Solvent effects in chemistry:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, New Jersey
Wiley
[2016]
|
| Ausgabe: | Second edition |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | xi, 227 Seiten Diagramme |
| ISBN: | 9781119030980 |
Internformat
MARC
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| 245 | 1 | 0 | |a Solvent effects in chemistry |c Erwin Buncel, Robert A. Stairs |
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Datensatz im Suchindex
| _version_ | 1804174795205509120 |
|---|---|
| adam_text | CONTENTS
n
Preface to the Second Edition viii
Preface to the First Edition x
1 Physicochemical Foundations 1
1.1 Generalities 1
1.2 Classification of Solvents 4
1.3 Solvents in the Workplace and the Environment 6
1.4 Some Essential Thermodynamics and Kinetics:
Tendency and Rate 7
1.5 Equilibrium Considerations 7
1.6 Thermodynamic Transfer Functions 9
1.7 Kinetic Considerations: Collision Theory 10
1.8 Transition-State Theory 11
1.9 Reactions in Solution 16
1.10 Diffusion-Controlled Reactions 16
1.11 Reaction in Solution and the Transition-State Theory 18
Problems 21
2 Unreactive Solvents 23
2.1 Intermolecular Potentials 23
2.2 Activity and Equilibrium in Nonelectrolyte Solutions 24
2.3 Kinetic Solvent Effects 28
2.4 Solvent Polarity 30
2.5 Electrostatic Forces 30
2.6 Electrolytes in Solution 33
36
39
42
47
53
55
57
57
58
59
60
62
65
76
77
78
82
83
83
84
86
87
89
89
91
95
101
106
110
111
112
112
113
119
123
123
126
139
2.7 Solvation
2.8 Single Ion Solvation
2.9 Ionic Association
2.10 Solvent Mixtures
2.11 Salt Effects
Problems
Reactive Solvents
3.1 Specific Solute/Solvent Interactions
3.2 Hydrogen Bonding
3.3 Acids and Bases in Solvents
3.4 Br0nsted-Lowry Acids and Bases
3.5 Acidity Functions
3.6 Acids and Bases in Kinetics
3.7 Lewis Acids and Bases
3.8 Hard and Soft Acids and Bases (HSAB)
3.9 Scales of Hardness or Softness
3.10 Acids and Bases in Reactive Aprotic Solvents
3.11 Extremes of Acidity and Basicity
3.12 Oxidation and Reduction
3.13 Acidity/Redox Diagrams
3.14 Unification of Acid—Base and Redox Concepts
Problems
Chemometrics: Solvent Effects and Statistics
4.1 Linear Free Energy Relationships
4.2 Correlations between Empirical Parameters and
Other Measurable Solvent Properties
4.3 Representation of Correlation Data on the Hemisphere
4.4 Some Particular Cases
4.5 Acidity and Basicity Parameters
4.6 Base Softness Parameters
4.7 Conclusion
Theories of Solvent Effects
5.1 Introduction: Modeling
5.2 Quantum-Mechanical Methods
5.3 Statistical-Mechanical Methods
5.4 Integral Equation Theories
5.5 Solvation Calculations
5.6 Some Results
Problems
CONTENTS
vil
6 Dipolar Aprotic Solvents 140
6.1 Introduction 140
6.2 Acidities in DMSO and the H-Scale
in DMS0-H20 Mixtures 142
6.3 Use of Thermodynamic Transfer Functions 144
6.4 Classification of Rate Profile-Medium Effect Reaction Types 147
6.5 Bimolecular Nucleophilic Substitution 149
6.6 Proton Transfer 152
6.7 D2-HO Exchange 153
Problems 154
7 Examples of Other Solvent Classes 155
7.1 Introduction 155
7.2 Acidic Solvents 155
7.3 Basic Solvents 158
7.4 Chiral Solvents 161
8 New Solvents and Green Chemistry 164
8.1 Neoteric Solvents 164
8.2 Supercritical Fluids 164
8.3 Ionic Liquids 167
8.4 Low-Transition-Temperature Mixtures 173
8.5 Bio-Based Solvents 174
8.6 Fluorous Solvents 174
8.7 Switchable Solvents 174
8.8 Green Solvent Chemistry 176
9 Concluding Observations 182
9.1 Choosing a Solvent 182
9.2 Envoi 184
Appendix (Tables listing parameters, selected values) 185
Answers 197
References 199
Index 214
Provides invaluable resource to virtually all
chemists and field workers for the research and
development programs of solvent effects
Solvents are integral to everyday research activities. Choosing the appropriate solvent
allows thermodynamic and kinetic control of a chemical reaction. Building on this
foundation to cultivate a deeper understanding of the topic can better aid and result in
the determination of reaction mechanisms and syntheses planning.
