Determination method and soil emission behavior of crude oil volatile organic and polycyclic aromatic hydrocarbons:
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2015
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIII, 92 Bl. Ill., graph. Darst. |
Internformat
MARC
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Datensatz im Suchindex
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| adam_text | TABLE OF CONTENTS
PREFACE I
SUMMARY II
LIST OF ABBREVIATIONS AND SYMBOLS VIII
LIST OF FIGURES X
LIST OF TABLES XIII
1 OBJECTIVE OF THE THESIS 1
1.1 PROJECT INTRODUCTION 1
1.2 OBJECTIVE AND ORGANIZATION OF THE THESIS 3
2 GENERAL INTRODUCTION 5
2.1 ANALYTICAL METHODS FOR CRUDE OIL VOLATILE ORGANIC AND POLYCYCLIC
AROMATIC
HYDROCARBONS 6
2.1.1 HEADSPACE 7
2.1.2 SOLID PHASE MICROEXTRACTION 9
2.1.3 OTHER PURIFICATION METHODS FOR CRUDE OIL VOLATILE ORGANIC AND
POLYCYCLIC AROMATIC
HYDROCARBONS 11
2.2 CRUDE OIL EVAPORATION 13
2.3 VOLATILE ORGANIC COMPOUNDS SORPTION IN SOIL AND EVAPORATION THROUGH
SOIL 14
2.4 CRUDE OIL SPILL POLLUTION AND REMOTE DETECTION 16
3 MATERIALS, METHODS AND THEORY 18
3.1 CHARACTERISTICS OF THE SOIL 18
3.2 MATERIALS 18
3.2.1 MATERIALS USED FOR DETERMINATION OF VOLATILE ORGANIC AND
POLYCYCLIC AROMATIC
HYDROCARBONS IN CRUDE OIL WITH EFFICIENT GAS-CHROMATOGRAPHIC METHODS 18
3.2.2 MATERIALS USED FOR SORPTION MECHANISMS STUDY OF CRUDE OIL BINARY
VOLATILE ORGANIC
IV
HTTP://D-NB.INFO/1072552612
COMPOUNDS ANALYSIS WITH SOLID PHASE MICROEXTRACTION 19
3.2.3 MATERIALS USED FOR STUDY OF CRUDE OIL VOLATILE ORGANIC COMPOUNDS
EMISSION FROM
SOIL 19
3.3 METHODS 20
3.3.1 METHODS FOR DETERMINATION OF VOLATILE ORGANIC AND POLYCYCLIC
AROMATIC HYDROCARBONS
IN CRUDE OIL WITH EFFICIENT GAS-CHROMATOGRAPHIC METHODS 20
3.3.1.1 INSTRUMENTATION 20
3.3.1.2 DIRECT CALIBRATION FOR SUPER VOCS IN CRUDE OIL AND QUANTITATION
WITH ONE-DROP
METHOD 21
3.3.1.3 PAHS STANDARDS AND CRUDE OIL PREPARATION 21
3.3.2 METHODS FOR SORPTION MECHANISMS STUDY OF CRUDE OIL BINARY VOLATILE
ORGANIC
COMPOUNDS ANALYSIS WITH SOLID PHASE MICROEXTRACTION 22
3.3.2.1 SPME APPARATUS 22
3.3.2.2 ANALYTICAL METHODS 22
3.3.3 METHODS FOR STUDY OF CRUDE OIL VOLATILE ORGANIC COMPOUNDS EMISSION
FROM SOIL 23
3.3. 3.1 GAS CHROMATOGRAPH (GC) EXPERIMENTS AND SPME CONDITIONS 23
3.3. 3.2 BET ISOTHERM TESTS 24
3.3.3.3 VOCS DIFFUSION EXPERIMENTS 24
3.4 THEORY FOR CRUDE OIL VOLATILE ORGANIC COMPOUNDS EMISSION PREDICTION
FROM SOIL 25
3.4.1 NON-EQUILIBRIUM MASS TRANSFER ANALYSIS WITH SPME 25
3.4.2 LIQUID EVAPORATION 25
3.4.3 BET ISOTHERM PARAMETERS ESTIMATION 25
3.4.4 MODEL FOR DIFFUSION FLUX THROUGH SOIL LAYER 26
4 RESULTS 27
4.1 DETERMINATION OF VOLATILE ORGANIC AND POLYCYCLIC AROMATIC
HYDROCARBONS IN CRUDE OIL
WITH EFFICIENT GAS-CHROMATOGRAPHIC METHODS 27
