Current Challenges on Large Supramolecular Assemblies:
Gespeichert in:
1. Verfasser: | |
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Format: | Elektronisch E-Book |
Sprache: | English |
Veröffentlicht: |
Dordrecht
Springer Netherlands
1999
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Schriftenreihe: | NATO Science Series, Series C: Mathematical and Physical Sciences
519 |
Schlagworte: | |
Online-Zugang: | Volltext |
Beschreibung: | The objectives of the ARW were: - identifying areas and highlighting approaches by which large Supramolecular (SM) Assemblies can be synthesised - reviewing and combining methods to characterise and analyse such assemblies. The first part of the ARW is devoted to reviewing synthetic achievements in recent years for several families of SM compounds, and to bringing out principles for crystal structure design, including novel quantum mechanical methods. Synthesis pertains both to the chemical synthesis of components for SM assembly, and to the subsequent assembly process based on complementarity and non-covalent interactions. The elaboration of multiple recognition "algorithms" concurrently employed (for instance, 1t-1t and hydrogen bonds) has recently reached a high degree of sophistication in the sequence: Molecules -7 Supermolecule -7 SM array -7 Crystal or Conglomerate Novel Large Assemblies comprise synthetic entities with molecular weight as high as 15000, and hybrid SM assemblies between synthetic molecules and DNA. Further developments are foreseen at a higher level of organisation, such as between supermolecules or with electromagnetic fields in photochemical processes. Creation of 2D Assemblies is now a powerful tool for creation and study of SM interactions. Moreover, much is to be learned in going from 2D to 3D assemblies in crystal growth and other forms of organisation such as micelles or liquid crystals. On the other hand, crystal engineering based on Molecular Recognition in the Crystal State leads to novel 2D assemblies occurring within predesigned crystal structures (hydrophobic organic clays or nanoporous networks) |
Beschreibung: | 1 Online-Ressource (XIV, 424 p) |
ISBN: | 9789401152846 9789401062244 |
ISSN: | 1389-2185 |
DOI: | 10.1007/978-94-011-5284-6 |
Internformat
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spelling | Tsoucaris, George Verfasser aut Current Challenges on Large Supramolecular Assemblies edited by George Tsoucaris Proceedings of the NATO Advanced Research Workshop, Athens, Greece, 31 October-5 November 1997 Dordrecht Springer Netherlands 1999 1 Online-Ressource (XIV, 424 p) txt rdacontent c rdamedia cr rdacarrier NATO Science Series, Series C: Mathematical and Physical Sciences 519 1389-2185 The objectives of the ARW were: - identifying areas and highlighting approaches by which large Supramolecular (SM) Assemblies can be synthesised - reviewing and combining methods to characterise and analyse such assemblies. The first part of the ARW is devoted to reviewing synthetic achievements in recent years for several families of SM compounds, and to bringing out principles for crystal structure design, including novel quantum mechanical methods. Synthesis pertains both to the chemical synthesis of components for SM assembly, and to the subsequent assembly process based on complementarity and non-covalent interactions. The elaboration of multiple recognition "algorithms" concurrently employed (for instance, 1t-1t and hydrogen bonds) has recently reached a high degree of sophistication in the sequence: Molecules -7 Supermolecule -7 SM array -7 Crystal or Conglomerate Novel Large Assemblies comprise synthetic entities with molecular weight as high as 15000, and hybrid SM assemblies between synthetic molecules and DNA. Further developments are foreseen at a higher level of organisation, such as between supermolecules or with electromagnetic fields in photochemical processes. Creation of 2D Assemblies is now a powerful tool for creation and study of SM interactions. Moreover, much is to be learned in going from 2D to 3D assemblies in crystal growth and other forms of organisation such as micelles or liquid crystals. On the other hand, crystal engineering based on Molecular Recognition in the Crystal State leads to novel 2D assemblies occurring within predesigned crystal structures (hydrophobic organic clays or nanoporous networks) Chemistry Chemistry, Organic Chemistry, Physical organic Crystallography Physical Chemistry Organic Chemistry Chemie Supramolekulare Chemie (DE-588)4306141-2 gnd rswk-swf 1\p (DE-588)1071861417 Konferenzschrift gnd-content 2\p (DE-588)1071861417 Konferenzschrift 1997 Athen gnd-content Supramolekulare Chemie (DE-588)4306141-2 s 3\p DE-604 https://doi.org/10.1007/978-94-011-5284-6 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
spellingShingle | Tsoucaris, George Current Challenges on Large Supramolecular Assemblies Chemistry Chemistry, Organic Chemistry, Physical organic Crystallography Physical Chemistry Organic Chemistry Chemie Supramolekulare Chemie (DE-588)4306141-2 gnd |
subject_GND | (DE-588)4306141-2 (DE-588)1071861417 |
title | Current Challenges on Large Supramolecular Assemblies |
title_alt | Proceedings of the NATO Advanced Research Workshop, Athens, Greece, 31 October-5 November 1997 |
title_auth | Current Challenges on Large Supramolecular Assemblies |
title_exact_search | Current Challenges on Large Supramolecular Assemblies |
title_full | Current Challenges on Large Supramolecular Assemblies edited by George Tsoucaris |
title_fullStr | Current Challenges on Large Supramolecular Assemblies edited by George Tsoucaris |
title_full_unstemmed | Current Challenges on Large Supramolecular Assemblies edited by George Tsoucaris |
title_short | Current Challenges on Large Supramolecular Assemblies |
title_sort | current challenges on large supramolecular assemblies |
topic | Chemistry Chemistry, Organic Chemistry, Physical organic Crystallography Physical Chemistry Organic Chemistry Chemie Supramolekulare Chemie (DE-588)4306141-2 gnd |
topic_facet | Chemistry Chemistry, Organic Chemistry, Physical organic Crystallography Physical Chemistry Organic Chemistry Chemie Supramolekulare Chemie Konferenzschrift Konferenzschrift 1997 Athen |
url | https://doi.org/10.1007/978-94-011-5284-6 |
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