d-block chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Oxford
Oxford Univers Press
[2015]
|
| Ausgabe: | Second edition |
| Schriftenreihe: | Oxford chemistry primers
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | ix, 128 Seiten Illustrationen |
| ISBN: | 9780198700968 |
Internformat
MARC
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Datensatz im Suchindex
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|---|---|
| adam_text | Table of contents
1. Introduction
1.1 The d-block and transition elements
1.2 Occurrence of d-block metals
1.3 d-Block metals in nature
1.4 Gemstones
1.5 Diverse experimental observations
1.6 Summary
1.7 Exercises
1.8 Further reading
2. Complexes
2.1 Introduction
2.2 A simple Lewis model of bonding
2.3 Ligands
2.4 Inner/outer sphere complexes
2.5 Polydentate ligands
2.6 Stability constants
2.7 Chelate effect
2.8 The concept of hard and soft acids and bases
2.9 Summary
2.10 Exercises
3. Shape and isomerism
3.1 Introduction
3.2 Coordination number 1
3.3 Coordination number 2
3.4 Coordination number 3
3.5 Coordination number 4
3.6 Coordination number 5
3.7 Coordination number 6
3.S Higher coordination numbers
3.9 Isomerism
3.10 Constitutional ¡somensm
301 Stereoisomerism
322 Summary
323 Exercises
TABLE OF CONTENTS
4. Metal classification and electron counting
4.1 Introduction
4.2 Valence electronic configurations of neutral metals
4.3 Oxidation number and electronic configuration
4.4 Comparisons of the deblock and /-block metals
4.5 Calculation of oxidation number
4.6 The covalent bond classification
4.7 Electron counting
4.8 Electron counting starting from the oxidation number
4.9 Electron counting from the CBC
4.10 Extending the CBC: equivalent neutral class
4.11 Summary
4.12 Exercises
4.13 Reference
5. An ionic model of metal complexes
5.1 Introduction
5.2 The crystal field theory
5.3 The effect of two z-axis electrons on p orbitals
5.4 Crystal field description of octahedral complexes
5.5 Crystal field splitting for cubic MLS and tetrahedral ML4 complexes
5.6 Crystal field splitting for a square planar ML4 complex
5.7 The dn configurations of octahedral complexes
5.8 Tetrahedral complexes
5.9 Crystal field theory limitations
5.10 Summary
5.11 Exercises
6. Covalent models of metal complexes
6.1 Introduction
6.2 A valence bond model: octahedral six-coordination
6.3 The molecular orbital approach for a-bonded ligands
6.4 Other geometries
6.5 k Donor ligands
6.6 n Acceptor ligands
6.7 Other ;r acceptor ligands
6.8 Nitrosyl complexes
6.9 Phosphine and phosphite complexes
6.10 Aikene complexes
6.11 The 18-electron rule
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91
TABLE OF CONTENTS
IX
6.12 The effect of ;r interactions upon the valence electron count 92
6.13 Metal-metal bonding 94
6.14 Summary 97
6.15 Exercises 97
7. Consequences of d orbital splitting 98
7.1 Introduction 98
7.2 Spectroscopy and the measurement of Aoct 98
7.3 Selection rules for d-block metal complexes 99
7.4 The low intensity of the d-d band in [Ti(OH2)6]3+ 101
7.5 Charge transfer spectra 101
7.6 Magnetism 102
7.7 Factors affecting the size of Aoct 104
7.8 Distorted complexes: theJahn-Teller effect 106
7.9 Periodic consequences of crystal field stabilization energies 110
7.10 Summary 113
7.11 Exercises 114
8. Formulae and nomenclature 115
8.1 Introduction 115
8.2 Representation of metal complex formulae 115
8.3 Examples of ligand symbols 115
8.4 Nomenclature for metal complexes 116
8.5 Summary 121
8.6 Exercises 122
8.7 Reference 122
Further reading 123
Glossary 124
Index 127
|
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| discipline | Chemie / Pharmazie Chemie |
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| illustrated | Illustrated |
| indexdate | 2024-07-10T07:07:39Z |
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| isbn | 9780198700968 |
| language | English |
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| physical | ix, 128 Seiten Illustrationen |
| publishDate | 2015 |
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| series2 | Oxford chemistry primers |
| spelling | Winter, Mark J. Verfasser (DE-588)172829186 aut d-block chemistry Mark J. Winter Second edition Oxford Oxford Univers Press [2015] © 2015 ix, 128 Seiten Illustrationen txt rdacontent n rdamedia nc rdacarrier Oxford chemistry primers Elementos de transicao larpcal Transition metal compounds Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf (DE-588)4151278-9 Einführung gnd-content (DE-588)4123623-3 Lehrbuch gnd-content Übergangsmetallkomplexe (DE-588)4131837-7 s DE-604 Digitalisierung UB Regensburg - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028129230&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Winter, Mark J. d-block chemistry Elementos de transicao larpcal Transition metal compounds Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| subject_GND | (DE-588)4131837-7 (DE-588)4151278-9 (DE-588)4123623-3 |
| title | d-block chemistry |
| title_auth | d-block chemistry |
| title_exact_search | d-block chemistry |
| title_full | d-block chemistry Mark J. Winter |
| title_fullStr | d-block chemistry Mark J. Winter |
| title_full_unstemmed | d-block chemistry Mark J. Winter |
| title_short | d-block chemistry |
| title_sort | d block chemistry |
| topic | Elementos de transicao larpcal Transition metal compounds Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| topic_facet | Elementos de transicao Transition metal compounds Übergangsmetallkomplexe Einführung Lehrbuch |
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