Lanthanides and actinides in molecular magnetism:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2015
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XVIII, 346 S. Ill., graph. Darst. |
| ISBN: | 3527335269 9783527335268 9783527673476 |
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MARC
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| 245 | 1 | 0 | |a Lanthanides and actinides in molecular magnetism |c ed. by. Richard A. Layfield ... |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2015 | |
| 300 | |a XVIII, 346 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
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Datensatz im Suchindex
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V
CONTENTS
PREFACE XIII
LIST OF CONTRIBUTORS XV
1 ELECTRONIC STRUCTURE AND MAGNETIC PROPERTIES OF LANTHANIDE MOLECULAR
COMPLEXES 1
LORENZO SORACE
AND DANTE GATTESCHI
1.1 INTRODUCTION 1
1.2 FREE ION ELECTRONIC STRUCTURE 3
1.2.1 FREE ION MAGNETISM
6
1.3 ELECTRONIC STRUCTURE OF LANTHANIDE IONS IN A LIGAND FIELD 7
1.3.1 STEVENS' FORMALISM 9
1.3.2 WYBOURNE'S FORMALISM 9
1.3.3 STANDARDIZATION 13
1.3.4 CALCULATION OF CRYSTAL FIELD PARAMETERS 13
1.4 MAGNETIC PROPERTIES OF ISOLATED LANTHANIDE IONS 16
1.4.1 EFFECT OF A MAGNETIC FIELD 16
1.4.2 EPR SPECTROSCOPY OF LANTHANIDE COMPLEXES 17
1.5 EXCHANGE COUPLING IN SYSTEMS CONTAINING ORBITALLY DEGENERATE
LANTHANIDES 21
ACKNOWLEDGEMENTS 23
REFERENCES 23
2 MONONUCLEAR LANTHANIDE COMPLEXES: USE OF THE CRYSTAL FIELD THEORY
TO DESIGN SINGLE-ION MAGNETS AND SPIN QUBITS
27
JUAN M. CLEMENTE-JUAN, EUGENIO CORONADO, AND
ALEJANDRO GAITA-ARIHO
2.1 INTRODUCTION 27
2.2 MODELLING THE MAGNETIC PROPERTIES OF LANTHANIDE SINGLE-ION
MAGNETS: THE USE OF THE CRYSTAL FIELD MODEL 29
2.2.1 THEORETICAL BACKGROUND 29
HTTP://D-NB.INFO/1058702866
VI | CONTENTS
2.2.2 HOW TO DETERMINE THE CRYSTAL-FIELD PARAMETERS: 1. THE ISHIKAWA
APPROACH 30
2.2.3 HOW TO DETERMINE THE CRYSTAL-FIELD PARAMETERS: 2. THE POINT CHARGE
ELECTROSTATIC MODEL 34
2.2.4 HOW TO DETERMINE THE CRYSTAL-FIELD PARAMETERS: 3. THE EFFECTIVE
POINT CHARGE MODEL 36
