Closed-shell and open-shell ferracyclobutadienes-syntheses, characterization and reactivity studies:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
Berlin
mbv, Mensch-und-Buch-Verl.
2014
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | III, 403 S. graph. Darst. 21 cm |
| ISBN: | 9783863875510 |
Internformat
MARC
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| 008 | 150224s2014 d||| m||| 00||| eng d | ||
| 020 | |a 9783863875510 |c kart. : EUR 49.90 |9 978-3-86387-551-0 | ||
| 035 | |a (OCoLC)904025769 | ||
| 035 | |a (DE-599)BVBBV042375919 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-29T | ||
| 082 | 0 | |a 547.05621 |2 22//ger | |
| 100 | 1 | |a Das, Ujjal |d 1984- |e Verfasser |0 (DE-588)1064965180 |4 aut | |
| 245 | 1 | 0 | |a Closed-shell and open-shell ferracyclobutadienes-syntheses, characterization and reactivity studies |c Ujjal Das |
| 264 | 1 | |a Berlin |b mbv, Mensch-und-Buch-Verl. |c 2014 | |
| 300 | |a III, 403 S. |b graph. Darst. |c 21 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a Zugl.: Bonn, Univ., Diss., 2014 | ||
| 650 | 0 | 7 | |a Cyclobutadienderivate |0 (DE-588)4148500-2 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Strukturaufklärung |0 (DE-588)4183788-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Chemische Synthese |0 (DE-588)4133806-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Reaktivität |0 (DE-588)4208182-8 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Eisenorganische Verbindungen |0 (DE-588)4151587-0 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Eisenorganische Verbindungen |0 (DE-588)4151587-0 |D s |
| 689 | 0 | 1 | |a Cyclobutadienderivate |0 (DE-588)4148500-2 |D s |
| 689 | 0 | 2 | |a Chemische Synthese |0 (DE-588)4133806-6 |D s |
| 689 | 0 | 3 | |a Strukturaufklärung |0 (DE-588)4183788-5 |D s |
| 689 | 0 | 4 | |a Reaktivität |0 (DE-588)4208182-8 |D s |
| 689 | 0 | |5 DE-604 | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027812095&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-027812095 | ||
Datensatz im Suchindex
| _version_ | 1804153015420059648 |
|---|---|
| adam_text | 1
INDEX
