Optical Activity and Chiral Discrimination: Proceedings of the NATO Advanced Study Institute held at the University of Sussex, Falmer, England, September 10–22, 1978
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Dordrecht
Springer Netherlands
1979
|
| Schriftenreihe: | NATO Advanced Study Institutes Series, Series C — Mathematical and Physical Sciences
48 |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Beschreibung: | For Louis Pasteur, the two distinctive properties of dissymmetric systems, optical activity and chiral discrimination, provided prime evidence for a Divine origin to the universe. Handedness appeared to be built into the macrocosm of the galaxies, each with a non-superposable mirror image by virtue of its rotation, as well as the microcosm of each molecule of most natural products. The best that the chemist in the laboratory could accomplish appeared to be the synthesis of the detordu internally-compensated meso-form and, as Pasteur ultimately came to admit, the externally-compensated racemic form. In the latter case the chemist generated not merely one but two chiral structures, although parity, and secondary symmetry generally, seemed to be conserved in the enantiomer antipode pair. The cosmic element in the Pasteur tradition received an augmentation in secular form from demonstrations of the non conservation of parity in the weak interactions, and from the discovery of net circularity in the extra-terrestrial photons, such as those from the less-distant planets, particularly the photons from the Jupiter red-spot. The development of the photoacoustic circular analysers a decade ago was received in fact with as much enthusiasm by the astronomers as by the chemists. It would be just to add, however, that the majority of these circular analysers are now to be found, not in the observatories, but in the physical and chemistry laboratories devoted to the molecular aspects of the Pasteur tradition |
| Beschreibung: | 1 Online-Ressource (XI, 372 p) |
| ISBN: | 9789401576444 9789048183555 |
| ISSN: | 1389-2185 |
| DOI: | 10.1007/978-94-015-7644-4 |
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Datensatz im Suchindex
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| any_adam_object | |
| author | Mason, Stephen F. |
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| author_sort | Mason, Stephen F. |
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| building | Verbundindex |
| bvnumber | BV042416141 |
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| dewey-ones | 540 - Chemistry and allied sciences |
| dewey-raw | 540 |
| dewey-search | 540 |
| dewey-sort | 3540 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| doi_str_mv | 10.1007/978-94-015-7644-4 |
| format | Electronic eBook |
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| isbn | 9789401576444 9789048183555 |
| issn | 1389-2185 |
| language | English |
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| spelling | Mason, Stephen F. Verfasser aut Optical Activity and Chiral Discrimination Proceedings of the NATO Advanced Study Institute held at the University of Sussex, Falmer, England, September 10–22, 1978 edited by Stephen F. Mason Proceedings of the NATO Advanced Study Institute, Falmer, England, September 10-22, 1978 Dordrecht Springer Netherlands 1979 1 Online-Ressource (XI, 372 p) txt rdacontent c rdamedia cr rdacarrier NATO Advanced Study Institutes Series, Series C — Mathematical and Physical Sciences 48 1389-2185 For Louis Pasteur, the two distinctive properties of dissymmetric systems, optical activity and chiral discrimination, provided prime evidence for a Divine origin to the universe. Handedness appeared to be built into the macrocosm of the galaxies, each with a non-superposable mirror image by virtue of its rotation, as well as the microcosm of each molecule of most natural products. The best that the chemist in the laboratory could accomplish appeared to be the synthesis of the detordu internally-compensated meso-form and, as Pasteur ultimately came to admit, the externally-compensated racemic form. In the latter case the chemist generated not merely one but two chiral structures, although parity, and secondary symmetry generally, seemed to be conserved in the enantiomer antipode pair. The cosmic element in the Pasteur tradition received an augmentation in secular form from demonstrations of the non conservation of parity in the weak interactions, and from the discovery of net circularity in the extra-terrestrial photons, such as those from the less-distant planets, particularly the photons from the Jupiter red-spot. The development of the photoacoustic circular analysers a decade ago was received in fact with as much enthusiasm by the astronomers as by the chemists. It would be just to add, however, that the majority of these circular analysers are now to be found, not in the observatories, but in the physical and chemistry laboratories devoted to the molecular aspects of the Pasteur tradition Chemistry Chemistry/Food Science, general Chemie Chiralität Chemie (DE-588)4147732-7 gnd rswk-swf Rotationsdispersion (DE-588)4178488-1 gnd rswk-swf Zirkulardichroismus (DE-588)4010215-4 gnd rswk-swf 1\p (DE-588)1071861417 Konferenzschrift gnd-content Zirkulardichroismus (DE-588)4010215-4 s 2\p DE-604 Chiralität Chemie (DE-588)4147732-7 s 3\p DE-604 Rotationsdispersion (DE-588)4178488-1 s 4\p DE-604 https://doi.org/10.1007/978-94-015-7644-4 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 4\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Mason, Stephen F. Optical Activity and Chiral Discrimination Proceedings of the NATO Advanced Study Institute held at the University of Sussex, Falmer, England, September 10–22, 1978 Chemistry Chemistry/Food Science, general Chemie Chiralität Chemie (DE-588)4147732-7 gnd Rotationsdispersion (DE-588)4178488-1 gnd Zirkulardichroismus (DE-588)4010215-4 gnd |
| subject_GND | (DE-588)4147732-7 (DE-588)4178488-1 (DE-588)4010215-4 (DE-588)1071861417 |
| title | Optical Activity and Chiral Discrimination Proceedings of the NATO Advanced Study Institute held at the University of Sussex, Falmer, England, September 10–22, 1978 |
| title_alt | Proceedings of the NATO Advanced Study Institute, Falmer, England, September 10-22, 1978 |
| title_auth | Optical Activity and Chiral Discrimination Proceedings of the NATO Advanced Study Institute held at the University of Sussex, Falmer, England, September 10–22, 1978 |
| title_exact_search | Optical Activity and Chiral Discrimination Proceedings of the NATO Advanced Study Institute held at the University of Sussex, Falmer, England, September 10–22, 1978 |
| title_full | Optical Activity and Chiral Discrimination Proceedings of the NATO Advanced Study Institute held at the University of Sussex, Falmer, England, September 10–22, 1978 edited by Stephen F. Mason |
| title_fullStr | Optical Activity and Chiral Discrimination Proceedings of the NATO Advanced Study Institute held at the University of Sussex, Falmer, England, September 10–22, 1978 edited by Stephen F. Mason |
| title_full_unstemmed | Optical Activity and Chiral Discrimination Proceedings of the NATO Advanced Study Institute held at the University of Sussex, Falmer, England, September 10–22, 1978 edited by Stephen F. Mason |
| title_short | Optical Activity and Chiral Discrimination |
| title_sort | optical activity and chiral discrimination proceedings of the nato advanced study institute held at the university of sussex falmer england september 10 22 1978 |
| title_sub | Proceedings of the NATO Advanced Study Institute held at the University of Sussex, Falmer, England, September 10–22, 1978 |
| topic | Chemistry Chemistry/Food Science, general Chemie Chiralität Chemie (DE-588)4147732-7 gnd Rotationsdispersion (DE-588)4178488-1 gnd Zirkulardichroismus (DE-588)4010215-4 gnd |
| topic_facet | Chemistry Chemistry/Food Science, general Chemie Chiralität Chemie Rotationsdispersion Zirkulardichroismus Konferenzschrift |
| url | https://doi.org/10.1007/978-94-015-7644-4 |
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