Green extraction of natural products: theory and practice
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| Format: | Buch |
| Sprache: | English |
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[2015]
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| Beschreibung: | XVIII, 363 S. Ill., graph. Darst. 244 mm x 170 mm |
| ISBN: | 3527336532 9783527336531 9783527676828 |
Internformat
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| 245 | 1 | 0 | |a Green extraction of natural products |b theory and practice |c ed. by Farid Chemat ... |
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Datensatz im Suchindex
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| adam_text |
CONTENTS
PREFACE
XIII
LIST OF CONTRIBUTORS
XV
1 GREEN EXTRACTION: FROM CONCEPTS TO RESEARCH, EDUCATION, AND
ECONOMICAL OPPORTUNITIES 1
FARID CHEMAT,
NATACHA ROMBAUT, ANNE-SYLVIE
FABIANO-TIXIER, JEAN
T.
PIERSON, ANDANTOINE
BILY
1.1 INTRODUCTION 1
1.2 ORANGE FRUIT IS NOT LIMITED TO PRODUCE ONLY JUICE? 5
1.3 CHEMISTRY OF NATURAL PRODUCTS 9
1.3.1 PRIMARY METABOLITES 9
1.3.1.1 GLUCIDES 9
1.3.1.2 LIPIDS 10
1.3.1.3 AMINO ACIDS AND PROTEINS 10
1.3.2 SECONDARY METABOLITES 12
1.3.2.1 TERPENOIDS 12
1.3.2.2 ALKALOIDS 14
1.3.2.3 POLYPHENOLS 14
1.4 FROM METABOLITES TO INGREDIENTS 17
1.5 GREEN EXTRACTION FROM RESEARCH TO TEACHING 22
1.5.1 PRINCIPLE: INNOVATION BY SELECTION OF VARIETIES AND USE OF
RENEWABLE
PLANT RESOURCES 28
1.5.2 PRINCIPLE: USE OF ALTERNATIVE SOLVENTS AND AGRO SOLVENT 28
1.5.3 PRINCIPLE: PRODUCTION OF COPRODUCTS INSTEAD OF WASTE TO INCLUDE
BIOREFINERY 29
1.5.4 PRINCIPLE: PRIORITIZING A NON-DENATURED AND BIODEGRADABLE EXTRACT
WITHOUT CONTAMINANT 29
1.6 CONCLUSIONS AND PERSPECTIVE 29
REFERENCES 30
HTTP://D-NB.INFO/1056932473
VI | CONTENTS
2
2.1
2.2
2.3
2.3.1
2.3.2
2.3.3
2.3.4
2.3.4.1
2.3.4.2
2.3.4.3
2.3.4.4
2.3.4.5
2.4
2.4.1
2.4.2
2.4.3
2.5
2.5.1
2.5.2
2.6
2.7
3
3.1
3.2
3.2.1
3.2.2
3.2.3
3.3
3.3.1
3.3.2
3.3.3
3.3.4
3.4
3.4.1
3.4.2
3.4.3
3.4.4
3.4.4.1
PROCESS ENGINEERING AND PRODUCT DESIGN FOR GREEN EXTRACTION
37
SIMON BOTH, REINHARD DITZ,
MARTIN TEGTMEIER,
URBAN JENELTEN,
ANDJOCHEN
ST RUBE
MARKET AND MARKET DEVELOPMENT 37
REGULATORY FRAMEWORK 38
SYSTEMATIC APPARATUS AND PROCESS DESIGN 39
DESIGN OF EXPERIMENTS 40
GRAPHICAL CALCULATION METHODS 40
PHYSICOCHEMICAL MODELING 41
APPROACHES FOR DESCRIPTION OF DIFFUSION 45
MAXWELL-STEFAN APPROACH 46
CALCULATION OF DIFFUSION COEFFICIENTS 48
THERMODYNAMIC FACTOR 49
DETERMINATION OF ACTIVITY COEFFICIENTS 49
PROOF OF PRINCIPLE 49
MODEL-BASED REALIZATION: APPARATUS AND PROCESS DESIGN 50