Solvent Effects in Chemistry provides the introduction to the concepts, theory and
experimental knowledge concerning solvent effects on the rate and equilibrium of
chemical reactions. It begins with basic thermodynamics and kinetics, with consideration
given to theoretical calculations (quantum chemistry, molecular dynamics, etc.), to
statistical methods (chemometrics), and to modern-day concerns such as green
chemistry. Furthermore, this monograph:
• Employs a semi quantitative approach, avoiding unnecessary detail or rigor so that
the discussions are accessible to students and professionals alike
• Is suitable for undergraduates, graduate students, and newcomers from related
fields in chemistry and chemical engineering where an understanding of solvent
effects is desired
• Provides examples from inorganic and organic chemistry
As this book is aimed at upper-level undergraduates, graduates, and newcomers to the
field, the more advanced topics in the book are presented in a succinct and clear way so
that concepts can be easily grasped. It is also intended as a supplementary text for all
kinds of chemists, namely, academic researchers, chemical engineers, environmental
scientists, government and industrial workers in chemistry who will find the text a
reliable source for their research.
The molecule represented on the front cover is 4-[(4 -hydroxyphenyl)azo-N-methylpyridine,
called Buncel s dye by Rauhut, Clark and Steinke (1993). The solvatochromism of this and a
small number of related dyes forms the basis of the polarity parameter n*azo
Erwin Buncel, Ph.D., FRSC, is Professor Emeritus in Physical Organic Chemistry at
Queen s University. He received his Ph.D. in organic chemistry in 1957 and his D.Sc.
in physical organic chemistry in 1970, both at the University of London. He has won
several awards and honors, including the R.U. Lemieux Award in organic chemistry—
Canadian Society for Chemistry in 1999, and he was a Fellow of the World Innovation
Foundation (2001). He has recently been elected a fellow of the Royal Society of Canada.
Robert A. Stairs, Ph.D, FCIC, is Professor Emeritus in the Department of Chemistry
at Trent University at Peterborough, Ontario, having joined at its opening in 1964,
after teaching at Cornell and at Queen s University in Kingston. During his 25 years at
Trent, he served as chair of the Department twice. Since retiring, Prof. Stairs keeps up
a close relationship withTrent, returning regularly for seminars and special events, and
maintaining a modest research program.
ISBN 978-1-119-03098-0
|
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| edition | Second edition |
| format | Book |
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| id | DE-604.BV042620393 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T07:06:04Z |
| institution | BVB |
| isbn | 9781119030980 |
| language | English |
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| spelling | Buncel, Erwin 1931- Verfasser (DE-588)171996003 aut Solvent effects in chemistry Erwin Buncel, Robert A. Stairs Second edition Hoboken, New Jersey Wiley [2016] © 2016 xi, 227 Seiten Diagramme txt rdacontent n rdamedia nc rdacarrier Chemie (DE-588)4009816-3 gnd rswk-swf Lösungsmittel (DE-588)4036160-3 gnd rswk-swf Lösungsmitteleffekt (DE-588)4168032-7 gnd rswk-swf Chemie (DE-588)4009816-3 s Lösungsmittel (DE-588)4036160-3 s Lösungsmitteleffekt (DE-588)4168032-7 s DE-604 Stairs, Robert A. Verfasser aut Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028053113&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028053113&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Buncel, Erwin 1931- Stairs, Robert A. Solvent effects in chemistry Chemie (DE-588)4009816-3 gnd Lösungsmittel (DE-588)4036160-3 gnd Lösungsmitteleffekt (DE-588)4168032-7 gnd |
| subject_GND | (DE-588)4009816-3 (DE-588)4036160-3 (DE-588)4168032-7 |
| title | Solvent effects in chemistry |
| title_auth | Solvent effects in chemistry |
| title_exact_search | Solvent effects in chemistry |
| title_full | Solvent effects in chemistry Erwin Buncel, Robert A. Stairs |
| title_fullStr | Solvent effects in chemistry Erwin Buncel, Robert A. Stairs |
| title_full_unstemmed | Solvent effects in chemistry Erwin Buncel, Robert A. Stairs |
| title_short | Solvent effects in chemistry |
| title_sort | solvent effects in chemistry |
| topic | Chemie (DE-588)4009816-3 gnd Lösungsmittel (DE-588)4036160-3 gnd Lösungsmitteleffekt (DE-588)4168032-7 gnd |
| topic_facet | Chemie Lösungsmittel Lösungsmitteleffekt |
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