Magnetism Diagrams for Transition Metal Ions:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Boston, MA
Springer US
1979
|
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Beschreibung: | The study ofmagneticproperties as a method to determine molecularand electronic structure of the ground state has a long tradition, in particular as far as metal complexes and solids of the transition metals are concerned. In the early days of the development, the emphasiswas placedon the observation ofdeviationsfrom the "spin-only" magnetic moment, the underlying assumption being that the value of themomentatroomtemperaturewouldsufficetodetermine boththeoxidationstate of the metal and the stereochemistry of the complex. The increasing number of deviations from these simple rules shifted the interest of researchers to the more detailed study ofthe temperature dependence of the magnetic moment. Most of the experimentalresults was then limited to measurementson powderedsubstancesand totemperatures between 77 and 300 K. Although themajorityofdataarestillofthis type, magnetic studies down to or even below 4. 2 K have become more common within the last few years as the sophistication of the equipment has increased. In addition, the investigation of magnetic anisotropies and principal magnetic suscep tibilities received a new impetus. In order to make the best possible use of the theory, magnetism diagrams based on calculations by the ligand field theory were produced. As a rule, these diagrams show the effective magnetic moment as a function of the temperature and of any N additional parameters of interest. The first magnetism diagrams applicable to d electronicconfigurationswerepublished 30 yearsago byKotani. Thesediagrams are limited to the configurations (t2g)N, N = 1 to 4, in octahedral symmetry |
| Beschreibung: | 1 Online-Ressource |
| ISBN: | 9781461330035 9781461330059 |
| DOI: | 10.1007/978-1-4613-3003-5 |
Internformat
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| 500 | |a The study ofmagneticproperties as a method to determine molecularand electronic structure of the ground state has a long tradition, in particular as far as metal complexes and solids of the transition metals are concerned. In the early days of the development, the emphasiswas placedon the observation ofdeviationsfrom the "spin-only" magnetic moment, the underlying assumption being that the value of themomentatroomtemperaturewouldsufficetodetermine boththeoxidationstate of the metal and the stereochemistry of the complex. The increasing number of deviations from these simple rules shifted the interest of researchers to the more detailed study ofthe temperature dependence of the magnetic moment. Most of the experimentalresults was then limited to measurementson powderedsubstancesand totemperatures between 77 and 300 K. Although themajorityofdataarestillofthis type, magnetic studies down to or even below 4. 2 K have become more common within the last few years as the sophistication of the equipment has increased. In addition, the investigation of magnetic anisotropies and principal magnetic suscep tibilities received a new impetus. In order to make the best possible use of the theory, magnetism diagrams based on calculations by the ligand field theory were produced. As a rule, these diagrams show the effective magnetic moment as a function of the temperature and of any N additional parameters of interest. The first magnetism diagrams applicable to d electronicconfigurationswerepublished 30 yearsago byKotani. Thesediagrams are limited to the configurations (t2g)N, N = 1 to 4, in octahedral symmetry | ||
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Datensatz im Suchindex
| _version_ | 1804153072681746432 |
|---|---|
| any_adam_object | |
| author | König, E. |
| author_facet | König, E. |
| author_role | aut |
| author_sort | König, E. |
| author_variant | e k ek |
| building | Verbundindex |
| bvnumber | BV042411371 |
| classification_tum | PHY 000 |
| collection | ZDB-2-PHA ZDB-2-BAE |
| ctrlnum | (OCoLC)863801734 (DE-599)BVBBV042411371 |
| dewey-full | 538 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 538 - Magnetism |
| dewey-raw | 538 |
| dewey-search | 538 |
| dewey-sort | 3538 |
| dewey-tens | 530 - Physics |
| discipline | Physik |
| doi_str_mv | 10.1007/978-1-4613-3003-5 |
| format | Electronic eBook |
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| id | DE-604.BV042411371 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T01:20:48Z |
| institution | BVB |
| isbn | 9781461330035 9781461330059 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027846864 |
| oclc_num | 863801734 |
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| owner_facet | DE-91 DE-BY-TUM DE-83 |
| physical | 1 Online-Ressource |
| psigel | ZDB-2-PHA ZDB-2-BAE ZDB-2-PHA_Archive |
| publishDate | 1979 |
| publishDateSearch | 1979 |
| publishDateSort | 1979 |
| publisher | Springer US |