QUANTIFICATION OF DETERMINING FACTORS 52
PROOF OF PRINCIPLE - PROCESS OPTIMIZATION 53
PROOF OF PRINCIPLE - COST-DRIVEN DECISION 53
EXTRACT PURIFICATION 54
MODELING APPROACHES 56
SCALE-UP AND MINI-PLANT 56
TOTAL PROCESS DEVELOPMENT AND DESIGN 62
CONCLUSIONS AND SUMMARY 65
ACKNOWLEDGMENTS 66
REFERENCES 66
TAILOR-MADE PRODUCTION OF PLANTS FOR GREEN EXTRACTION
71
HANSJOERG HAGELS
INTRODUCTION 71
SUSTAINABLE PROCESSES 72
SOCIAL SUSTAINABILITY 73
ENVIRONMENTAL SUSTAINABILITY 74
ECONOMIC SUSTAINABILITY 75
PRODUCTION TECHNOLOGY 75
CHOICE OF CULTIVATION LOCATION 75
CROP ROTATION 78
FERTILIZATION 79
ORGANIC FARMING 82
SEED AND SEED STOCK 84
BREEDING 84
SEED
88
VEGETATIVE PROPAGATION
88
STOCK MAINTENANCE 89
DISEASES 89
CONTENTS VII
3.4.5 PESTS 90
3.4.5.1 WEED CONTROL 90
3.4.6 HARVESTING TECHNOLOGY 91
3.4.7 PURIFICATION OF HARVEST 91
3.4.8 MECHANICAL TREATMENT 91
3.4.9 THERMAL TREATMENT 91
3.4.9.1 NATURAL DRYING 92
3.4.9.2 ARTIFICIAL DRYING 92
3.5 QUALITY CRITERIA 92
3.5.1 QUALITY MANAGEMENT 92
3.5.2 QUALITY CONTROL 95
GLOSSARY AND ABBREVIATIONS 96
REFERENCES 96
FURTHER READING 99
4 MASS TRANSFER ENHANCEMENT FOR SOLID-LIQUID EXTRACTIONS
101
SIMON BOTH,
JOCHEN STRUBE,
AND GIANCARLO
CRAVATTO
4.1 INTRODUCTION 101
4.2 STATE OF THE ART SOLID-LIQUID EXTRACTION 102
4.2.1 BATCH PROCESSES 105
4.2.2 CONTINUOUS PROCESSES 106
4.2.3 HYDRO- AND STEAM DISTILLATION 109
4.2.4 ALEMBIC DISTILLATION 111
4.2.5 MECHANICAL EXPRESSION (EXTRUSION) 112
4.3 ENHANCEMENT OF SOLID-LIQUID EXTRACTION PROCESSES 115
4.3.1 MICROWAVE-ASSISTED EXTRACTION (MAE) 115
4.3.2 ULTRASOUND-ASSISTED EXTRACTION (UAE) 118
4.3.3 TURBO EXTRACTION 119
4.4 EXAMPLE PROCESSES FOR SOLID-LIQUID EXTRACTION ENHANCEMENT 122
4.4.1 EXTRACTION OF POLYPHENOLS FROM BLACK TEA - CONVENTIONAL AND
ULTRASOUND-ASSISTED EXTRACTION 122
4.4.1.1 MATERIAL AND METHODS 123
4.4.1.2 EQUIPMENT CONCEPTS 126
4.4.1.3 EQUILIBRIUM LINE BY MULTISTAGE MACERATION AND TOTAL
EXTRACTION 127
4.4.1.4 MASS TRANSPORT KINETICS 130
4.4.1.5 PARTICLE SIZE DISTRIBUTION 131
4.4.1.6 SEM MEASUREMENTS - CELL DISRUPTION 132
4.4.1.7 CONCLUSIONS 132
4.4.2 PILOT SCALE UAE OF CLOVE BUDS IN BATCH AND FLOW REACTORS 134
4.4.2.1 EXPERIMENTAL METHODS AND REACTORS 135
4.4.2.2 RESULTS AND DISCUSSION 137
4.4.2.3 CONCLUSIONS 139
4.4.3 UAE AND MAE OF LIPIDS FROM MICROALGAE 139
4.4.3.1 EXPERIMENTAL METHODS AND EQUIPMENTS 139
VIIII CONTENTS
4.4.3.2 CONCLUSIONS 141
4.5 CONCLUSION 141
SYMBOLS 142
REFERENCES 142
5 FUNDAMENTALS OF PROCESS-INTENSIFICATION STRATEGY FOR GREEN EXTRACTION
OPERATIONS
14S
TAMARA ALLAFAND KARIM ALLAF