1. INTRODUCTION 6
1.1 METALLACYCLOBUTADIENES 6
1.2 SYNTHESES OF METALLACYCLOBUTADIENES 12
1.3 GROUP 6 METALLACYCLOBUTADIENES 16
1.4 GROUP 7 METALLACYCLOBUTADIENES 20
1.5 GROUP 9 METALLACYCLOBUTADIENES 22
1.6 VALENCE ISOMERISATION OF METALLACYCLOBUTADIENES 23
1.7 STRUCTURE AND BONDING OF METALLACYCLOBUTADIENES 27
1.8 ELECTRON RICH CATIONIC FERRACYCLOBUTADIENES [FE{C3(NR2)3}(CO)3][BF
4
] 30
2. GOALS AND OBJECTIVES 32
3. RESULTS AND DISCUSSION 33
3.1 SYNTHESES OF CLOSED-SHELL 16VE FERRACYCLOBUTADIENES 33
3.1.1 SYNTHESIS OF [FE(CO)
3
{C
3
(NET2)3}]BF4 33
3.1.2 SYNTHESES OF [FE{K
2
-C3(NET2)
3
}(CO)2L]BF
4
41
3.1.3 SYNTHESES OF [FE{K
2
-C
3
(NET
2
)3}(CO)L
2
]BF
4
44
3.1.4 SYNTHESES OF [FE {K
2
-C
3
(NR
2
)3
} (CO)
2
(NU)] (NU = CI, N
3
, NC4H4) 45
3.1.5 SYNTHESES OF [FE {
K
2
-C
3
(NR
2
)
3
} (CO)
2
(E)] (E = SNME
3
, MECO, BUCO) 47
3.1.6 MISCELLANEOUS METHODS OF SYNTHESES 51
3.2 MOLECULAR STRUCTURES OF 16VE CLOSED-SHELL FERRACYCLOBUTADIENES 53
3.3 NMR-SPECTROSCOPIC DATA OF CLOSED-SHELL 16VE FERRACYCLOBUTADIENES 67
3.4 INFRARED SPECTROSCOPIC DATA OF CLOSED-SHELL FERRACYCLOBUTADIENES: 86
3.5 UV-VIS SPECTROSCOPIC DATA OF THE CLOSED-SHELL 16VE
FERRACYCLOBUTADIENES 91
3.6 MFISSBAUER SPECTROSCOPIC DATA OF 16VE CLOSED-SHELL
FERRACYCLOBUTADIENES 93
3.7 OPEN-SHELL FERRACYCLOBUTADIENES 95
3.7.1 17VE FERRACYCLOBUTADIENES [FE(CO)2L{C3(NET2)3}]; (L = PME3, IM-ME
4
) 98
3.7.2 15VE FERRACYCLOBUTADIENES [FE(CO)L2{C3(NET2)
3
][BARF24]2;
(L = PME3, IM-ME4)
117
3.8 REACTIVITY STUDIES OF THE CLOSED-SHELL FERRACYCLOBUTADIENES 128
3.8.1 NUCLEOPHILIC ADDITIONS 128
3.8.2 OXIDATIVE ADDITION 136
3.8.3 TWO ELECTRON REDUCTIONS AND TRAPPING EXPERIMENTS 148
3.8.3.1 TWO ELECTRON REDUCTION OF 16VE CATIONIC FERRACYCLOBUTADIENES 148
3.8.3.2 TRAPPING OF A FERRACYCLOBUTADIENE SALT WITH ALLYLCHLORIDE 156
3.8.3.3 ELECTROPHILIC TRAPPING OF FERRACYCLOBUTADIENE SALTS 162
3.8.3.4 TRAPPING REACTION WITH ARECL (E = GE, SN) 169
3.8.4 NITRENE INSERTION INTO FERRACYCLOBUTADIENES 176
3.8.5 SYNTHESES OF THE ZWITTER-IONIC [7, 8]-DIHYDROPENTALENE COMPLEXES
183
3.8.6 POLY(DIALKYLAMINO)CYCLOPENTADIENYL COMPLEXES: SYNTHESES AND
REACTIVITIES 195