2.3 MAGNETO-STRUCTURAL CORRELATIONS FOR SOME TYPICAL SYMMETRIES 40
2.4 IMPACT OF LANTHANIDE COMPLEXES IN QUANTUM COMPUTING 44
2.4.1 QUANTUM COMPUTING PARADIGMS AND DESIGN CRITERIA 45
2.4.2 COMBINING PHYSICAL QUBIT IMPLEMENTATIONS WITH LANTHANIDE
COMPLEXES 48
2.4.3 MOLECULAR SPIN QUBITS 50
2.5 CONCLUSIONS 53
ACKNOWLEDGEMENTS 54
REFERENCES 55
3 POLYNUCLEAR LANTHANIDE SINGLE MOLECULE MAGNETS
61
JINKUI TANG AND PENG ZHANG
3.1 INTRODUCTION 61
3.2 SYNTHETIC STRATEGIES 62
3.2.1 DY
3
TRIANGLES AND THEIR DERIVATIVES 64
3.2.1.1 SEMINAL DY
3
TRIANGLE 64
3.2.1.2 OTHER TRIANGULAR DY
3
SYSTEMS 65
3.2.1.3 THE COUPLING OF DY
3
TRIANGLES
68
3.2.2 LINEAR POLYNUCLEAR LANTHANIDE COMPLEXES SHOWING ROBUST SMM
BEHAVIOUR 71
3.2.2.1 LINEAR DY
3
SMMS 72
3.2.2.2 LINEAR DY
4
SMMS 73
3.2.3 PLANAR DY
4
SMMS 75
3.2.4 DY* SMMS HAVING MULTIPLE |I*-0 ( 4) BRIDGES 78
3.2.4.1 THE DY
4
GRIDS FIXED BY N
4
-0 ATOM 78
3.2.4.2 THE DY
4
TETRAHEDRON FIXED BY |I
4
-0 ATOM 80
3.2.4.3 THE DY
5
PYRAMID FIXED BY |I
5
-0 ATOM 80
3.2.5 HYDRAZONE-BASED LANTHANIDE SMMS 82
3.2.5.1 THE ASSEMBLY OF DY
6
TRIANGULAR PRISM WITH DY
2
UNITS 83
3.2.5.2 A DY
3
MOLECULAR CLUSTER PAIR (DY
6
) 84
3.2.6 THE ORGANOMETALLIC SYNTHESIS * A NEW APPROACH 85
3.3 CONCLUSION
86
REFERENCES
86
4
4.1
LANTHANIDES IN EXTENDED MOLECULAR NETWORKS
89
ROBERTA SESSOLI
AND KEVIN BERNOT
INTRODUCTION 89
CONTENTS VII
4.2 EXTENDED NETWORKS BASED ON GD
3+
91
4.2.1 METAL-ORGANIC FRAMEWORKS 91
4.2.1.1 MAGNETO-CALORIC EFFECT 91
4.2.1.2 SLOW MAGNETIC RELAXATION AND PHONON BOTTLENECK EFFECTS 94
4.2.2 MAGNETIC CHAINS 96
4.2.2.1 MAGNETIC INTERACTIONS INVOLVING GD
3+
IONS 96
4.2.2.2 GADOLINIUM-RADICAL CHAINS 96
4.3 EXTENDED NETWORKS BASED ON ANISOTROPIC IONS 101
4.3.1 SCM IN A NUTSHELL 101
4.3.2 AN OVERVIEW OF MONODIMENSIONAL LANTHANIDE CHAINS BASED ON
ANISOTROPIC IONS 104
4.3.2.1 CHAINS BASED ON 4F IONS 104
4.3.2.2 CHAINS BASED ON 3D-4F IONS 106
4.3.2.3 CHAINS BASED ON RADICALS AND 4F IONS 111
4.3.3 THE KEY POINT OF NONCOLLINEARITY OF MAGNETIC ANISOTROPY 112
4.4 CONCLUSIONS 119
REFERENCES 119
5 EXPERIMENTAL ASPECTS OF LANTHANIDE SINGLE-MOLECULE MAGNET
PHYSICS
125
KASPER
5.
