Polypeptoid block copolymers: synthesis, modification, and structure formation
Gespeichert in:
| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2014
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XVII, 128 S. graph. Darst. |
Internformat
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| 245 | 1 | 0 | |a Polypeptoid block copolymers |b synthesis, modification, and structure formation |c von Christian Secker |
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| 300 | |a XVII, 128 S. |b graph. Darst. | ||
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| 502 | |a Potsdam, Univ., Diss., 2014 | ||
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| 650 | 0 | 7 | |a Blockcopolymere |0 (DE-588)4146026-1 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Polypeptide |0 (DE-588)4175278-8 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Glycin |0 (DE-588)4157727-9 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Polypeptide |0 (DE-588)4175278-8 |D s |
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Datensatz im Suchindex
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| adam_text | V. TABLE OF CONTENTS
I. EIDESSTATTLICHE ERKLARUNG II
II. ACKNOWLEDGEMENT III
III. DEDICATION IV
IV. ABSTRACT V
V. TABLE OF CONTENTS VII
VI. TABLE OF FIGURES X
VII. LIST OF TABLES XV
VIII. TABLE OF ABBREVIATIONS XVI
1. INTRODUCTION 1
2. FUNDAMENTAL PRINCIPLES 3
2.1. POLYPEPTOID SYNTHESIS 3
2.1.1. MONOMER 3
2.1.2. RING OPENING POLYMERIZATION - ROP 4
2.2. BLOCK COPOLYMER PHASE BEHAVIOR 8
2.2.1. BULK SEGREGATION 8
2.2.2. SELF-ASSEMBLY IN SOLUTION 11
2.2.3. PHASE BEHAVIOR OF POLYPEPTOID COPOLYMERS 12
2.3. THERMORESPONSIVE POLYMERS 13
2.3.1. IDEAL SOLUTION 14
2.3.2. POLYMER SOLUTION - ENTROPY CONTRIBUTION 15
2.3.3. POLYMER SOLUTION - ENTHALPY CONTRIBUTION AND CRITICAL SOLUTION
BEHAVIOR 17
2.3.4. THERMORESPONSIVE BEHAVIOR OF POLYPEPTOIDS 21
2.4. POLYMER CRYSTALLIZATION 22
2.4.1. NUCLEATION AND GROWTH 22
2.4.2. CRYSTALLIZATION OF POLYPEPTOIDS 24
2.5. CLICK REACTIONS IN POLYMER CHEMISTRY 26
2.5.1. THIOL-YNE AND ALKYNE-AZIDE CLICK REACTIONS 26
2.5.2. CLICK REACTIONS APPLIED TO POLYPEPTOIDS 27
2.6. SELECTED METHODS 28
2.6.1. (MICRO) DIFFERENTIAL SCANNING CALORIMETRY - ^DSC AND DSC 28
2.6.2. LIGHT SCATTERING 29
2.7. SUMMARY OF LITERATURE STUDY 34
VII
HTTP://D-NB.INFO/1069776300
3. RESEARCH OBJECTIVE 35
4. RESULTS AND DISCUSSION 37
4.1. THERMAL INDUCED SELF-ASSEMBLY 37
4.1.1. PHASE- AND CRYSTALLIZATION BEHAVIOR OF POLY
(IV
-N-PROPYL GLYCINE) 37
4.1.2. POLY(/V-N-PROPYL GLYCINE)-B-POLY(W-METHYL GLYCINE) BLOCK
COPOLYMERS 43
4.1.3. SUMMARY 55
4.2. SOLVENT INDUCED SELF-ASSEMBLY 56
4.2.1. POST-MODIFICATION POTENTIAL OF POLY(./V-PROPARGYL GLYCINE) 57
4.2.2. SUMMARY 71
4.2.3. POLY(7V-PROPARGYL GLYCINE)-B-POLY(/V-METHYL GLYCINE) BLOCK
COPOLYMERS 72
4.2.4. SUMMARY 79
5. CONCLUSION 80
6. OUTLOOK 82
7. EXPERIMENTAL SECTION 85
7.1. MATERIALS 85
7.2. REACTION MONITORING AND LOW MOLAR MASS COMPOUND ANALYSIS 85
7.3. MOLAR MASS CHARACTERIZATION OF POLYMERS 86
7.4. PHASE BEHAVIOR OF POLYMERS 87
7.4.1. THERMORESPONSIVNESS 87
7.4.2. AGGREGATE CHARACTERIZATION 88
7.5. THERMAL ANALYSIS 89
7.6. WIDE-ANGLE X-RAY SCATTERING 90
7.7. ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY 90
7.8. SOLID STATE NMR 90
7.9. MONOMER SYNTHESIS 91
7.10. POLYMER SYNTHESIS 92
7.10.1. POLY^-N-PROPY^-B-POLY^-METHYL GLYCINE) SERIES 92
7.10.2. POLY(7V-PROPARGYL GLYCINE) POST-MODIFICATIONS 94
7.10.3. POLY(./V-PROPARGYL GLYCINE)-B-POLY(7V-METHYL GLYCINE) SERIES 98
8. LITERATURE 102
9. SUPPORTING INFORMATION 109
9.1. DSC DATA 109
