Kinetics of Metal-Gas Interactions at Low Temperatures: Hydriding, Oxidation, Poisoning
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Berlin, Heidelberg
Springer Berlin Heidelberg
1998
|
| Schriftenreihe: | Springer Series in Surface Sciences
36 |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Beschreibung: | Kinetics of Metal-Gas Interactions at Low Temperatures is devoted to the formation of natural oxide films. These thin surface layers are produced instantaneously when oxygen or water vapor is present in the gas atmosphere. They are responsible for corrosion behavior, for wear and friction of metallic materials, and also for hydrogen embrittlement and poisoning of catalytic surface reactions. Oxidation is a hindrance in surface science and in modern thin-film manufacturing. It can be reliably avoided only with expensive ultra-high vacuum techniques. Despite the practical relevance of the topic, quantitative data are sparse and the few papers published on low-temperature oxidation provide mainly qualitative information. This monograph presents an introduction to the subject in a tutorial style. It demonstrates how complex metal-gas interactions can be analyzed by standard procedures of chemical kinetics, and simulated by reaction models. Typical features of metal-gas reactions observed at ambient and elevated temperatures are illustrated by experimental results. Possible reaction mechanisms are described both by approximations and by advanced models. Rate and time laws describe the limiting cases and the more realistic situation where, in an overall reaction, several crucial partial steps must be considered, namely, adsorption onto the surface and the diffusion of charged or uncharged defects in metallic or semiconducting surface layers |
| Beschreibung: | 1 Online-Ressource (XIII, 206p. 103 illus) |
| ISBN: | 9783642603112 9783540639756 |
| ISSN: | 0931-5195 |
| DOI: | 10.1007/978-3-642-60311-2 |
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Datensatz im Suchindex
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| any_adam_object | |
| author | Fromm, Eckehard |
| author_facet | Fromm, Eckehard |
| author_role | aut |
| author_sort | Fromm, Eckehard |
| author_variant | e f ef |
| building | Verbundindex |
| bvnumber | BV042413327 |
| classification_tum | PHY 000 |
| collection | ZDB-2-PHA ZDB-2-BAE |
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| dewey-full | 530.417 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 530 - Physics |
| dewey-raw | 530.417 |
| dewey-search | 530.417 |
| dewey-sort | 3530.417 |
| dewey-tens | 530 - Physics |
| discipline | Physik |
| doi_str_mv | 10.1007/978-3-642-60311-2 |
| format | Electronic eBook |
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| id | DE-604.BV042413327 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T01:20:52Z |
| institution | BVB |
| isbn | 9783642603112 9783540639756 |
| issn | 0931-5195 |
| language | English |
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| physical | 1 Online-Ressource (XIII, 206p. 103 illus) |
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| publisher | Springer Berlin Heidelberg |
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| series2 | Springer Series in Surface Sciences |
| spelling | Fromm, Eckehard Verfasser aut Kinetics of Metal-Gas Interactions at Low Temperatures Hydriding, Oxidation, Poisoning by Eckehard Fromm Berlin, Heidelberg Springer Berlin Heidelberg 1998 1 Online-Ressource (XIII, 206p. 103 illus) txt rdacontent c rdamedia cr rdacarrier Springer Series in Surface Sciences 36 0931-5195 Kinetics of Metal-Gas Interactions at Low Temperatures is devoted to the formation of natural oxide films. These thin surface layers are produced instantaneously when oxygen or water vapor is present in the gas atmosphere. They are responsible for corrosion behavior, for wear and friction of metallic materials, and also for hydrogen embrittlement and poisoning of catalytic surface reactions. Oxidation is a hindrance in surface science and in modern thin-film manufacturing. It can be reliably avoided only with expensive ultra-high vacuum techniques. Despite the practical relevance of the topic, quantitative data are sparse and the few papers published on low-temperature oxidation provide mainly qualitative information. This monograph presents an introduction to the subject in a tutorial style. It demonstrates how complex metal-gas interactions