3.8.6.1 SYNTHESES OF POLY(DIALKYLAMINO)CYCLOPENTADIENYL COMPLEXES OF
IRON 196
3.8.6.2 MOLECULAR STRUCTURES OF POLY(DIALKYLAMINO)CYCLOPENTADIENYL
COMPLEXES OF IRON222
3.8.6.3 SPECTROSCOPIC FEATURES OF THE POLYAMINOCYCLOPENTADIENYL
COMPLEXES IRON 233
3.8.6.4 REACTIVITY STUDIES OF IRON PENTA(DIALKYLAMINO)CYCLOPENTADIENYL
COMPLEXES 237
3.8.6.4.1 REDOX BEHAVIOR OF [FE(CO)
3
{C
5
NME
2
}5]BF
4
(PA-CP-1) 237
3.8.6.4.2 CS(NME2)5 LIGAND TRANSFER REACTIONS 243
3.8.6.4.3 SYNTHESES AND REACTIVITY OF POLY(DIALKYLAMINO)FERROCENES 246
4. SUMMARY 255
5. OUTLOOK 262
6. EXPERIMENTAL SECTION 265
HTTP://D-NB.INFO/1064722520
2
6.1 GENERAL PART 265
6.2 ANALYTICAL METHODS 266
6.3 LIST OF AVAILABLE CHEMICALS 270
6.4 LIST OF COMPOUNDS SYNTHESIZED ACCORDING TO THE REPORTED PROCEDURES
271
6.5 SYNTHESES 272
6.5.1 [FE{C
2
(NET
2
)2(C=0)}(C0)3] (1) 272
6.5.2 [FE{C
2
(NET
2
)
2
C(NET)}(CO)
3
] (2) 272
6.5.3 [FE{K
2
-N(ME)CCN(ME)C(0)(C2(NET2)
2
)}(C0)
3
] (3) 273
6.5.4 [FE{C
3
(NET
2
)3
}(CO
)3
]BF
4
(FCB-ET
-4)
274
6.5.5 [FE{C
3
(NET
2
)
3
}(CO)
2
(MECN)]BF
4
(FCB-ET-5) 276
6.5.6 [FE
{C3
(NET
2
)
3
}(CO)
2
(NC
5
H
5
)]BF4
(FCB-ET-6) 277
6.5.7 [FE{C
3
(NET
2
)
3
}(CO
)2
(ME
3
P
)]BF4
(FCB-ET-7) 279
6.5.8 [FE{C
3
(NET
2
)3
}(CO)
2
(PPH
3
)]BF4
(FCB-ET-9) 281
6.5.9 [FE{C
3
(NET
2
)3
}(CO)
2
(CNME
)]BF4
(FCB-ET-10) 282
6.5.10 [FE
{C
3
(NET
2
)
3
}
(CO)
2
(CN
L
BU)]BF
4
(FCB-ET-11) 283
6.5.11 [FE{C
3
(NET
2
)
3
}(CO)
2
(IM-ME
4
)]BF
4
(FCB-ET-12) 284
6.5.12 [FE{C
3
(NET
2
)
3
}(CO)(PME
3
)
2
]BF
4
(FCB-ET-13) 284
6.5.13 [FE{C
3
(NET
2
)
3
}(CO)(IM-ME
4
)
2
]BF
4
(FCB-ET-14) 286
6.5.14 [FE{C
3
(NET
2
)
3
}(CO)
2
CL] (FCB-ET-15) 286
6.5.15 [FE{C
3
(NET
2
)
3
}(CO)
2
(N
3
)] (FCB-ET-16) 287
6.5.16 [FE
{C3
(NET
2
)
3
}(CO)
2
(SNMEJ)] (FCB-ET-19) 288
6.5.17 [FE{C
3
(NET
2
)
3
}(CO)
2
(CH
3
CO)] (FCB-ET-20) 289
6.5.18 [FE{C
3
(NET
2
)
3
}(CO)
2
( BUCO)] (FCB-ET-21) 290
6.5.19 [FE{C
3
(NET
2
)
3
}(CO)
2
(CH
2
CN)] (FCB-ET-22) 291
6.5.20 [FE{C
3
(NET
2
)
3
}(CO)
2
(ME
3
P)
2
]BF
4
(FCB-ET-24) 292
6.5.21 [FE{C
3
(NET
2
)
3
}I
2
(CO)(PME
3
)]L3 (FCB-ET-25) 292
6.5.22 [FE{C
3
(NET
2
)
3
}I
2
(CO)(CNME)]BF
4
(FCB-ET-27) 293
6.5.23 [FE{C
3
(NET