PEDERSEN,
DANIEL N. WOODRUFF, JESPER BENDIX,
AND RODOLPHE CLERAC
5.1 INTRODUCTION 125
5.2 MANIFESTATION OF SINGLE-MOLECULE MAGNET BEHAVIOUR 127
5.2.1 MAGNETIZATION AND AC SUSCEPTIBILITY MEASUREMENTS 127
5.2.2 NMR SPECTROSCOPY 132
5.2.3 MUON SPIN ROTATION 133
5.3 QUANTIFYING THE MAGNETIC ANISOTROPY 135
5.4 SPLITTING OF THE GROUND MULTIPLET 139
5.4.1 MAGNETIC RESONANCE SPECTROSCOPIES 139
5.4.2 LUMINESCENCE SPECTROSCOPY 140
5.4.3 INELASTIC NEUTRON SCATTERING 141
5.5 OBSERVATION OF THE SIGNATURES OF EXCHANGE COUPLING 146
5.5.1 CHEMICAL SUBSTITUTION 146
5.5.2 X-RAY MAGNETIC CIRCULAR DICHROISM 147
5.6 CONCLUDING REMARKS AND PERSPECTIVES 149
REFERENCES 150
6 COMPUTATIONAL MODELLING OF THE MAGNETIC PROPERTIES OF LANTHANIDE
COMPOUNDS
153
LIVIU
UNGURAND LIVIU F. CHIBOTARU
6.1 INTRODUCTION 153
6.2 AB INITIO DESCRIPTION OF LANTHANIDES AND ITS RELATION TO OTHER
METHODS 153
VIII | CONTENTS
6.2.1 AB INITIO APPROACH FOR THE ELECTRONIC STRUCTURE OF LANTHANIDES 155
6.2.1.1 ACCOUNTING FOR STATIC ELECTRON CORRELATION WITHIN CASSCF 155
6.2.1.2 ACCOUNTING FOR DYNAMICAL ELECTRON CORRELATION: AN IMPORTANT STEP
TOWARDS ACCURATE PREDICTIONS 155
6.2.1.3 ACCOUNTING FOR RELATIVISTIC EFFECTS WITHIN THE DOUGLAS - KROLL
- HESS
THEORY 156
6.2.1.4 SPIN-ORBIT MULTIPLETS OF FREE LANTHANIDE IONS: RELATIVISTIC
CASSCF/RASSI METHOD IN WORK 157
6.2.2 AB INITIO VERSUS TWO-COMPONENT DFT 159
. 6.2.3 AB INITIO VERSUS PHENOMENOLOGICAL CRYSTAL FIELD THEORY FOR
LANTHANIDES 159
6.3 AB INITIO CALCULATION OF ANISOTROPIC MAGNETIC PROPERTIES
OF MONONUCLEAR COMPLEXES 160
6.3.1 IMPLEMENTATION OF AB INITIO METHODOLOGY: SINGLE_ANISO
PROGRAM 161
6.3.2 TEMPERATURE-DEPENDENT MAGNETIC SUSCEPTIBILITY AND
FIELD-DEPENDENT MAGNETIZATION 163
6.3.3 MAGNETIC ANISOTROPY IN LOW-LYING DOUBLETS 164
6.3.4 AB INITIO CRYSTAL FIELD 166
6.4 AB INITIO CALCULATION OF ANISOTROPIC MAGNETIC PROPERTIES
OF POLYNUCLEAR COMPLEXES 169
6.4.1 TWO-STEP APPROACH FOR THE CALCULATION OF ELECTRONIC STRUCTURE
OF POLYNUCLEAR LANTHANIDE COMPLEXES 170
6.4.2 KEY RULES FOR CLUSTER FRAGMENTATION 170
6.4.3 IMPLEMENTATION OF AB INITIO METHODOLOGY: POLY_ANISO
PROGRAM 171
6.4.4 NONCOLLINEAR MAGNETIC STRUCTURE OF LN* COMPLEXES 172
6.4.5 MIXED LANTHANIDE-TRANSITION METAL COMPOUNDS 176
6.4.6 LANTHANIDE-CONTAINING MAGNETIC CHAINS 178
6.5 CONCLUSIONS 180
REFERENCES 181
7 LANTHANIDE COMPLEXES AS REALIZATIONS OF QUBITS AND QUGATES
FOR QUANTUM COMPUTING
185
GUILLEM AROML, FERNANDO LUIS,
AND OLIVIER ROUBEAU
7.1 INTRODUCTION TO QUANTUM COMPUTATION 185
7.1.1 GENERAL INTRODUCTION 185
7.1.2 DEFINITION OF QUBITS, QUGATES, TIMESCALES AND ESSENTIAL
REQUIREMENTS 186
7.1.3 CURRENT PROPOSALS FOR THE QC HARDWARE 189
