3 Synthesis of Heterodoped Nanocarbons, 137
4.4 Characterization of Heterodoped Nanotubes and Graphene, 139
4.5 Potential Applications, 146
4.6 Summary and Outlook, 152
References, 152
PART II CARBON NANOMATERIALS FOR ENERGY
CONVERSION 163
5 High-Performance Polymer Solar Cells Containing
Carbon Nanomaterials 165
5.1 Introduction, 165
5.2 Carbon Nanomaterials as Transparent Electrodes, 167
5.2.1 CNT Electrode, 168
5.2.2 Graphene Electrode, 169
5.2.3 Graphene/CNT Hybrid Electrode, 171
5.3 Carbon Nanomaterials as Charge Extraction Layers, 171
5.4 Carbon Nanomaterials in the Active Layer, 178
5.4.1 Carbon Nanomaterials as an Electron Acceptor, 178
5.4.2 Carbon Nanomaterials as Additives, 180
5.4.3 Donor/Acceptor Functionalized with Carbon Nanomaterials, 183
5.5 Concluding Remarks, 185
Acknowledgments, 185
References, 185
Vlll
CONTENTS
6 Graphene for Energy Solutions and Its Printable Applications
6.1 Introduction to Graphene, 191
6.2 Energy Harvesting from Solar Cells, 192
6.2.1 DSSCs, 193
6.2.2 Graphene and DSSCs, 195
6.2.2.1 Counter Electrode, 195
6.2.2.2 Photoanode, 198
6.2.2.3 Transparent Conducting Oxide, 199
6.2.2.4 Electrolyte, 200
6.3 OPV Devices, 200
6.3.1 Graphene and OP Vs, 201
6.3.1.1 Transparent Conducting Oxide, 201
6.3.1.2 BHJ, 203
6.3.1.3 Hole Transport Layer, 204
6.4 Lithium-Ion Batteries, 204
6.4.1 Graphene and Lithium-Ion Batteries, 205
6.4.1.1 Anode Material, 205
6.4.1.2 Cathode Material, 209
6.4.2 Li-S and Li-02 Batteries, 211
6.5 Supercapacitors, 212
6.5.1 Graphene and Supercapacitors, 213
6.6 Graphene Inks, 216
6.7 Conclusions, 219
References, 220
191
7 Quantum Dot and Heterojunction Solar Cells
Containing Carbon Nanomaterials 237
7.1 Introduction, 237
7.2 QD Solar Cells Containing Carbon Nanomaterials, 238
7.2.1 CNTs and Graphene as TCE in QD Solar Cells, 238
7.2.1.1 CNTs as TCE Material in QD Solar Cells, 239
7.2.1.2 Graphene as TCE Material in QD Solar Cells, 240
7.2.2 Carbon Nanomaterials and QD Composites in Solar Cells, 241
7.2.2.1 C60 and QD Composites, 241
1.2.2.2 CNTs and QD Composites, 244
7.2.2.3 Graphene and QD Composites, 245
7.2.3 Graphene QDs Solar Cells, 247
7.2.3.1 Physical Properties of GQDs, 247
1.23.2 Synthesis of GQDs, 247
7.23.3 PV Devices of GQDs, 247
7.3 Carbon Nanomaterial/Semiconductor Heterojunction Solar Cells, 249
7.3.1 Principle of Carbon/Semiconductor Heterojunction Solar Cells, 249
7.3.2 a-C/Semiconductor Heterojunction Solar Cells, 250
7.3.3 CNT/Semiconductor Heterojunction Solar Cells, 252
CONTENTS
ix
7.3.4 Graphene/Semiconductor Heterojunction Solar Cells, 253
7.4 Summary, 261
References, 261
8 Fuel Cell Catalysts Based on Carbon Nanomaterials
8.1 Introduction, 267
8.2 Nanocarbon-Supported Catalysts, 268
8.2.1 CNT-Supported Catalysts, 268
8.2.2 Graphene-Supported Catalysts, 271
8.3 Interface Interaction between Pt Clusters and
Graphitic Surface, 276
8.4 Carbon Catalyst, 281
8.4.1 Catalytic Activity for ORR, 281
8.4.2 Effect of N-Dope on O0 Adsorption, 283
8.4.3 Effect of N-Dope on the Local Electronic Structure for
Pyridinic-N and Graphitic-N, 285
8.4.3.1 Pyridinic-N, 287
8.4.3.2 Graphitic-N, 288
8.4.4 Summary of Active Sites for ORR, 290
References, 291
PART III CARBON NANOMATERIALS FOR ENERGY STORAGE
9 Supercapacitors Based on Carbon Nanomaterials
9.1 Introduction, 297
9.2 Supercapacitor Technology and Performance, 298
9.3 Nanoporous Carbon, 304
9.3.1 Supercapacitors with Nonaqueous Electrolytes, 304
