Reactive and Flexible Molecules in Liquids:
Gespeichert in:
1. Verfasser: | |
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Format: | Elektronisch E-Book |
Sprache: | English |
Veröffentlicht: |
Dordrecht
Springer Netherlands
1989
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Schriftenreihe: | NATO ASI Series, Series C: Mathematical and Physical Sciences
291 |
Schlagworte: | |
Online-Zugang: | Volltext |
Beschreibung: | The observable phenomena in liquids ",hich distinguishes this state of matter from other types of condensed matter can be mainly assigned to a) the configurational disorder and b) the random motion of molecules. Both, the static and the dynamic aspect of randomness are typical for the liquid state and serve as a useful guideline in the attempts to theoretically understand this state. These two basic features, however, introduce in liquid state theory a number of apparently unsurmountable technical and conceptual problems so that progress in the last decades has only been made by small steps. In order not to complicate the situation even more, the tacit assumption was made that we could neglect internal motions of the molecules and that the molecular interactions which had to be taken into account are as simple as possible. We thus became accustomed to visualize molecules in the liquid as a dense assembly of classical rigid particles interacting with a potential which basically is represented by a Lennard-Jones type relation. In the last decade, it has become obvious that with these restrictions we dis regard many interesting effects in those liquids which are the most important ones. We thus see a serious gap developing between the refinements of liquid state theory and the exciting experiments being carried out in many laboratories |
Beschreibung: | 1 Online-Ressource (X, 460 p) |
ISBN: | 9789400910430 9789401069618 |
ISSN: | 1389-2185 |
DOI: | 10.1007/978-94-009-1043-0 |
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language | English |
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spelling | Dorfmüller, Th Verfasser aut Reactive and Flexible Molecules in Liquids edited by Th. Dorfmüller Proceedings of the NATO Advanced Study Institute, Nafplion, Greece, September 23-October 2, 1988 Dordrecht Springer Netherlands 1989 1 Online-Ressource (X, 460 p) txt rdacontent c rdamedia cr rdacarrier NATO ASI Series, Series C: Mathematical and Physical Sciences 291 1389-2185 The observable phenomena in liquids ",hich distinguishes this state of matter from other types of condensed matter can be mainly assigned to a) the configurational disorder and b) the random motion of molecules. Both, the static and the dynamic aspect of randomness are typical for the liquid state and serve as a useful guideline in the attempts to theoretically understand this state. These two basic features, however, introduce in liquid state theory a number of apparently unsurmountable technical and conceptual problems so that progress in the last decades has only been made by small steps. In order not to complicate the situation even more, the tacit assumption was made that we could neglect internal motions of the molecules and that the molecular interactions which had to be taken into account are as simple as possible. We thus became accustomed to visualize molecules in the liquid as a dense assembly of classical rigid particles interacting with a potential which basically is represented by a Lennard-Jones type relation. In the last decade, it has become obvious that with these restrictions we dis regard many interesting effects in those liquids which are the most important ones. We thus see a serious gap developing between the refinements of liquid state theory and the exciting experiments being carried out in many laboratories Chemistry Chemistry, Physical organic Physical Chemistry Chemie https://doi.org/10.1007/978-94-009-1043-0 Verlag Volltext |
spellingShingle | Dorfmüller, Th Reactive and Flexible Molecules in Liquids Chemistry Chemistry, Physical organic Physical Chemistry Chemie |
title | Reactive and Flexible Molecules in Liquids |
title_alt | Proceedings of the NATO Advanced Study Institute, Nafplion, Greece, September 23-October 2, 1988 |
title_auth | Reactive and Flexible Molecules in Liquids |
title_exact_search | Reactive and Flexible Molecules in Liquids |
title_full | Reactive and Flexible Molecules in Liquids edited by Th. Dorfmüller |
title_fullStr | Reactive and Flexible Molecules in Liquids edited by Th. Dorfmüller |
title_full_unstemmed | Reactive and Flexible Molecules in Liquids edited by Th. Dorfmüller |
title_short | Reactive and Flexible Molecules in Liquids |
title_sort | reactive and flexible molecules in liquids |
topic | Chemistry Chemistry, Physical organic Physical Chemistry Chemie |
topic_facet | Chemistry Chemistry, Physical organic Physical Chemistry Chemie |
url | https://doi.org/10.1007/978-94-009-1043-0 |
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