5.1 PROCESS-INTENSIFICATION STRATEGY PI-S FROM HIGH CAPACITY TO HIGH
CONTROLLED QUALITY INDUSTRIAL MANUFACTURING 145
5.2 WHAT DOES "INTENSIFIED INDUSTRIAL MANUFACTURING" MEAN? 145
5.2.1 UNIT OPERATION PERFORMANCE 146
5.2.2 FINAL PRODUCT QUALITY 146
5.2.3 EQUIPMENT RELIABILITY 147
5.3 INTENSIFICATION STRATEGY AS A PLURIDIMENSIONAL APPROACH 148
5.3.1 OBJECTIVES OF INTENSIFICATION STRATEGY 148
5.3.2 SPECIFIC CASE OF FOOD INDUSTRY 148
5.3.3 PI-S AS A CONTINUAL PROGRESSING-DEVELOPMENT STRATEGY 148
5.4 FUNDAMENTALS FOR STARTING BASIS ANALYSES 149
5.4.1 INTENSIFICATION PROCEDURE 149
5.4.1.1 INTENSIFICATION CYCLE 149
5.4.1.2 MULTI-CYCLE INTENSIFICATION PROCEDURE 150
5.4.1.3 INTENSIFICATION CHARTER ISO
5.4.2 SPECIFICITIES OF INSTANT CONTROLLED PRESSURE DIC DROP IN PROCESS
INTENSIFICATION STRATEGY PI-S 151
5.4.2.1 INTRODUCTION 151
5.4.2.2 TRANSFER PHENOMENA IN INSTANTANEOUS CONTROLLED PRESSURE DROP
DIC TREATMENT 152
5.4.2.3 DIC - TEXTURING 155
5.4.3 MASS TRANSFER BY PERMEABILITY 156
5.5 PROCESSES OF EXTRACTION 158
5.5.1 EXTRACTION OF VOLATILE COMPOUNDS 158
5.5.1.1 KINETICS 159
5.5.1.2 INTENSIFICATION OF ESSENTIAL OIL EXTRACTION 161
5.5.2 CASE OF SOLVENT EXTRACTION 162
5.5.2.1 INTRODUCTION 162
5.5.2.2 EXTRACTION PROCESS ISSUES 162
5.5.2.3 KINETIC MODELING 166
5.5.3 CONCLUSION: PROCESS INTENSIFICATION STRATEGY. HOW TO USE PI-S
SOLVENT EXTRACTION PROCESSES? 168
5.6 CONCLUSION 170
REFERENCES 170
CONTENTS IX
6 PANORAMA OF SUSTAINABLE SOLVENTS FOR GREEN EXTRACTION
PROCESSES
173
IRAJ KOUDOUS,
WERNER KUNZ,
ANDJOCHEN STRUBE
6.1 INTRODUCTION 173
6.2 THERMODYNAMIC MODELS OF MIXING AND DISSOLVING 176
6.2.1 UN1FAC AND MODIFIED UNIFAC 176
6.2.2 THE HANSEN SOLUBILITY PARAMETERS 178
6.2.3 COSMO AND COSMO-RS 180
6.2.3.1 EXAMPLE 1: MUTUAL SOLUBILITY OF ACETONE WITH BENZENE,
CHLOROFORM,
AND CARBON DISULFIDE 183
6.2.3.2 EXAMPLE 2: SOLUBILITY SCREENING FOR INDIGO 184
6.3 SOLVENT SELECTION FOR GREEN SOLID-LIQUID EXTRACTION 187
6.3.1 GENERAL GREEN SOLVENT RANKING WITH COSMO-RS 188
6.3.2 CONCRETE EXAMPLE: SOLID-LIQUID EXTRACTION OF CARNESOL AND
CARNOSIC ACID FROM SAGE 188
6.3.3 EXPERIMENTAL VALIDATION OF COSMO-RS SOLVENT RANKING 192
6.3.4 CONCLUSION 192
6.4 ALTERNATIVE SOLVENTS FOR GREEN EXTRACTION 194
6.4.1 IONIC LIQUIDS 194
6.4.2 LOW-TRANSITION-TEMPERATURE MIXTURES AND DEEP EUTECTIC
SOLVENTS 196
6.4.3 IONIC LIQUIDS SCREENING WITH COSMO-RS 197
6.5 PURIFICATION STRATEGIES OF NATURAL PRODUCTS 199
6.5.1 DATABASED AND CALCULATED PHYSICOCHEMICAL PROPERTIES 204
6.5.2 FEED CHARACTERIZATION 213
6.5.2.1 CONCEPTUAL PROCESS DESIGN 216
