Physics and Chemistry of Electrons and Ions in Condensed Matter:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Dordrecht
Springer Netherlands
1984
|
| Schriftenreihe: | NATO ASI Series, Series C: Mathematical and Physical Sciences
130 |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Beschreibung: | xvii PART I PROPERTIES OF CRYSTALLINE MATERIALS The Effective U in Oxides and in Sulfides: Conceptual Phase Diagrams and their Applications . . . . . . . . . . . . . . . ; . . . . . . . •. . . . . . . . 1 John B. Goodenough 1. Definitions 1 2. Interatomic interactions 23 References 44 Electron Correlations in Elementary Structures. The Case of Weak Correlations: Metallic and Covalent Bondings . . . . . . . . . . . . . . . . . 45 J. Friedel Introduct i on 45 1. The H2 molecule 46 2. Other elementary diatomic molecules 52 3. Metallic aggregates 53 4. Macroscopic phases of transition metals 57 5. Aggregates and solids of tetravalent (sp) elements 64 6. Aggregates of covalent dimers 67 7. Weak distortions of metallic closepacked or covalent structures 69 Appendixes 74 References 82 Statistical Thermodynamics of Mixed Valence at Low Temperatures . •. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . •. . . . . . . . . . . . 85 Dieter Wohlleben 1. Introduction 85 2. The free enthalpy without mixing 86 3. The valence fluctuation temperature 89 4. 'The free enthalpy with interconfigurational mlxlng 90 5. Equation of state for the valence fluctuation ~~n~e ~ 6. The conduction electron density of states near T=O 98 7. Application to Ce metal 101 8. Acknowledgements 104 References 104 Mixed Valency in Inorganic Chemistry •. . . •. . . . ~ . . . •. . •. . . . . . . . 109 P. Day CONTENTS vi Important Discussion of Part I Intermedi ate Val ency (IV) Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . 111 N. F. Mott Thermal Expansion and Specific Heat of Mixed Valence Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 R. Pott 1. Introduction 117 2. Experiments and experimental results 117 3. Discussion 120 4. Acknowledgements 122 5 |
| Beschreibung: | 1 Online-Ressource (XVIII, 732 p) |
| ISBN: | 9789400964402 9789400964426 |
| ISSN: | 1389-2185 |
| DOI: | 10.1007/978-94-009-6440-2 |
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Datensatz im Suchindex
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| dewey-raw | 541 |
| dewey-search | 541 |
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| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| doi_str_mv | 10.1007/978-94-009-6440-2 |
| format | Electronic eBook |
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| record_format | marc |
| series2 | NATO ASI Series, Series C: Mathematical and Physical Sciences |
| spelling | Acrivos, J. V. Verfasser aut Physics and Chemistry of Electrons and Ions in Condensed Matter edited by J. V. Acrivos, N. F. Mott, A. D. Yoffe Proceedings of the NATO Advanced Study Institute, Cambridge, U.K., September 6-17, 1983 Dordrecht Springer Netherlands 1984 1 Online-Ressource (XVIII, 732 p) txt rdacontent c rdamedia cr rdacarrier NATO ASI Series, Series C: Mathematical and Physical Sciences 130 1389-2185 xvii PART I PROPERTIES OF CRYSTALLINE MATERIALS The Effective U in Oxides and in Sulfides: Conceptual Phase Diagrams and their Applications . . . . . . . . . . . . . . . ; . . . . . . . •. . . . . . . . 1 John B. Goodenough 1. Definitions 1 2. Interatomic interactions 23 References 44 Electron Correlations in Elementary Structures. The Case of Weak Correlations: Metallic and Covalent Bondings . . . . . . . . . . . . . . . . . 45 J. Friedel Introduct i on 45 1. The H2 molecule 46 2. Other elementary diatomic molecules 52 3. Metallic aggregates 53 4. Macroscopic phases of transition metals 57 5. Aggregates and solids of tetravalent (sp) elements 64 6. Aggregates of covalent dimers 67 7. Weak distortions of metallic closepacked or covalent structures 69 Appendixes 74 References 82 Statistical Thermodynamics of Mixed Valence at Low Temperatures . •. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . •. . . . . . . . . . . . 85 Dieter Wohlleben 1. Introduction 85 2. The free enthalpy without mixing 86 3. The valence fluctuation temperature 89 4. 'The free enthalpy with interconfigurational mlxlng 90 5. Equation of state for the valence fluctuation ~~n~e ~ 6. The conduction electron density of states near T=O 98 7. Application to Ce metal 101 8. Acknowledgements 104 References 104 Mixed Valency in Inorganic Chemistry •. . . •. . . . ~ . . . •. . •. . . . . . . . 109 P. Day CONTENTS vi Important Discussion of Part I Intermedi ate Val ency (IV) Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . 111 N. F. Mott Thermal Expansion and Specific Heat of Mixed Valence Compounds . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117 R. Pott 1. Introduction 117 2. Experiments and experimental results 117 3. Discussion 120 4. Acknowledgements 122 5 Chemistry Chemistry, Physical organic Physical Chemistry Chemie Festkörperchemie (DE-588)4129288-1 gnd rswk-swf Ion (DE-588)4027597-8 gnd rswk-swf Kondensierte Materie (DE-588)4132810-3 gnd rswk-swf Festkörperphysik (DE-588)4016921-2 gnd rswk-swf Elektron (DE-588)4125978-6 gnd rswk-swf 1\p (DE-588)1071861417 Konferenzschrift 1983 Cambridge gnd-content Kondensierte Materie (DE-588)4132810-3 s Ion (DE-588)4027597-8 s 2\p DE-604 Elektron (DE-588)4125978-6 s 3\p DE-604 Festkörperphysik (DE-588)4016921-2 s 4\p DE-604 Festkörperchemie (DE-588)4129288-1 s 5\p DE-604 Mott, N. F. Sonstige oth Yoffe, A. D. Sonstige oth https://doi.org/10.1007/978-94-009-6440-2 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 4\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 5\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Acrivos, J. V. Physics and Chemistry of Electrons and Ions in Condensed Matter Chemistry Chemistry, Physical organic Physical Chemistry Chemie Festkörperchemie (DE-588)4129288-1 gnd Ion (DE-588)4027597-8 gnd Kondensierte Materie (DE-588)4132810-3 gnd Festkörperphysik (DE-588)4016921-2 gnd Elektron (DE-588)4125978-6 gnd |
| subject_GND | (DE-588)4129288-1 (DE-588)4027597-8 (DE-588)4132810-3 (DE-588)4016921-2 (DE-588)4125978-6 (DE-588)1071861417 |
| title | Physics and Chemistry of Electrons and Ions in Condensed Matter |
| title_alt | Proceedings of the NATO Advanced Study Institute, Cambridge, U.K., September 6-17, 1983 |
| title_auth | Physics and Chemistry of Electrons and Ions in Condensed Matter |
| title_exact_search | Physics and Chemistry of Electrons and Ions in Condensed Matter |
| title_full | Physics and Chemistry of Electrons and Ions in Condensed Matter edited by J. V. Acrivos, N. F. Mott, A. D. Yoffe |
| title_fullStr | Physics and Chemistry of Electrons and Ions in Condensed Matter edited by J. V. Acrivos, N. F. Mott, A. D. Yoffe |
| title_full_unstemmed | Physics and Chemistry of Electrons and Ions in Condensed Matter edited by J. V. Acrivos, N. F. Mott, A. D. Yoffe |
| title_short | Physics and Chemistry of Electrons and Ions in Condensed Matter |
| title_sort | physics and chemistry of electrons and ions in condensed matter |
| topic | Chemistry Chemistry, Physical organic Physical Chemistry Chemie Festkörperchemie (DE-588)4129288-1 gnd Ion (DE-588)4027597-8 gnd Kondensierte Materie (DE-588)4132810-3 gnd Festkörperphysik (DE-588)4016921-2 gnd Elektron (DE-588)4125978-6 gnd |
| topic_facet | Chemistry Chemistry, Physical organic Physical Chemistry Chemie Festkörperchemie Ion Kondensierte Materie Festkörperphysik Elektron Konferenzschrift 1983 Cambridge |
| url | https://doi.org/10.1007/978-94-009-6440-2 |
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