Substituent Effects in Radical Chemistry:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Dordrecht
Springer Netherlands
1986
|
| Schriftenreihe: | NATO ASI Series, Mathematical and Physical Sciences
189 |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Beschreibung: | Respectably old radical chemistry which plays a rna jor role in life-processes, both desired (breathing, ... ) and non-desired (in flammatory diseases, ageing, ... ) has been gaining new youth in the past decade. Modern spectroscopy and other physical methods, recent advances in computational methods as well as impressive and mechanistically well-understood syntheses have led to a number of spectacular deve lopments in the field of radical chemistry. The impact of these achi evements will reach far beyond the field of organic chemistry, for example into biology and medicine. New facts and concepts in this rapidly expanding field deserved discussion among a number of leading experts present at the Workshop both for the information and constructive criticism. This happened during a particular brainstorming session and some of the impressions and reflections exchanged are recorded in the Epilogue. Indeed the topic chosen seems to be quintessential for the whole radical chemistry understanding and exploiting (single and multiple) substituent effects on radicals. We had the honour to organise this Workshop because some years ago, in collaboration with L. Stella, we became involved in radical stabi lising effects when both a donor and an acceptor (captor) groups are present on a C-radical. This leads to an enhanced stabilisation which we called the captodative effect and we have endeavoured the first extensi ve investigation of this effect on carbon centered radicals |
| Beschreibung: | 1 Online-Ressource (XIV, 482 p) |
| ISBN: | 9789400947580 9789401086141 |
| ISSN: | 1389-2185 |
| DOI: | 10.1007/978-94-009-4758-0 |
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| 500 | |a Respectably old radical chemistry which plays a rna jor role in life-processes, both desired (breathing, ... ) and non-desired (in flammatory diseases, ageing, ... ) has been gaining new youth in the past decade. Modern spectroscopy and other physical methods, recent advances in computational methods as well as impressive and mechanistically well-understood syntheses have led to a number of spectacular deve lopments in the field of radical chemistry. The impact of these achi evements will reach far beyond the field of organic chemistry, for example into biology and medicine. New facts and concepts in this rapidly expanding field deserved discussion among a number of leading experts present at the Workshop both for the information and constructive criticism. This happened during a particular brainstorming session and some of the impressions and reflections exchanged are recorded in the Epilogue. Indeed the topic chosen seems to be quintessential for the whole radical chemistry understanding and exploiting (single and multiple) substituent effects on radicals. We had the honour to organise this Workshop because some years ago, in collaboration with L. Stella, we became involved in radical stabi lising effects when both a donor and an acceptor (captor) groups are present on a C-radical. This leads to an enhanced stabilisation which we called the captodative effect and we have endeavoured the first extensi ve investigation of this effect on carbon centered radicals | ||
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Datensatz im Suchindex
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| dewey-full | 547 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547 |
| dewey-search | 547 |
| dewey-sort | 3547 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| doi_str_mv | 10.1007/978-94-009-4758-0 |
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| spelling | Viehe, Heinz G. Verfasser aut Substituent Effects in Radical Chemistry edited by Heinz G. Viehe, Zdenek Janousek, Robert Merényi Proceedings of the NATO Advanced Research Workshop, Louvain-la-Neuve, Belgium, January 20-24, 1986 Dordrecht Springer Netherlands 1986 1 Online-Ressource (XIV, 482 p) txt rdacontent c rdamedia cr rdacarrier NATO ASI Series, Mathematical and Physical Sciences 189 1389-2185 Respectably old radical chemistry which plays a rna jor role in life-processes, both desired (breathing, ... ) and non-desired (in flammatory diseases, ageing, ... ) has been gaining new youth in the past decade. Modern spectroscopy and other physical methods, recent advances in computational methods as well as impressive and mechanistically well-understood syntheses have led to a number of spectacular deve lopments in the field of radical chemistry. The impact of these achi evements will reach far beyond the field of organic chemistry, for example into biology and medicine. New facts and concepts in this rapidly expanding field deserved discussion among a number of leading experts present at the Workshop both for the information and constructive criticism. This happened during a particular brainstorming session and some of the impressions and reflections exchanged are recorded in the Epilogue. Indeed the topic chosen seems to be quintessential for the whole radical chemistry understanding and exploiting (single and multiple) substituent effects on radicals. We had the honour to organise this Workshop because some years ago, in collaboration with L. Stella, we became involved in radical stabi lising effects when both a donor and an acceptor (captor) groups are present on a C-radical. This leads to an enhanced stabilisation which we called the captodative effect and we have endeavoured the first extensi ve investigation of this effect on carbon centered radicals Chemistry Chemistry, Organic Organic Chemistry Chemie Radikal Chemie (DE-588)4076475-8 gnd rswk-swf Substituenteneffekt (DE-588)4183924-9 gnd rswk-swf 1\p (DE-588)1071861417 Konferenzschrift 1986 Louvain-la-Neuve gnd-content Radikal Chemie (DE-588)4076475-8 s Substituenteneffekt (DE-588)4183924-9 s 2\p DE-604 Janousek, Zdenek Sonstige oth Merényi, Robert Sonstige oth https://doi.org/10.1007/978-94-009-4758-0 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Viehe, Heinz G. Substituent Effects in Radical Chemistry Chemistry Chemistry, Organic Organic Chemistry Chemie Radikal Chemie (DE-588)4076475-8 gnd Substituenteneffekt (DE-588)4183924-9 gnd |
| subject_GND | (DE-588)4076475-8 (DE-588)4183924-9 (DE-588)1071861417 |
| title | Substituent Effects in Radical Chemistry |
| title_alt | Proceedings of the NATO Advanced Research Workshop, Louvain-la-Neuve, Belgium, January 20-24, 1986 |
| title_auth | Substituent Effects in Radical Chemistry |
| title_exact_search | Substituent Effects in Radical Chemistry |
| title_full | Substituent Effects in Radical Chemistry edited by Heinz G. Viehe, Zdenek Janousek, Robert Merényi |
| title_fullStr | Substituent Effects in Radical Chemistry edited by Heinz G. Viehe, Zdenek Janousek, Robert Merényi |
| title_full_unstemmed | Substituent Effects in Radical Chemistry edited by Heinz G. Viehe, Zdenek Janousek, Robert Merényi |
| title_short | Substituent Effects in Radical Chemistry |
| title_sort | substituent effects in radical chemistry |
| topic | Chemistry Chemistry, Organic Organic Chemistry Chemie Radikal Chemie (DE-588)4076475-8 gnd Substituenteneffekt (DE-588)4183924-9 gnd |
| topic_facet | Chemistry Chemistry, Organic Organic Chemistry Chemie Radikal Chemie Substituenteneffekt Konferenzschrift 1986 Louvain-la-Neuve |
| url | https://doi.org/10.1007/978-94-009-4758-0 |
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