2
)
3
}I
2
(CO)(CN BU
)][BF4]
(FCB-ET-28) 294
6.5.24 [FE{C
3
(NET
2
)
3
}I
2
(CNME)
2
]BF
4
(FCB-ET-29) 295
6.5.25 HG[FE{C
3
(NET
2
)
3
}(CO)
3
]
2
(FCB-ET-30) 296
6.5.26 [FE{C
3
(NET
2
)
3
}(CO)
2
(C
3
H
5
CO)] (FCB-ET-32) 297
6.5.27 [FE{C
3
(NET
2
)
3
}(CO)
2
(PME
3
)] (FCB-ET-34) 298
6.5.28 [FE{C
3
(NET
2
)
3
}(CO)
2
(IM-ME
4
)] (FCB-ET-35) 298
6.5.29 [FE{C
3
(NET
2
)
3
}(CO)(PME
3
)
2
][BARF
24
]
2
(FCB-ET-36) 299
6.5.30 [FE{C
3
(NET
2
)
3
}(CO)(IM-ME
4
)
2
][BARF
24
]
2
(FCB-ET-37) 299
6.5.31 [{C
3
(NME
2
)
3
GE(AR
TNP
)}FE(CO)
4
] (43) 300
6.5.32 [FE{C
3
(NET
2
)
3
N}(CO)
3
] (45) 301
6.5.33 [{C
8
H
5
(NET
2
)
3
}FE(CO)
3
] (47) 302
6.5.34 [{C
8
H
5
(NME
2
)
3
}FE(CO
)3]
(48)
303
6.5.35 [{CGHS(NET
2
)3}
FE(CO)
2
(PME
3
)] (49) 304
6.5.36 [{C
5
(NET
2
)
4
(PH)}FE(CO)
2
][BARF
24
] (56) 305
6.5.37 [FE{C
5
(NET
2
)3(NME
2
)(PH)}(CO)
2
][BARF
2
4] (57) 306
6.5.38 [FE{C
3
(NME2)
3
}(CO)
3
]BF
4
(FCB-ME-1) 308
6.5.39 [FE{C
3
(NME
2
)
3
}(CO)
2
(MECN)]BF
4
(FCB-ME-2) 309
6.5.40 [FE{C
3
(NME
2
)
3
}(CO)
2
(NC
5
H
5
)]BF
4
(FCB-ME-3) 309
6.5.41 [FE{C
3
(NME
2
)
3
}(CO)
2
(PHCN)]BF
4
310
6.5.42 [FE{C
3
(NME
2
)
3
}(CO)
2
(PME
3
)]BF
4
(FCB-ME-4) 310
6.5.43 [FE
{C
3
(NME
2
)
3
}
(CO)
2
(CN BU)]BF
4
(FCB-ME-5) 312
6.5.44 [FE
{C
3
(NME
2
)
3
}(CO)
2
(CL)] (FCB-ME-6) 312
6.5.45 [FE{C
3
(NME
2
)
3
}(CO)
2
(SNME
3
)] (FCB-ME-8) 313
6.5.46 [FE{C
3
(NME
2
)
3
}(CO)
2
(CH
3
CO)] (FCB-ME-9) 314
3
6.5.47 [FE{C
3
(NME
2
)3}L2(CO)( BUNC)] (FCB-ME-10) 315
6.5.48 HG[FE{C
3
(NME
2
)3}(CO)3]2 (FCB-ME-11) 316
6.5.49 [FE{C(NET2)C(NET
2
)C(NET2)(ME)}(CO)
2
] (AC-1) 316
6.5.50 [FE{T!
3
-C
2
(NET2)2CH(NET
2
}(CO)3] (AC-2) 317
6.5.51 [FE{T)
3
-C
2
(NME
2
)
2
CH(NME
2
)}(CO)
3
] (AC-3) 317
6.5.52 [FE
{TI
3
-C
2
(NET
2
)2C(NET
2
)(NC
4
H4)}(CO)3)] (AC-4) 318
6.5.53 [FE{TI
3
-C2(NME
2
)
2
C(NME
2
)(C
4
H4N}(CO)3] (AC-6) 319
6.5.54 [FE{TI
2
-C
2
(NME
2
)
2
CH(NME
2
)}(CO)
3
] (AC-8) 319
6.5.55 [FE{C
3
(NET
2
)3(AUPPH
3
)}(CO)
3
] (AC-9) 320
6.5.56 [FE{C
3
(NME
2
)
3
(AUPPH
3
)}(CO)
3
] (AC-10) 321
6.5.57 [{C
5
(NME
2
)
5
}FE(CO)
3
]BF
4
(PA-CP-1) 322
6.5.58 [{C
5
(NME
2
)
3
(NET
2
)
2
}FE(CO)
3
]BF
4
(PA-CP-2) 322
6.5.59 [{C