| record_format | marc |
| spelling | König, E. Verfasser aut Magnetism Diagrams for Transition Metal Ions by E. König, S. Kremer Boston, MA Springer US 1979 1 Online-Ressource txt rdacontent c rdamedia cr rdacarrier The study ofmagneticproperties as a method to determine molecularand electronic structure of the ground state has a long tradition, in particular as far as metal complexes and solids of the transition metals are concerned. In the early days of the development, the emphasiswas placedon the observation ofdeviationsfrom the "spin-only" magnetic moment, the underlying assumption being that the value of themomentatroomtemperaturewouldsufficetodetermine boththeoxidationstate of the metal and the stereochemistry of the complex. The increasing number of deviations from these simple rules shifted the interest of researchers to the more detailed study ofthe temperature dependence of the magnetic moment. Most of the experimentalresults was then limited to measurementson powderedsubstancesand totemperatures between 77 and 300 K. Although themajorityofdataarestillofthis type, magnetic studies down to or even below 4. 2 K have become more common within the last few years as the sophistication of the equipment has increased. In addition, the investigation of magnetic anisotropies and principal magnetic suscep tibilities received a new impetus. In order to make the best possible use of the theory, magnetism diagrams based on calculations by the ligand field theory were produced. As a rule, these diagrams show the effective magnetic moment as a function of the temperature and of any N additional parameters of interest. The first magnetism diagrams applicable to d electronicconfigurationswerepublished 30 yearsago byKotani. Thesediagrams are limited to the configurations (t2g)N, N = 1 to 4, in octahedral symmetry Physics Chemistry, inorganic Magnetism Magnetism, Magnetic Materials Inorganic Chemistry Übergangsmetallion (DE-588)4186579-0 gnd rswk-swf Magnetische Resonanz (DE-588)4196789-6 gnd rswk-swf Übergangsmetall (DE-588)4078494-0 gnd rswk-swf Tabelle (DE-588)4184303-4 gnd rswk-swf Magnetische Kernresonanz (DE-588)4037005-7 gnd rswk-swf Magnetismus (DE-588)4037021-5 gnd rswk-swf Ligandenfeldtheorie (DE-588)4167657-9 gnd rswk-swf Diagramm (DE-588)4012044-2 gnd rswk-swf Übergangsmetall (DE-588)4078494-0 s Magnetismus (DE-588)4037021-5 s Tabelle (DE-588)4184303-4 s 1\p DE-604 Ligandenfeldtheorie (DE-588)4167657-9 s Diagramm (DE-588)4012044-2 s 2\p DE-604 Magnetische Resonanz (DE-588)4196789-6 s 3\p DE-604 Magnetische Kernresonanz (DE-588)4037005-7 s 4\p DE-604 5\p DE-604 Übergangsmetallion (DE-588)4186579-0 s 6\p DE-604 Kremer, S. Sonstige oth https://doi.org/10.1007/978-1-4613-3003-5 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 4\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 5\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 6\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | König, E. Magnetism Diagrams for Transition Metal Ions Physics Chemistry, inorganic Magnetism Magnetism, Magnetic Materials Inorganic Chemistry Übergangsmetallion (DE-588)4186579-0 gnd Magnetische Resonanz (DE-588)4196789-6 gnd Übergangsmetall (DE-588)4078494-0 gnd Tabelle (DE-588)4184303-4 gnd Magnetische Kernresonanz (DE-588)4037005-7 gnd Magnetismus (DE-588)4037021-5 gnd Ligandenfeldtheorie (DE-588)4167657-9 gnd Diagramm (DE-588)4012044-2 gnd |
| subject_GND | (DE-588)4186579-0 (DE-588)4196789-6 (DE-588)4078494-0 (DE-588)4184303-4 (DE-588)4037005-7 (DE-588)4037021-5 (DE-588)4167657-9 (DE-588)4012044-2 |
| title | Magnetism Diagrams for Transition Metal Ions |
| title_auth | Magnetism Diagrams for Transition Metal Ions |
| title_exact_search | Magnetism Diagrams for Transition Metal Ions |
| title_full | Magnetism Diagrams for Transition Metal Ions by E. König, S. Kremer |
| title_fullStr | Magnetism Diagrams for Transition Metal Ions by E. König, S. Kremer |
| title_full_unstemmed | Magnetism Diagrams for Transition Metal Ions by E. König, S. Kremer |
| title_short | Magnetism Diagrams for Transition Metal Ions |
| title_sort | magnetism diagrams for transition metal ions |
| topic | Physics Chemistry, inorganic Magnetism Magnetism, Magnetic Materials Inorganic Chemistry Übergangsmetallion (DE-588)4186579-0 gnd Magnetische Resonanz (DE-588)4196789-6 gnd Übergangsmetall (DE-588)4078494-0 gnd Tabelle (DE-588)4184303-4 gnd Magnetische Kernresonanz (DE-588)4037005-7 gnd Magnetismus (DE-588)4037021-5 gnd Ligandenfeldtheorie (DE-588)4167657-9 gnd Diagramm (DE-588)4012044-2 gnd |
| topic_facet | Physics Chemistry, inorganic Magnetism Magnetism, Magnetic Materials Inorganic Chemistry Übergangsmetallion Magnetische Resonanz Übergangsmetall Tabelle Magnetische Kernresonanz Magnetismus Ligandenfeldtheorie Diagramm |
| url | https://doi.org/10.1007/978-1-4613-3003-5 |
| work_keys_str_mv | AT konige magnetismdiagramsfortransitionmetalions AT kremers magnetismdiagramsfortransitionmetalions |