9.3.2 Supercapacitors with Aqueous Electrolytes, 311
9.4 Graphene and Carbon Nanotubes, 321
9.5 Nanostructured Carbon Composites, 326
9.6 Other Composites with Carbon Nanomaterials, 327
9.7 Conclusions, 329
References, 330
10 Lithium-Ion Batteries Based on Carbon Nanomaterials
10.1 Introduction, 339
10.2 Improving Li-Ion Battery Energy Density, 344
10.3 Improvements to Lithium-Ion Batteries Using Carbon
Nanomaterials, 345
10.3.1 Carbon Nanomaterials as Active Materials, 345
10.4 Carbon Nanomaterials as Conductive Additives, 346
10.4.1 Current and SOA Conductive Additives, 346
267
295
297
339
X
CONTENTS
10.5 SWCNT Additives to Increase Energy Density, 348
10.6 Carbon Nanomaterials as Current Collectors, 351
10.6.1 Current Collector Options, 351
10.7 Implementation of Carbon Nanomaterial Current Collectors
for Standard Electrode Composites, 354
10.7.1 Anode: MCMB Active Material, 354
10.7.2 Cathode: NCA Active Material, 356
10.8 Implementation of Carbon Nanomaterial Current Collectors
for Alloying Active Materials, 356
10.9 Ultrasonic Bonding for Pouch Cell Development, 358
10.10 Conclusion, 359
References, 362
11 Lithium/Sulfur Batteries Based on Carbon Nanomaterials
11.1 Introduction, 365
1 1.2 Fundamentals of Lithium/Sulfur Cells, 366
11.2.1 Operating Principles, 366
11.2.2 Scientific Problems, 368
11.2.2.1 Dissolution and Shuttle Effect of Lithium
Polysulfides, 369
11.2.2.2 Insulating Nature of Sulfur and Li2S, 369
11.2.2.3 Volume Change of the Sulfur Electrode
during Cycling, 369
11.2.3 Research Strategy, 369
11.3 Nanostructure Carbon-Sulfur, 370
11.3.1 Porous Carbon-Sulfur Composite, 371
11.3.2 One-Dimensional Carbon-Sulfur Composite, 373
1 1.3.3 Two-Dimensional Carbon (Graphene)-Sulfur, 375
11.3.4 Three-Dimensional Carbon Paper-Sulfur, 377
11.3.5 Preparation Method of Sulfur-Carbon Composite, 377
11.4 Carbon Layer as a Polysulfide Separator, 380
11.5 Opportunities and Perspectives, 381
References, 382
12 Lithium-Air Batteries Based on Carbon Nanomaterials
12.1 Metal-Air Batteries, 385
12.2 Li-Air Chemistry, 387
12.2.1 Aqueous Electrolyte Cell, 387
12.2.2 Nonaqueous Aprotic Electrolyte Cell, 389
12.2.3 Mixed Aqueous/Aprotic Electrolyte Cell, 391
12.2.4 All Solid-State Cell, 391
12.3 Carbon Nanomaterials for Li-Air Cells Cathode, 393
12.4 Amorphous Carbons, 393
12.4.1 Porous Carbons, 393
365
385
CONTENTS
xi
12.5 Graphitic Carbons, 395
12.5.1 Carbon Nanotubes, 395
12.5.2 Graphene, 398
12.5.3 Composite Air Electrodes, 400
12.6 Conclusions, 403
References, 403
13 Carbon-Based Nanomaterials for H2 Storage
13.1 introduction, 407
13.2 Hydrogen Storage in Fullerenes, 408
13.3 Hydrogen Storage in Carbon Nanotubes, 414
13.4 Hydrogen Storage in Graphene-Based Materials, 419
13.5 Conclusions, 427
Acknowledgments, 428
References, 428
Index
407
439
Presents state-of-the art synthetic techniques and applications for the
use of carbon-based nanomaterials in energy conversion and storage
The world faces the challenge of needing to double its energy supply by 2050. This implies that
fossil fuels (e.g., oil, coal, natural gas) will be replaced by clean energy sources. For decades,
considerable effort has been made to utilize carbon nanomaterials (e.g., fuilerenes, carbon
nanotubes, and graphene) as new energy materials for the development of high-performance energy
conversion and storage systems, which are paramount for a wide range of everyday applications.