7.1.3.1 TRAPPED IONS 189
7.1.3.2 NUCLEAR SPINS 190
7.1.3.3 SUPERCONDUCTING QUBITS 191
CONTENTS IX
7.1.3.4 SPIN QUBITS 191
7.1.3.5 PHOTONS 191
7.1.3.6 HYBRID PROPOSALS AND QUANTUM CIRCUITS 192
7.2 QUANTUM COMPUTING WITH ELECTRON SPIN QUBITS 192
7.2.1 ELECTRONIC SPINS IN SEMICONDUCTORS: QDS AND DOPANTS 192
7.2.1.1 QUANTUM DOTS 193
7.2.1.2 DOPANTS AND DEFECTS 193
7.2.2 ELECTRONIC SPINS IN MOLECULES: ORGANIC RADICALS AND TRANSITION
METAL COMPLEXES 194
7.2.2.1 ORGANIC RADICALS 194
7.2.2.2 TRANSITION METAL COMPLEXES 195
7.3 SINGLE LANTHANIDE IONS AS SPIN QUBITS 197
7.3.1 QUANTUM COHERENCE OF LANTHANIDE IONS DOPED INTO CRYSTALLINE
SOLIDS 198
7.3.2 CONTROL OF THE MAGNETIC ANISOTROPY OF LANTHANIDE IONS: CHEMICAL
DESIGN OF SPIN QUBITS 199
7.3.2.1 MONONUCLEAR SINGLE MOLECULE MAGNETS 199
7.3.2.2 GADOLINIUM(III) POMS AS SPIN QUBITS 200
7.3.2.3 MONONUCLEAR SMMS OF LN(III) IONS WITH NONZERO ORBITAL
MOMENT 202
7.4 LANTHANIDE MOLECULES AS PROTOTYPES OF TWO-QUBIT QUANTUM
GATES 204
7.4.1 A FAMILY OF ASYMMETRIC [LN
2
] COMPLEXES WITH WEAK MAGNETIC
COUPLING 204
7.4.2 HETEROMETALLIC [LNLN'] COMPLEXES: A FABRIC OF CHEMICAL
ASYMMETRY AND INDIVIDUAL QUBITS 208
7.4.3 EVALUATING QUBIT PROPERTIES 209
7.4.4 WEAK COUPLING 211
7.4.5 ASYMMETRY AND ENERGY DIAGRAMS 212
7.4.6 DECOHERENCE OF THE MOLECULAR QUANTUM PROCESSOR PROTOTYPES 215
7.5 CONCLUSIONS AND OUTLOOK 215
REFERENCES 216
8 BIS(PHTHALOCYANINATO) LANTHANIDE(LLL) COMPLEXES - FROM MOLECULAR
MAGNETISM TO SPINTRONIC DEVICES
223
YANHUA LAN, SVETLANA KLYATSKAYA,
AND MARIO RUBEN
8.1 INTRODUCTION 223
8.1.1 MOLECULAR MAGNETISM 223
8.1.2 MULTINUCLEAR VERSUS MONONUCLEAR: D- VERSUS F-METAL IONS 224
8.1.3 MOLECULAR VERSUS ORGANIC SPINTRONICS 227
8.2 SYNTHESIS AND STRUCTURE OF LNPC
2
COMPLEXES 229
8.2.1 SYNTHESIS OF BIS(PHTHALOCYANINATO) LANTHANIDE(III) COMPLEXES 229
X | CONTENTS
8.2.2 SYNTHESIS OF HETEROLEPTIC LANTHANIDE(III) COMPLEXES CONTAINING
PORPHYRIN-BASED LIGANDS 235
8.2.3 OXIDATION STATES OF BIS(PHTHALOCYANINATO) LANTHANIDE(III)
COMPLEXES 239
8.2.4 ROTATION ANGLES AND SKEW ANGLES IN LNPC
2
IN RELATION TO THE
LANTHANIDE CONTRACTION 243
8.3 BULK MAGNETISM OF LNPC
2
COMPLEXES 246
8.3.1 MAGNETISM OF BIS(PHTHALOCYANINATO) LANTHANIDE(LII)
COMPLEXES 246
8.3.2 THREE SPIN SYSTEMS IN [TBPC
2
] SINGLE-ION MOLECULAR MAGNETS
(SIMMS) 246
8.3.2.1 THE ORGANIC RADICAL (S) 246
8.3.2.2 THE ELECTRONIC SPIN (J) 248
8.3.2.3 THE NUCLEAR SPIN (I) 249
8.3.3 FURTHER SIMS OF LNPC
2
WITH LN = TB, DY AND HO 249
8.3.4 INTERNAL KONDO IN LNPC
2
COMPLEXES WITH LN = CE, YB 255
8.3.5 STABLE ORGANIC RADICALS S = 1/2 IN LNPC
2
WITH LN = Y, LU 257
8.3.6 A SPECIAL CASE: HALF-FILLING OF THE F-ORBITALS IN GDPC