6.5.2.2 MODELING DEPTHS AND FEED CHARACTERIZATION APPROACH 219
6.5.2.3 SYSTEM 1: VANILLIN 223
6.5.2.4 POTENTIAL UNIT OPERATIONS FOR PRODUCT PURIFICATION 223
6.5.2.5 DATA EVALUATION 225
6.5.2.6 MODEL-BASED PROCESS DESIGN AND CALCULATION OF SEPARATION
COSTS 225
6.5.2.7 SEPARATION COST ESTIMATION 228
6.5.2.8 SYSTEM 2: TEA AROMA 228
6.5.2.9 DATA FOR POTENTIAL UNIT OPERATION 228
6.5.2.10 PROCESS DESIGN AND COST ESTIMATION 229
6.5.2.11 DISCUSSION AND CONCLUSIONS 230
SYMBOLS 231
GREEK LETTERS 232
INDICES 232
REFERENCES 232
X | CONTENTS
7 WATER AS GREEN SOLVENT FOR EXTRACTION OF NATURAL PRODUCTS
237
LOIC PETIGNY, MUSTAFA ZAFER
3ZEL, SANDRINE PERINO,
JOEL WAJSMAN,
AND FARID
CHEMAT
7.1 INTRODUCTION 237
7.2 MACERATION 239
7.2.1 PRINCIPLE AND PROCESS 239
7.2.2 APPLICATIONS 240
7.3 SUBCRITICAL WATER EXTRACTION 243
7.3.1 PRINCIPLE AND PROCESS 243
7.3.2 APPLICATIONS 245
7.4 ENZYMATIC ASSISTANCE 248
7.4.1 PRINCIPLES AND PROCESS 248
7.4.2 APPLICATIONS 249
7.5 MICELLAR EXTRACTION 251
7.5.1 PRINCIPLE AND PROCESS 251
7.5.2 APPLICATIONS 252
7.6 HYDROTROPES 255
7.6.1 PRINCIPLES AND PROCESS 255
7.6.2 APPLICATIONS 256
7.7 CONCLUSION 259
REFERENCES 260
8 COVERAGE EXPLOITATION OF BY-PRODUCTS FROM THE AGROFOOD
INDUSTRY 265
CARLOS A. LEDESMA-ESCOBAR
AND MARIA D. LUQUE DE CASTRO
8.1 INTRODUCTION 265
8.2 TREATMENTS FOR SAFE DISPOSAL/EXPLOITATION OF AGROFOOD WASTES OR
RESIDUES 265
8.2.1 PHYSICAL PROCESSES 266
8.2.2 PHYSICOCHEMICAL PROCESSES 267
8.2.3 ADVANCED OXIDATION PROCESSES 267
8.2.4 THERMAL PROCESSES 268
8.2.5 BIOLOGICAL TREATMENTS 270
8.3 EXPLOITATION OF BY-PRODUCTS FROM OLIVE TREES AND OLIVE OIL
PRODUCTION 271
8.3.1 GENERALITIES 271
8.3.2 EXPLOITATION OF ALPECHIN 277
8.3.3 OVERALL USE OF EITHER ALPERUJO OR ORUJO 278
8.3.4 PARTIAL USE OF EITHER ALPECHIN OR ALPERUJO 279
8.3.5 OLIVE LEAF EXPLOITATION 280
8.3.6 FORESEEABLE/DESIRABLE FUTURE USES OF OLIVE TREE-OLIVE OIL
WASTES 280
8.4 EXPLOITATION OF BY-PRODUCTS FROM VINEYARDS AND WINE
PRODUCTION 283
8.4.1 GENERALITIES 283
CONTENTS XI
8.4.2 TYPES AND CHARACTERISTICS OF VINEYARD RESIDUES 286
8.4.3 PRESENT AND POTENTIAL EXPLOITATION OF VINEYARD RESIDUES 286
8.4.4 TYPES AND CHARACTERISTICS OF WINE RESIDUES 288
8.4.5 PRESENT AND POTENTIAL EXPLOITATION OF WINE RESIDUES: OVERALL AND
PARTIAL EXPLOITATION 288
8.5 EXPLOITATION OF BY-PRODUCTS FROM THE CITRUS JUICE INDUSTRY 291
8.5.1 GENERALITIES 291
8.5.2 USES AND POTENTIAL APPLICATIONS OF BIOACTIVE COMPOUNDS FROM
CITRUS RESIDUES 293
8.5.3 POTENTIAL EXPLOITATION OF CITRUS RESIDUES FOR ENERGY PRODUCTION
296
