Optical Studies in Liquids and Solids:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Boston, MA
Springer US
1969
|
| Schriftenreihe: | Proceedings (Trudy) of the P. N. Lebedev Physics Institute
39 |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Beschreibung: | The study of the vibrations of polyatomic molecules has recently turned into one of the most widespread and powerful methods of studying molecular structure. These vibrations appear directly in the infrared absorption spectra and Raman spectra of gases, liquids, and solids. A measurement of the number of bands in addition to their positions (frequencies or wavelengths) offers the possibility of obtaining a great deal of important information regarding the geometric and mechanical properties of the molecules, the types of chemical bonds, and so forth. It is now quite difficult to list the vast number of specific problems solved by measuring vibrational frequencies. As a result of the successful development of research methods and the widespread application of vibrational spectra in analyzing the structures of molecules and the constitution of materials, it now becomes necessary to develop the theory of molecular vibrations further. Existing theory, of course, is based on the assumption of the harmonicity of molecular vibrations, which, strictly speaking, is not justified experimentally. The anharmonicity of the molecular vibrations has therefore to be taken into account by introducing appropriate approximations. Thus, in carrying out calculations on the vibrations of polyatomic molecules, one uses the force constants calculated from the observed frequency values. However, as a result of the anharmonicity of the vibrations, the values of the observed frequencies differ from the harmonic values, and the force constants used therefore differ from the true ones, i. e |
| Beschreibung: | 1 Online-Ressource (IX, 266 p) |
| ISBN: | 9781468487244 9781468487268 |
| DOI: | 10.1007/978-1-4684-8724-4 |
Internformat
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| 245 | 1 | 0 | |a Optical Studies in Liquids and Solids |c edited by Academician D. V. Skobel'tsyn |
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| 490 | 1 | |a The Lebedev Physics Institute Series |v 39 | |
| 500 | |a The study of the vibrations of polyatomic molecules has recently turned into one of the most widespread and powerful methods of studying molecular structure. These vibrations appear directly in the infrared absorption spectra and Raman spectra of gases, liquids, and solids. A measurement of the number of bands in addition to their positions (frequencies or wavelengths) offers the possibility of obtaining a great deal of important information regarding the geometric and mechanical properties of the molecules, the types of chemical bonds, and so forth. It is now quite difficult to list the vast number of specific problems solved by measuring vibrational frequencies. As a result of the successful development of research methods and the widespread application of vibrational spectra in analyzing the structures of molecules and the constitution of materials, it now becomes necessary to develop the theory of molecular vibrations further. Existing theory, of course, is based on the assumption of the harmonicity of molecular vibrations, which, strictly speaking, is not justified experimentally. The anharmonicity of the molecular vibrations has therefore to be taken into account by introducing appropriate approximations. Thus, in carrying out calculations on the vibrations of polyatomic molecules, one uses the force constants calculated from the observed frequency values. However, as a result of the anharmonicity of the vibrations, the values of the observed frequencies differ from the harmonic values, and the force constants used therefore differ from the true ones, i. e | ||
| 650 | 4 | |a Physics | |
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Datensatz im Suchindex
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| dewey-full | 539 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 539 - Modern physics |
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| dewey-search | 539 |
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| dewey-tens | 530 - Physics |
| discipline | Physik |
| doi_str_mv | 10.1007/978-1-4684-8724-4 |
| format | Electronic eBook |
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| id | DE-604.BV042412191 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T01:20:50Z |
| institution | BVB |
| isbn | 9781468487244 9781468487268 |
| language | English |
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| oclc_num | 863986237 |
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| owner_facet | DE-91 DE-BY-TUM DE-83 |
| physical | 1 Online-Ressource (IX, 266 p) |
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| publishDate | 1969 |
| publishDateSearch | 1969 |
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| publisher | Springer US |
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| series | Proceedings (Trudy) of the P. N. Lebedev Physics Institute |
| series2 | The Lebedev Physics Institute Series |
| spelling | Optical Studies in Liquids and Solids edited by Academician D. V. Skobel'tsyn Boston, MA Springer US 1969 1 Online-Ressource (IX, 266 p) txt rdacontent c rdamedia cr rdacarrier The Lebedev Physics Institute Series 39 The study of the vibrations of polyatomic molecules has recently turned into one of the most widespread and powerful methods of studying molecular structure. These vibrations appear directly in the infrared absorption spectra and Raman spectra of gases, liquids, and solids. A measurement of the number of bands in addition to their positions (frequencies or wavelengths) offers the possibility of obtaining a great deal of important information regarding the geometric and mechanical properties of the molecules, the types of chemical bonds, and so forth. It is now quite difficult to list the vast number of specific problems solved by measuring vibrational frequencies. As a result of the successful development of research methods and the widespread application of vibrational spectra in analyzing the structures of molecules and the constitution of materials, it now becomes necessary to develop the theory of molecular vibrations further. Existing theory, of course, is based on the assumption of the harmonicity of molecular vibrations, which, strictly speaking, is not justified experimentally. The anharmonicity of the molecular vibrations has therefore to be taken into account by introducing appropriate approximations. Thus, in carrying out calculations on the vibrations of polyatomic molecules, one uses the force constants calculated from the observed frequency values. However, as a result of the anharmonicity of the vibrations, the values of the observed frequencies differ from the harmonic values, and the force constants used therefore differ from the true ones, i. e Physics Atomic, Molecular, Optical and Plasma Physics Flüssigkeit (DE-588)4017621-6 gnd rswk-swf Optik (DE-588)4043650-0 gnd rswk-swf Flüssigkeit (DE-588)4017621-6 s Optik (DE-588)4043650-0 s 1\p DE-604 Skobelʹcyn, Dmitrij Vladimirovič 1892-1990 (DE-588)1041834187 edt Proceedings (Trudy) of the P. N. Lebedev Physics Institute 39 (DE-604)BV024978434 39 https://doi.org/10.1007/978-1-4684-8724-4 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Optical Studies in Liquids and Solids Proceedings (Trudy) of the P. N. Lebedev Physics Institute Physics Atomic, Molecular, Optical and Plasma Physics Flüssigkeit (DE-588)4017621-6 gnd Optik (DE-588)4043650-0 gnd |
| subject_GND | (DE-588)4017621-6 (DE-588)4043650-0 |
| title | Optical Studies in Liquids and Solids |
| title_auth | Optical Studies in Liquids and Solids |
| title_exact_search | Optical Studies in Liquids and Solids |
| title_full | Optical Studies in Liquids and Solids edited by Academician D. V. Skobel'tsyn |
| title_fullStr | Optical Studies in Liquids and Solids edited by Academician D. V. Skobel'tsyn |
| title_full_unstemmed | Optical Studies in Liquids and Solids edited by Academician D. V. Skobel'tsyn |
| title_short | Optical Studies in Liquids and Solids |
| title_sort | optical studies in liquids and solids |
| topic | Physics Atomic, Molecular, Optical and Plasma Physics Flüssigkeit (DE-588)4017621-6 gnd Optik (DE-588)4043650-0 gnd |
| topic_facet | Physics Atomic, Molecular, Optical and Plasma Physics Flüssigkeit Optik |
| url | https://doi.org/10.1007/978-1-4684-8724-4 |
| volume_link | (DE-604)BV024978434 |
| work_keys_str_mv | AT skobelʹcyndmitrijvladimirovic opticalstudiesinliquidsandsolids |