can be analyzed by standard procedures of chemical kinetics, and simulated by reaction models. Typical features of metal-gas reactions observed at ambient and elevated temperatures are illustrated by experimental results. Possible reaction mechanisms are described both by approximations and by advanced models. Rate and time laws describe the limiting cases and the more realistic situation where, in an overall reaction, several crucial partial steps must be considered, namely, adsorption onto the surface and the diffusion of charged or uncharged defects in metallic or semiconducting surface layers Physics Optical materials Surface and Interface Science, Thin Films Strongly Correlated Systems, Superconductivity Optical and Electronic Materials Reaktionskinetik (DE-588)4048655-2 gnd rswk-swf Wasserstoff (DE-588)4064784-5 gnd rswk-swf Metalloxide (DE-588)4169619-0 gnd rswk-swf Metall-Wasserstoff-System (DE-588)4169641-4 gnd rswk-swf Dünne Schicht (DE-588)4136925-7 gnd rswk-swf Lösung Chemie (DE-588)4036159-7 gnd rswk-swf Oxidation (DE-588)4137187-2 gnd rswk-swf Niedrigtemperatur (DE-588)4417434-2 gnd rswk-swf Metallhydride (DE-588)4169593-8 gnd rswk-swf Metalloberfläche (DE-588)4169612-8 gnd rswk-swf Metalloberfläche (DE-588)4169612-8 s Wasserstoff (DE-588)4064784-5 s Lösung Chemie (DE-588)4036159-7 s Reaktionskinetik (DE-588)4048655-2 s Metallhydride (DE-588)4169593-8 s Dünne Schicht (DE-588)4136925-7 s 1\p DE-604 Oxidation (DE-588)4137187-2 s Niedrigtemperatur (DE-588)4417434-2 s Metalloxide (DE-588)4169619-0 s 2\p DE-604 Metall-Wasserstoff-System (DE-588)4169641-4 s 3\p DE-604 https://doi.org/10.1007/978-3-642-60311-2 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Fromm, Eckehard Kinetics of Metal-Gas Interactions at Low Temperatures Hydriding, Oxidation, Poisoning Physics Optical materials Surface and Interface Science, Thin Films Strongly Correlated Systems, Superconductivity Optical and Electronic Materials Reaktionskinetik (DE-588)4048655-2 gnd Wasserstoff (DE-588)4064784-5 gnd Metalloxide (DE-588)4169619-0 gnd Metall-Wasserstoff-System (DE-588)4169641-4 gnd Dünne Schicht (DE-588)4136925-7 gnd Lösung Chemie (DE-588)4036159-7 gnd Oxidation (DE-588)4137187-2 gnd Niedrigtemperatur (DE-588)4417434-2 gnd Metallhydride (DE-588)4169593-8 gnd Metalloberfläche (DE-588)4169612-8 gnd |
| subject_GND | (DE-588)4048655-2 (DE-588)4064784-5 (DE-588)4169619-0 (DE-588)4169641-4 (DE-588)4136925-7 (DE-588)4036159-7 (DE-588)4137187-2 (DE-588)4417434-2 (DE-588)4169593-8 (DE-588)4169612-8 |
| title | Kinetics of Metal-Gas Interactions at Low Temperatures Hydriding, Oxidation, Poisoning |
| title_auth | Kinetics of Metal-Gas Interactions at Low Temperatures Hydriding, Oxidation, Poisoning |
| title_exact_search | Kinetics of Metal-Gas Interactions at Low Temperatures Hydriding, Oxidation, Poisoning |
| title_full | Kinetics of Metal-Gas Interactions at Low Temperatures Hydriding, Oxidation, Poisoning by Eckehard Fromm |
| title_fullStr | Kinetics of Metal-Gas Interactions at Low Temperatures Hydriding, Oxidation, Poisoning by Eckehard Fromm |
| title_full_unstemmed | Kinetics of Metal-Gas Interactions at Low Temperatures Hydriding, Oxidation, Poisoning by Eckehard Fromm |
| title_short | Kinetics of Metal-Gas Interactions at Low Temperatures |
| title_sort | kinetics of metal gas interactions at low temperatures hydriding oxidation poisoning |
| title_sub | Hydriding, Oxidation, Poisoning |
| topic | Physics Optical materials Surface and Interface Science, Thin Films Strongly Correlated Systems, Superconductivity Optical and Electronic Materials Reaktionskinetik (DE-588)4048655-2 gnd Wasserstoff (DE-588)4064784-5 gnd Metalloxide (DE-588)4169619-0 gnd Metall-Wasserstoff-System (DE-588)4169641-4 gnd Dünne Schicht (DE-588)4136925-7 gnd Lösung Chemie (DE-588)4036159-7 gnd Oxidation (DE-588)4137187-2 gnd Niedrigtemperatur (DE-588)4417434-2 gnd Metallhydride (DE-588)4169593-8 gnd Metalloberfläche (DE-588)4169612-8 gnd |
| topic_facet | Physics Optical materials Surface and Interface Science, Thin Films Strongly Correlated Systems, Superconductivity Optical and Electronic Materials Reaktionskinetik Wasserstoff Metalloxide Metall-Wasserstoff-System Dünne Schicht Lösung Chemie Oxidation Niedrigtemperatur Metallhydride Metalloberfläche |
| url | https://doi.org/10.1007/978-3-642-60311-2 |
| work_keys_str_mv | AT frommeckehard kineticsofmetalgasinteractionsatlowtemperatureshydridingoxidationpoisoning |