2
AND ITS
CONSEQUENCES 258
8.4 SURFACE MAGNETISM OF LNPC
2
COMPLEXES 259
8.4.1 DEPOSITION OF [TBPC
2
] SIMMS ON NONMAGNETIC
SUBSTRATES 261
8.4.1.1 HIGHLY ORIENTED PYROLITIC GRAPHITE 261
8.4.1.2 AU(LLL) 262
8.4.1.3 CU(LLL) 263
8.4.1.4 CU(100) 265
8.4.2 DEPOSITION OF [TBPC
2
] SIMS ON MAGNETIC SUBSTRATES 267
8.4.2.1 NICKEL THIN FILMS 267
8.4.2.2 COBALT THIN FILMS 269
8.4.2.3 LSMO 269
8.4.2.4 MANGANESE AND COBALT OXIDE LAYERS 269
8.4.2.5 SPIN POLARIZED SCANNING TUNNELLING MICROSCOPY (SP-STM)
ON CO/IR(LLL) 270
8.5 MOLECULAR SPINTRONIC DEVICES ON THE BASE
OF [TBPC
2
] SIMS 272
8.5.1 GRAPHENE TRANSISTOR 274
8.5.2 SUPRAMOLECULAR SPIN VALVE 276
8.5.3 MOLECULAR SPIN RESONATOR 278
8.5.4 MOLECULAR SPIN TRANSISTOR 280
8.6 CONCLUSION AND OUTLOOK 281
ABBREVIATIONS 283
REFERENCES 284
CONTENTS XI
9 LANTHANIDES AND THE MAGNETOCALORIC EFFECT
293
JOSEPH W. SHARPIES AND DAVID COLLISON
9.1 APPLICATIONS OF MAGNETS 293
9.2 COLD REASONING 294
9.3 CURRENT TECHNOLOGIES 294
9.4 HOW PARAMAGNETS ACT AS REFRIGERANTS 295
9.5 MORE PARAMETERS 297
9.6 AIMS 298
9.7 IMPORTANT CONCEPTS FOR A LARGE MAGNETOCALORIC EFFECT 298
9.7.1 SPIN 298
9.7.1.1 EXAMPLES 299
9.7.2 NATURE OF EXCHANGE COUPLING 301
9.7.2.1 PARAMAGNETISM 301
9.7.2.2 FERROMAGNETISM 303
9.7.2.3 ANTIFERROMAGNETISM 304
9.7.3 ACTIVE METAL PERCENTAGE 305
9.7.4 DENSITY 307
9.7.5 ANISOTROPY OR SPIN: WHAT KIND? 308
9.7.6 DIMENSIONALITY 310
9.8 HIGH-PERFORMANCE MCE MATERIALS 311
9.9 OUTLOOK 312
REFERENCES 313
10 ACTINIDE SINGLE-MOLECULE MAGNETS
315
STEPHEN T. LIDDLE
ANDJORIS VAN SLAGEREN
10.1 INTRODUCTION 315
10.2 LITERATURE SURVEY OF PUBLISHED ACTINIDE SINGLE-MOLECULE
MAGNETS 322
10.2.1 SINGLE-MOLECULE MAGNETS OF F
3
ACTINIDES (U
3+
, NP
4+
) 322
10.2.2 SINGLE-MOLECULE MAGNETS OF F
1
ACTINIDES (U
5+
) 330
10.2.3 MISCELLANEOUS: {NP
VI
0
2
CL
2
}{NP
V
0,CL(THF)
3
}, (15) 332
10.3 MAGNETIC COUPLING IN ACTINIDES 332
10.3.1 5F-5F COUPLINGS 333
10.3.2 5F-4F COUPLINGS 335
10.3.3 5F-3D COUPLINGS 335
10.3.4 5F-2P COUPLINGS 336
10.4 CONCLUSIONS 336
REFERENCES 336
INDEX
341 |
| any_adam_object | 1 |
| author2 | Layfield, Richard A. |
| author2_role | edt |
| author2_variant | r a l ra ral |
| author_facet | Layfield, Richard A. |
| building | Verbundindex |
| bvnumber | BV042477382 |
| classification_rvk | VE 9000 VH 8048 |
| ctrlnum | (OCoLC)892071758 (DE-599)DNB1058702866 |
| dewey-full | 546.41 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
| dewey-raw | 546.41 |
| dewey-search | 546.41 |
| dewey-sort | 3546.41 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV042477382 |
| illustrated | Illustrated |
| indexdate | 2024-08-03T02:16:30Z |