4.1.1 IDENTIFICATION FOR SUPER VOCS IN CRUDE OIL 27
4.1.2 EXTERNAL CALIBRATION METHOD FOR C5-C7 ALKANE STANDARDS 28
V
4.1.3 INTERNAL CALIBRATION METHOD FOR C1-C4 ALKANE STANDARDS 28
4.1.4 QUANTITATION OF SUPER VOCS WITH THE ONE-DROP METHOD 29
4.1.5 PAHS IN THE CRUDE OIL AND MAIN PAHS CHOOSE FOR CALIBRATION 32
4.1.6 PAHS CALIBRATION AND ANALYSIS OF CRUDE OIL 33
4.2 THE INFLUENCE OF DIFFERENT SORPTION MECHANISMS IN CRUDE OIL BINARY
VOLATILE ORGANIC
COMPOUNDS ANALYSIS DURING SOLID PHASE MICROEXTRACTION 35
4.3 A PREDICTIVE METHOD FOR VOLATILE ORGANIC COMPOUNDS EMISSION FROM
SOIL: TAKING
N-PENTANE AS AN EXAMPLE 38
4.3.1 BET DATA ANALYSIS 38
4.3.2 CALIBRATION FOR N-PENTANE WITH SPME 40
4.3.3 N-PENTANE EVAPORATION INTO AIR BY DIFFUSION 41
4.3.4 INFLUENCE OF THE GLASS COTTON ON FREE DIFFUSION 44
4.3.5 N-PENTANE EVAPORATION THROUGH SOIL 44
4.4 A PREDICTIVE METHOD FOR CRUDE OIL VOLATILE ORGANIC COMPOUNDS
EMISSION FROM SOIL:
EVAPORATION AND DIFFUSION BEHAVIOR INVESTIGATION OF BINARY GAS MIXTURES
46
4.4.1 VOCS BET ISOTHERM PARAMETERS 46
4.4.2 CALIBRATION FOR BINARY VOCS SYSTEM WITH SPME 47
4.4.3 VOCS EVAPORATION INTO AIR BY FREE DIFFUSION 49
4.4.4 VOCS EVAPORATION THROUGH SANDY SOIL LAYER 52
5 DISCUSSION 54
5.1 DETERMINATION OF VOLATILE ORGANIC AND POLYCYCLIC AROMATIC
HYDROCARBONS IN CRUDE OIL
WITH EFFICIENT GAS-CHROMATOGRAPHIC METHODS 54
5.1.1 ONE-DROP METHOD 54
5.1.2 PAHS ANALYSIS COMPARISON 55
5.2 THE INFLUENCE OF DIFFERENT SORPTION MECHANISMS IN CRUDE OIL BINARY
VOLATILE ORGANIC
COMPOUNDS ANALYSIS DURING SOLID PHASE MICROEXTRACTION 56
5.3 A PREDICTIVE METHOD FOR VOLATILE ORGANIC COMPOUNDS EMISSION FROM
SOIL: TAKING
N-PENTANE AS AN EXAMPLE 59
VI
5.3.1 VOC CALIBRATION WITH SPME IN A NON-STEADY-STATE MASS-TRANSFER
PROCESS 59
5.3.2 VOC FREE DIFFUSION 60
5.3.3 FREE DIFFUSION MODEL APPLIED TO SOIL EVAPORATION PREDICTION 61
5.3.4 EXPERIMENTAL AND PREDICTIVE FLUX ANALYSIS AND COMPARISON 61
5.4 A PREDICTIVE METHOD FOR CRUDE OIL VOLATILE ORGANIC COMPOUNDS
EMISSION FROM SOIL:
EVAPORATION AND DIFFUSION BEHAVIOR INVESTIGATION OF BINARY GAS MIXTURES
62
5.4.1 BINARY VOCS DETERMINATION WITH SPME 62
5.4.2 VOCS FREE DIFFUSION 63
5.4.3 VOCS EVAPORATION PREDICTION THROUGH SANDY SOIL WITH FREE DIFFUSION
MODEL 63
5.4.4 EXPERIMENTAL AND PREDICTIVE EVAPORATION FLUX ANALYSIS AND
COMPARISON 64
6 GENERAL CONCLUSIONS AND OUTLOOK 66
6.1 GENERAL CONCLUSIONS 66
6.2 OUTLOOK 67
REFERENCES 69
ACKNOWLEDGMENTS 81
APPENDIX 83
VII
|
| any_adam_object | 1 |
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| author_facet | Wang, Haijing |
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| dewey-search | 622.33820286 |
| dewey-sort | 3622.33820286 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Bergbau / Hüttenwesen |
