Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Dordrecht
Springer Netherlands
1989
|
| Schriftenreihe: | NATO ASI Series, Series C: Mathematical and Physical Sciences
257 |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Beschreibung: | When one considers the overall representation of frontier orbital filling of hexacoordinate (Oh) and tetracoordinate (Td) inorganic and organo metallic complexes, it clearly appears that out of 26 cases covering both high spin and low spin situations, 21 represent paramagnetic species (K. Purcell, J. Kotz, "Inorganic Chemistry", Saunders, 1977, p561). This would suggest that, if there is a part in chemistry to illustrate the reactivity of radical species, this part certainly is inorganic organometallic chemistry. In contrast with these expectations, and whereas the standard Organic Chemistry textbook (J. March ,"Advanced Organic Chemistry", J. Wiley, N. Y. , 1985) has a specific chapter devoted to free radical reactivity, neither the inorganic standard (FA Cotton, G. Wilkinson, "Advanced Inorganic Chemistry", Wiley, 1988), nor the Organometallic one (J. P. Collman, L. S. Hegedus, J. R. Norton, R. G. Finke, "Principles and Applications of Organotransition Metal Chemistry", University Science Books Mill Valley C. A. , 1987) possess such a specific chapter. The balance is partly restored because the two last cited books have a more comprehensive treatment of electron transfer phenomena. These comparisons show unambiguously that the importance of paramagnetic species in chemical reactivity still lacks a consistent treatment transcending the artificial barriers between branches of Chemistry. This book, which brings together experimental facts and concepts originating from organometallic and organic reactivities, is a step in the direction of bridging this gap. The unifying thread which connects the 35 chapters throughout this book is Activation/Selectivity and Catalysis by means of radical chemistry |
| Beschreibung: | 1 Online-Ressource (596p) |
| ISBN: | 9789400908772 9789401068826 |
| ISSN: | 1389-2185 |
| DOI: | 10.1007/978-94-009-0877-2 |
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| discipline | Chemie / Pharmazie Physik |
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| format | Electronic eBook |
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| spelling | Chanon, Michel 1940- Verfasser (DE-588)172018366 aut Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis edited by Michel Chanon, Michel Julliard, Jean Claude Poite Proceedings of the NATO Advanced Research Workshop, St. Maximin, France, October 4-9, 1987 Dordrecht Springer Netherlands 1989 1 Online-Ressource (596p) txt rdacontent c rdamedia cr rdacarrier NATO ASI Series, Series C: Mathematical and Physical Sciences 257 1389-2185 When one considers the overall representation of frontier orbital filling of hexacoordinate (Oh) and tetracoordinate (Td) inorganic and organo metallic complexes, it clearly appears that out of 26 cases covering both high spin and low spin situations, 21 represent paramagnetic species (K. Purcell, J. Kotz, "Inorganic Chemistry", Saunders, 1977, p561). This would suggest that, if there is a part in chemistry to illustrate the reactivity of radical species, this part certainly is inorganic organometallic chemistry. In contrast with these expectations, and whereas the standard Organic Chemistry textbook (J. March ,"Advanced Organic Chemistry", J. Wiley, N. Y. , 1985) has a specific chapter devoted to free radical reactivity, neither the inorganic standard (FA Cotton, G. Wilkinson, "Advanced Inorganic Chemistry", Wiley, 1988), nor the Organometallic one (J. P. Collman, L. S. Hegedus, J. R. Norton, R. G. Finke, "Principles and Applications of Organotransition Metal Chemistry", University Science Books Mill Valley C. A. , 1987) possess such a specific chapter. The balance is partly restored because the two last cited books have a more comprehensive treatment of electron transfer phenomena. These comparisons show unambiguously that the importance of paramagnetic species in chemical reactivity still lacks a consistent treatment transcending the artificial barriers between branches of Chemistry. This book, which brings together experimental facts and concepts originating from organometallic and organic reactivities, is a step in the direction of bridging this gap. The unifying thread which connects the 35 chapters throughout this book is Activation/Selectivity and Catalysis by means of radical chemistry Chemistry Chemistry, Organic Organic Chemistry Chemie Paramagnetismus (DE-588)4173291-1 gnd rswk-swf Metallorganische Verbindungen (DE-588)4038906-6 gnd rswk-swf Katalyse (DE-588)4029921-1 gnd rswk-swf 1\p (DE-588)1071861417 Konferenzschrift gnd-content 2\p (DE-588)1071861417 Konferenzschrift 1987 Saint-Maximin-la-Sainte-Baume gnd-content 3\p (DE-588)1071861417 Konferenzschrift 1987 Sainte-Maxime gnd-content Metallorganische Verbindungen (DE-588)4038906-6 s Katalyse (DE-588)4029921-1 s 4\p DE-604 Paramagnetismus (DE-588)4173291-1 s 5\p DE-604 Julliard, Michel Sonstige oth Poite, Jean Claude Sonstige oth https://doi.org/10.1007/978-94-009-0877-2 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 4\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 5\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Chanon, Michel 1940- Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis Chemistry Chemistry, Organic Organic Chemistry Chemie Paramagnetismus (DE-588)4173291-1 gnd Metallorganische Verbindungen (DE-588)4038906-6 gnd Katalyse (DE-588)4029921-1 gnd |
| subject_GND | (DE-588)4173291-1 (DE-588)4038906-6 (DE-588)4029921-1 (DE-588)1071861417 |
| title | Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis |
| title_alt | Proceedings of the NATO Advanced Research Workshop, St. Maximin, France, October 4-9, 1987 |
| title_auth | Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis |
| title_exact_search | Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis |
| title_full | Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis edited by Michel Chanon, Michel Julliard, Jean Claude Poite |
| title_fullStr | Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis edited by Michel Chanon, Michel Julliard, Jean Claude Poite |
| title_full_unstemmed | Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis edited by Michel Chanon, Michel Julliard, Jean Claude Poite |
| title_short | Paramagnetic Organometallic Species in Activation/Selectivity, Catalysis |
| title_sort | paramagnetic organometallic species in activation selectivity catalysis |
| topic | Chemistry Chemistry, Organic Organic Chemistry Chemie Paramagnetismus (DE-588)4173291-1 gnd Metallorganische Verbindungen (DE-588)4038906-6 gnd Katalyse (DE-588)4029921-1 gnd |
| topic_facet | Chemistry Chemistry, Organic Organic Chemistry Chemie Paramagnetismus Metallorganische Verbindungen Katalyse Konferenzschrift Konferenzschrift 1987 Saint-Maximin-la-Sainte-Baume Konferenzschrift 1987 Sainte-Maxime |
| url | https://doi.org/10.1007/978-94-009-0877-2 |
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