| institution | BVB |
| isbn | 3527335269 9783527335268 9783527673476 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027912426 |
| oclc_num | 892071758 |
| open_access_boolean | |
| owner | DE-11 DE-19 DE-BY-UBM |
| owner_facet | DE-11 DE-19 DE-BY-UBM |
| physical | XVIII, 346 S. Ill., graph. Darst. |
| publishDate | 2015 |
| publishDateSearch | 2015 |
| publishDateSort | 2015 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Lanthanides and actinides in molecular magnetism ed. by. Richard A. Layfield ... Weinheim Wiley-VCH 2015 XVIII, 346 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Actinoide (DE-588)4141330-1 gnd rswk-swf Lanthanoide (DE-588)4074013-4 gnd rswk-swf Molekularer Nanomagnet (DE-588)104638838X gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Lanthanoide (DE-588)4074013-4 s Actinoide (DE-588)4141330-1 s Molekularer Nanomagnet (DE-588)104638838X s DE-604 Layfield, Richard A. edt Erscheint auch als Online-Ausgabe, EPUB 978-3-527-67349-0 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-67348-3 Erscheint auch als Online-Ausgabe, PDF 978-3-527-67350-6 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4783431&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027912426&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Lanthanides and actinides in molecular magnetism Actinoide (DE-588)4141330-1 gnd Lanthanoide (DE-588)4074013-4 gnd Molekularer Nanomagnet (DE-588)104638838X gnd |
| subject_GND | (DE-588)4141330-1 (DE-588)4074013-4 (DE-588)104638838X (DE-588)4143413-4 |
| title | Lanthanides and actinides in molecular magnetism |
| title_auth | Lanthanides and actinides in molecular magnetism |
| title_exact_search | Lanthanides and actinides in molecular magnetism |
| title_full | Lanthanides and actinides in molecular magnetism ed. by. Richard A. Layfield ... |
| title_fullStr | Lanthanides and actinides in molecular magnetism ed. by. Richard A. Layfield ... |
| title_full_unstemmed | Lanthanides and actinides in molecular magnetism ed. by. Richard A. Layfield ... |
| title_short | Lanthanides and actinides in molecular magnetism |
| title_sort | lanthanides and actinides in molecular magnetism |
| topic | Actinoide (DE-588)4141330-1 gnd Lanthanoide (DE-588)4074013-4 gnd Molekularer Nanomagnet (DE-588)104638838X gnd |
| topic_facet | Actinoide Lanthanoide Molekularer Nanomagnet Aufsatzsammlung |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=4783431&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027912426&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT layfieldricharda lanthanidesandactinidesinmolecularmagnetism |