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| spelling | Wang, Haijing Verfasser aut Determination method and soil emission behavior of crude oil volatile organic and polycyclic aromatic hydrocarbons vorgelegt von Haijing Wang 2015 XIII, 92 Bl. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Cottbus-Senftenberg, Techn. Univ., Diss., 2015 Untersuchungsmethode (DE-588)4324907-3 gnd rswk-swf Kohlenwasserstoffe (DE-588)4125165-9 gnd rswk-swf Boden (DE-588)4007348-8 gnd rswk-swf Rohöl (DE-588)4178355-4 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Boden (DE-588)4007348-8 s Rohöl (DE-588)4178355-4 s Kohlenwasserstoffe (DE-588)4125165-9 s Untersuchungsmethode (DE-588)4324907-3 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028023361&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Wang, Haijing Determination method and soil emission behavior of crude oil volatile organic and polycyclic aromatic hydrocarbons Untersuchungsmethode (DE-588)4324907-3 gnd Kohlenwasserstoffe (DE-588)4125165-9 gnd Boden (DE-588)4007348-8 gnd Rohöl (DE-588)4178355-4 gnd |
| subject_GND | (DE-588)4324907-3 (DE-588)4125165-9 (DE-588)4007348-8 (DE-588)4178355-4 (DE-588)4113937-9 |
| title | Determination method and soil emission behavior of crude oil volatile organic and polycyclic aromatic hydrocarbons |
| title_auth | Determination method and soil emission behavior of crude oil volatile organic and polycyclic aromatic hydrocarbons |
| title_exact_search | Determination method and soil emission behavior of crude oil volatile organic and polycyclic aromatic hydrocarbons |
| title_full | Determination method and soil emission behavior of crude oil volatile organic and polycyclic aromatic hydrocarbons vorgelegt von Haijing Wang |
| title_fullStr | Determination method and soil emission behavior of crude oil volatile organic and polycyclic aromatic hydrocarbons vorgelegt von Haijing Wang |
| title_full_unstemmed | Determination method and soil emission behavior of crude oil volatile organic and polycyclic aromatic hydrocarbons vorgelegt von Haijing Wang |
| title_short | Determination method and soil emission behavior of crude oil volatile organic and polycyclic aromatic hydrocarbons |
| title_sort | determination method and soil emission behavior of crude oil volatile organic and polycyclic aromatic hydrocarbons |
| topic | Untersuchungsmethode (DE-588)4324907-3 gnd Kohlenwasserstoffe (DE-588)4125165-9 gnd Boden (DE-588)4007348-8 gnd Rohöl (DE-588)4178355-4 gnd |
| topic_facet | Untersuchungsmethode Kohlenwasserstoffe Boden Rohöl Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=028023361&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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