8.5.4 OTHER OVERALL AND PARTIAL USES OF CITRUS RESIDUES 297
ACKNOWLEDGMENTS 297
LIST OF ABBREVIATIONS 298
REFERENCES 298
9 SELECTIVE EXTRACTION FROM FOOD PLANTS AND RESIDUES BY PULSED ELECTRIC
FIELD
307
EUGENE VOROBIEV
AND NIKOLAI LEBOVKA
9.1 INTRODUCTION 307
9.2 BASICS OF PEF-ASSISTED EXTRACTION 308
9.3 APPLICATION OF PEF FOR DIFFERENT FOOD PLANTS AND RESIDUES 310
9.3.1 SUGAR BEETS 310
9.3.2 RED BEETS 313
9.3.3 CHICORY ROOTS 316
9.3.4 APPLES 317
9.3.5 GRAPES 318
9.3.6 OTHER FRUITS AND VEGETABLES 319
9.3.7 EGG YOLK 320
9.3.8 BIO-SUSPENSIONS AND YEASTS 320
9.3.9 MICROALGAE 321
9.3.10 RHIZOMES 323
9.3.11 BONES 323
9.3.12 EGGSHELL 324
9.3.13 LEAVES 324
9.3.14 HERBS 324
9.3.15 GINSENG 325
9.3.16 PEELS 325
9.3.17 MUSHROOMS 325
9.3.18 JUICES AND JUICE-BASED BEVERAGES 326
9.4 CONCLUSIONS 327
ACKNOWLEDGMENTS 327
REFERENCES 327
XII
| CONTENTS
10 GREEN EXTRACTION OF ARTEMISININ FROM
ARTEMISIA ANNUA
L
333
ALEXEI A. LAPKIN
10.1 INTRODUCTION 333
10.2 EXTRACTION TECHNOLOGIES FOR ISOLATION OF ARTEMISININ FROM A.
ANNUA 333
10.2.1 INDUSTRIAL EXTRACTION PROCESSES 336
10.2.2 CLEANER AND INTENSIFIED PROCESSES FOR EXTRACTION OF ARTEMISININ
339
10.2.2.1 INNOVATIVE PROCESS CONDITIONS FOR EXTRACTION 339
10.2.2.2 ALTERNATIVE SOLVENTS FOR EXTRACTION OF ARTEMISININ 340
10.3 INNOVATION IN ARTEMISININ PURIFICATION 346
10.3.1 HYBRID ADSORPTION-CRYSTALLIZATION SEPARATION 346
10.3.2 COLUMN AND HPLC CHROMATOGRAPHY 347
10.3.3 COUNTERCURRENT CHROMATOGRAPHY 348
10.4 ANALYSIS OF ARTEMISININ AND CO-METABOLITES 348
10.5 CONCLUSIONS AND OUTLOOK 350
REFERENCES 351
INDEX 357 |
| any_adam_object | 1 |
| author2 | Chemat, Farid 1968- |
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| format | Book |
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| genre | (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV042471163 |
| illustrated | Illustrated |
| indexdate | 2024-09-10T01:40:13Z |
| institution | BVB |
| isbn | 3527336532 9783527336531 9783527676828 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027906327 |
| oclc_num | 890019943 |
| open_access_boolean | |
| owner | DE-29T DE-11 DE-703 DE-1028 DE-19 DE-BY-UBM DE-83 DE-91S DE-BY-TUM |
| owner_facet | DE-29T DE-11 DE-703 DE-1028 DE-19 DE-BY-UBM DE-83 DE-91S DE-BY-TUM |
| physical | XVIII, 363 S. Ill., graph. Darst. 244 mm x 170 mm |
| publishDate | 2015 |
| publishDateSearch | 2015 |