9.1.1. TABULATED |IDSC AND PHOTOTURBIMETRY RESULTS 109
9.1.2. TABULATED DSC RESULTS 110
VIII
9.1.3. ADDITIONAL DSC CURVES 111
9.2. SLS DATA 114
9.3. ACTIVATION ENERGY CALCULATION 115
9.4. NMR DATA 117
9.5.FTIR DATA 126
9.6. SEC DATA 127
IX
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| any_adam_object | 1 |
| author | Secker, Christian 1985- |
| author_GND | (DE-588)1068827424 |
| author_facet | Secker, Christian 1985- |
| author_role | aut |
| author_sort | Secker, Christian 1985- |
| author_variant | c s cs |
| building | Verbundindex |
| bvnumber | BV042480771 |
| ctrlnum | (OCoLC)909791369 (DE-599)GBV820793272 |
| dewey-full | 668.9 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 668 - Technology of other organic products |
| dewey-raw | 668.9 |
| dewey-search | 668.9 |
| dewey-sort | 3668.9 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| id | DE-604.BV042480771 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T01:22:58Z |
| institution | BVB |
| language | English |
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| physical | XVII, 128 S. graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
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| spelling | Secker, Christian 1985- Verfasser (DE-588)1068827424 aut Polypeptoid block copolymers synthesis, modification, and structure formation von Christian Secker 2014 XVII, 128 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Potsdam, Univ., Diss., 2014 Selbstorganisation (DE-588)4126830-1 gnd rswk-swf Blockcopolymere (DE-588)4146026-1 gnd rswk-swf Polypeptide (DE-588)4175278-8 gnd rswk-swf Glycin (DE-588)4157727-9 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Polypeptide (DE-588)4175278-8 s Glycin (DE-588)4157727-9 s Blockcopolymere (DE-588)4146026-1 s Selbstorganisation (DE-588)4126830-1 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027915751&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Secker, Christian 1985- Polypeptoid block copolymers synthesis, modification, and structure formation Selbstorganisation (DE-588)4126830-1 gnd Blockcopolymere (DE-588)4146026-1 gnd Polypeptide (DE-588)4175278-8 gnd Glycin (DE-588)4157727-9 gnd |
| subject_GND | (DE-588)4126830-1 (DE-588)4146026-1 (DE-588)4175278-8 (DE-588)4157727-9 (DE-588)4113937-9 |
| title | Polypeptoid block copolymers synthesis, modification, and structure formation |
| title_auth | Polypeptoid block copolymers synthesis, modification, and structure formation |
| title_exact_search | Polypeptoid block copolymers synthesis, modification, and structure formation |
| title_full | Polypeptoid block copolymers synthesis, modification, and structure formation von Christian Secker |
| title_fullStr | Polypeptoid block copolymers synthesis, modification, and structure formation von Christian Secker |
| title_full_unstemmed | Polypeptoid block copolymers synthesis, modification, and structure formation von Christian Secker |
| title_short | Polypeptoid block copolymers |
| title_sort | polypeptoid block copolymers synthesis modification and structure formation |
| title_sub | synthesis, modification, and structure formation |
| topic | Selbstorganisation (DE-588)4126830-1 gnd Blockcopolymere (DE-588)4146026-1 gnd Polypeptide (DE-588)4175278-8 gnd Glycin (DE-588)4157727-9 gnd |
| topic_facet | Selbstorganisation Blockcopolymere Polypeptide Glycin Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027915751&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT seckerchristian polypeptoidblockcopolymerssynthesismodificationandstructureformation |