Amid the challenges and opening of new frontiers in nanotechnology, Carbon Nanomaterials for
Advanced Energy Systems: Advances in Materials Synthesis and Device Applications focuses on
synthesis and characterization of carbon nanomaterials for energy conversion and storage.
The book features the following:
• Systematic coverage of the synthesis and characterization of a wide array of carbon
nanomaterials
• Applications of carbon nanomaterials in solar cells (e.g.F polymer, dye-sensitized, and
quantum dot solar cells), thermoelectrics, fuel cells, supercapacitors, and lithium batteries
• Applications of carbon nanomaterials for energy-related gas storage, including hydrogen
and methane
• Detailed descriptions of multidimensional and multifunctional carbon architectures for
energy conversion and storage
Addressing one of the leading challenges facing society today as we steer away from dwindling
supplies of fuels and the need for electric power rises due to the proliferation of electronic
products, this book will be useful to graduate students and researchers in the field. It is also a
valuable resource for materials scientists, organic and inorganic chemists, physicists, chemical
engineers, electrical engineers, and device engineers in the discipline.
Wen Lu, PhD, obtained his BSc and MSc from Yunnan University in China and his PhD at the
University of Wollongong in Australia. He has been Senior Research Scientist and Group Leader
leading research in multiple research companies in the United States. His research activities have
been focused on the applications of electrochemistry and advanced materials to the development
of a range of electrochemical devices, including energy conversion and storage devices.
Jong-Beom Baek, PhD, is Professor of the School of Energy and Chemical Engineering/Director
of Low-Dimensional Carbon Materials Center (LCMC) in Ulsan National Institute of Science and
Technology (UNIST, Korea). He obtained his PhD in Polymer Science from the University of
Akron, USA. Dr. Baek’s current research interests focus on the defect-selective functionalization
of carbon-based nanomaterials for application-specific purposes, including energy-related
applications.
Liming Dai, PhD, is Kent Hale Smith Professor in the Department of Macromolecular Science
and Engineering, Case Western Reserve University, USA. He is also Director of the Center of
Advanced Science and Engineering for Carbon (Case4Carbon). Dr. Dai received his BSc degree
from Zhejiang University and PhD from the Australian National University. Dr. Dai’s expertise
lies across the synthesis, functionalization, and device fabrication of conjugated polymers and
carbon nanomaterials for energy-related and biomedical applications.
Cover Image: Courtesy of the Author
ISBN 978-1-118-58078-3
www.wiley.com
Wiley
Also available
as an e-book
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| id | DE-604.BV042758984 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T07:08:58Z |
| institution | BVB |
| isbn | 9781118580783 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-028189552 |
| oclc_num | 935878806 |
| open_access_boolean | |
| owner | DE-29T DE-703 |
| owner_facet | DE-29T DE-703 |
| physical | XVIII, 448 Seiten Illustrationen |
| publishDate | 2015 |
| publishDateSearch | 2015 |
| publishDateSort | 2015 |
| publisher | Wiley |
| record_format | marc |
| spelling | Carbon nanomaterials for advanced energy systems advances in materials synthesis and device applications edited by Wen Lu, Jong-Beom Baek, Liming Dai Hoboken, New Jersey Wiley [2015] XVIII, 448 Seiten Illustrationen txt rdacontent n rdamedia nc rdacarrier "With the proliferation of electronic devices, the world will need to double its energy supply by 2050. This book addresses this challenge and discusses synthesis and characterization of carbon nanomaterials for energy conversion and storage"-- Electric batteries / Materials Energy harvesting / Materials Fullerenes Nanostructured materials Carbon nanotubes TECHNOLOGY & ENGINEERING / Nanotechnology & MEMS. bisacsh Elektrochemie (DE-588)4014241-3 gnd rswk-swf Elektrochemische Energietechnik (DE-588)4151756-8 gnd rswk-swf Energieerzeugung (DE-588)4070813-5 gnd rswk-swf Karbon (DE-588)4126367-4 gnd rswk-swf Nanostrukturiertes Material (DE-588)4342626-8 gnd rswk-swf Energiespeicherung (DE-588)4014722-8 gnd rswk-swf Nanotechnologie (DE-588)4327470-5 gnd rswk-swf Energieumwandlung (DE-588)4014730-7 gnd rswk-swf Elektrochemie (DE-588)4014241-3 s Nanotechnologie (DE-588)4327470-5 s DE-604 Energieumwandlung (DE-588)4014730-7 s Energiespeicherung (DE-588)4014722-8 s Nanostrukturiertes Material (DE-588)4342626-8 s Elektrochemische Energietechnik (DE-588)4151756-8 s Karbon (DE-588)4126367-4 s Energieerzeugung (DE-588)4070813-5 s 1\p DE-604 Lu, Wen edt http://catalogimages.wiley.com/images/db/jimages/9781118580783.jpg Cover image Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028189552&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028189552&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Carbon nanomaterials for advanced energy systems advances in materials synthesis and device applications Electric batteries / Materials Energy harvesting / Materials Fullerenes Nanostructured materials Carbon nanotubes TECHNOLOGY & ENGINEERING / Nanotechnology & MEMS. bisacsh Elektrochemie (DE-588)4014241-3 gnd Elektrochemische Energietechnik (DE-588)4151756-8 gnd Energieerzeugung (DE-588)4070813-5 gnd Karbon (DE-588)4126367-4 gnd Nanostrukturiertes Material (DE-588)4342626-8 gnd Energiespeicherung (DE-588)4014722-8 gnd Nanotechnologie (DE-588)4327470-5 gnd Energieumwandlung (DE-588)4014730-7 gnd |
| subject_GND | (DE-588)4014241-3 (DE-588)4151756-8 (DE-588)4070813-5 (DE-588)4126367-4 (DE-588)4342626-8 (DE-588)4014722-8 (DE-588)4327470-5 (DE-588)4014730-7 |
| title | Carbon nanomaterials for advanced energy systems advances in materials synthesis and device applications |
| title_auth | Carbon nanomaterials for advanced energy systems advances in materials synthesis and device applications |
| title_exact_search | Carbon nanomaterials for advanced energy systems advances in materials synthesis and device applications |
| title_full | Carbon nanomaterials for advanced energy systems advances in materials synthesis and device applications edited by Wen Lu, Jong-Beom Baek, Liming Dai |
| title_fullStr | Carbon nanomaterials for advanced energy systems advances in materials synthesis and device applications edited by Wen Lu, Jong-Beom Baek, Liming Dai |
| title_full_unstemmed | Carbon nanomaterials for advanced energy systems advances in materials synthesis and device applications edited by Wen Lu, Jong-Beom Baek, Liming Dai |
| title_short | Carbon nanomaterials for advanced energy systems |
| title_sort | carbon nanomaterials for advanced energy systems advances in materials synthesis and device applications |
| title_sub | advances in materials synthesis and device applications |
| topic | Electric batteries / Materials Energy harvesting / Materials Fullerenes Nanostructured materials Carbon nanotubes TECHNOLOGY & ENGINEERING / Nanotechnology & MEMS. bisacsh Elektrochemie (DE-588)4014241-3 gnd Elektrochemische Energietechnik (DE-588)4151756-8 gnd Energieerzeugung (DE-588)4070813-5 gnd Karbon (DE-588)4126367-4 gnd Nanostrukturiertes Material (DE-588)4342626-8 gnd Energiespeicherung (DE-588)4014722-8 gnd Nanotechnologie (DE-588)4327470-5 gnd Energieumwandlung (DE-588)4014730-7 gnd |
| topic_facet | Electric batteries / Materials Energy harvesting / Materials Fullerenes Nanostructured materials Carbon nanotubes TECHNOLOGY & ENGINEERING / Nanotechnology & MEMS. Elektrochemie Elektrochemische Energietechnik Energieerzeugung Karbon Nanostrukturiertes Material Energiespeicherung Nanotechnologie Energieumwandlung |
| url | http://catalogimages.wiley.com/images/db/jimages/9781118580783.jpg http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028189552&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028189552&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT luwen carbonnanomaterialsforadvancedenergysystemsadvancesinmaterialssynthesisanddeviceapplications |