| publishDateSort | 2015 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Green extraction of natural products theory and practice ed. by Farid Chemat ... Weinheim Wiley-VCH [2015] XVIII, 363 S. Ill., graph. Darst. 244 mm x 170 mm txt rdacontent n rdamedia nc rdacarrier Grüne Chemie (DE-588)7563215-9 gnd rswk-swf Umweltverträgliches Produkt (DE-588)4061629-0 gnd rswk-swf Naturstoff (DE-588)4041418-8 gnd rswk-swf Lösungsmittel (DE-588)4036160-3 gnd rswk-swf Extraktion (DE-588)4016062-2 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Naturstoff (DE-588)4041418-8 s Extraktion (DE-588)4016062-2 s Lösungsmittel (DE-588)4036160-3 s Umweltverträgliches Produkt (DE-588)4061629-0 s Grüne Chemie (DE-588)7563215-9 s DE-604 Chemat, Farid 1968- (DE-588)1066582866 edt Erscheint auch als Online-Ausgabe, EPUB 978-3-527-67681-1 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-67680-4 Erscheint auch als Online-Ausgabe, PDF 978-3-527-67679-8 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=4761965&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027906327&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Green extraction of natural products theory and practice Grüne Chemie (DE-588)7563215-9 gnd Umweltverträgliches Produkt (DE-588)4061629-0 gnd Naturstoff (DE-588)4041418-8 gnd Lösungsmittel (DE-588)4036160-3 gnd Extraktion (DE-588)4016062-2 gnd |
| subject_GND | (DE-588)7563215-9 (DE-588)4061629-0 (DE-588)4041418-8 (DE-588)4036160-3 (DE-588)4016062-2 (DE-588)4143413-4 |
| title | Green extraction of natural products theory and practice |
| title_auth | Green extraction of natural products theory and practice |
| title_exact_search | Green extraction of natural products theory and practice |
| title_full | Green extraction of natural products theory and practice ed. by Farid Chemat ... |
| title_fullStr | Green extraction of natural products theory and practice ed. by Farid Chemat ... |
| title_full_unstemmed | Green extraction of natural products theory and practice ed. by Farid Chemat ... |
| title_short | Green extraction of natural products |
| title_sort | green extraction of natural products theory and practice |
| title_sub | theory and practice |
| topic | Grüne Chemie (DE-588)7563215-9 gnd Umweltverträgliches Produkt (DE-588)4061629-0 gnd Naturstoff (DE-588)4041418-8 gnd Lösungsmittel (DE-588)4036160-3 gnd Extraktion (DE-588)4016062-2 gnd |
| topic_facet | Grüne Chemie Umweltverträgliches Produkt Naturstoff Lösungsmittel Extraktion Aufsatzsammlung |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=4761965&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027906327&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT chematfarid greenextractionofnaturalproductstheoryandpractice |