5
(NME
2
)
5
}FE(CO)
2
(
,
BUNC)][BF4] (PA-CP-3) 323
6.5.60 [{C
5
(NME
2
)
5
}FE(CO)
2
(MECN)]BF
4
(PA-CP-4) 323
6.5.61 [{C
5
(NME
2
)
3
(NET2)2}FE(CO)
2
(MECN)]BF
4
(PA-CP-5) 324
6.5.62 [ {C
5
(NME
2
)
3
(NET
2
)
2
}FE(CO)2(PME
3
)]BF
4
(PA-CP-6) 324
6.5.63 [ {C
5
(NME
2
)
3
(NET2)ME}FE(CO)
3
]BF
4
325
6.5.64 [{C
5
(NME
2
)
5
}FE(CO)
2
(SNME
3
)] (PA-CP-7) 326
6.5.65 [ {C
5
(NME
2
)
3
(NET
2
)2}FE(CO)
2
(SNME
3
)] (PA-CP-8) 326
6.5.66 [{C
5
(NME
2
)5}FE(CO)
2
(MECO)] (PA-CP-9) 327
6.5.67 [ {C
5
(NET
2
)
3
(NME
2
)
2
}FE(CO)
2
(CH
2
CN)] (PA-CP-10) 327
6.5.68 [ {C
5
(NME
2
)
5
}FE(CO)
2
(CH
2
CN)] (PA-CP-12) 328
6.5.69 K[{C
5
(NME
2
)
5
}FE(CO)2] (PA-CP-16) 329
6.5.70 [{C
5
(NME
2
)5}FE(CO)2]2 (PA-CP-17) 329
6.5.71 [{C
5
(NME
2
)
5
}FE(CO)2H] (PA-CP-18) 330
6.5.72 [{C
5
(NME
2
)
5
}FE(CO)
2
CL] (PA-CP-19) 330
6.5.73 [ {C
5
(NME
2
)
5
}
2
FENI(CO)3] (PA-CP-20) 331
6.5.74 [{C
5
(NME
2
)
5
H}PT(CO)CL][NME
2
H
2
][FECL
4
] (PA-CP-21) 331
6.5.75 [FECP{C
5
(NME
2
)
5
}] (PA-CP-22) 332
6.5.76 [FECP{C
5
(NET
2
)
4
PH}] (PA-CP-24) 332
6.5.77 [RU{C
2
(NET
2
)
2
}(CO)
2
(PPH
3
)] (RU-3) 333
6.6 SYNTHESES OF IMPORTANT STARTING MATERIALS 334
6.6.1 ET
2
N(CL)C=CHCL (SI) 334
6.6.2 (ET
2
N)2C=C(CL)H (S2) 334
6.6.3 ET
2
N-OC-NET
2
(S3) 335
6.6.4 PR
2
N(CL)C=CHCL (S4) 335
6.6.5 ( PR
2
N)
2
C=CHCL (S6) 337
6.6.6 P^N-C^C-N P^ (S7) 338
6.6.7 KP(SIME
3
)
2
.0.5DME (S8) 339
6.6.8 (SIME
3
)P=C(OSIME
3
) BU (S9) 339
6.6.9 BU-C=P (S10) 340
6.6.10 ET
2
P-C=C-PET
2
(SLL) 341
6.6.11 C
3
HC1
5
(S12) 342
6.6.12 C
3
CU (S13) 343
6.6.13 [C
3
(NME
2
)
3
]CL (S14) 343
7. REFERENCES 345
8. APPENDICES 357
8.1 LIST OF ABBREVIATIONS 357
8.2 LIST OF COMPOUNDS 359
8.3 CRYSTAL DATA AND STRUCTURE REFINEMENT 363
8.3.1. [FE(C0)
3
{K
2
-C
2
(NET
2
)
2
C(0)}] (1) 363
4
8.3.2. [FE(C0)
3
{C(NME)C(NME)C
2
(NNET
2
)
2
C(0)}] (3) 363
8.3.3. [FE(CO)
3
{C
3
(NET2)3}]BF4 (FCB-ET-4) 363
8.3.4. [FE(CO)
2
(MECN){C
3
(NET
2
)
3
}]BF
4
(FCB-ET-5) 364
8.3.5. [FE(CO)
2
(NC
5
H
5
){C
3
(NET
2
)
3
}]BF
4
(FCB-ET-6) 364
8.3.6. [FE(CO)
2
(PME
3
){C
3
(NET
2
)
3
}]BF
4
(FCB-ET-7) 365
8.3.7. [FE(CO)
2
(PCY
3
){C
3
(NET2)
3
}]BF
4
(FCB-ET-8) 365
8.3.8. [FE(CO)
2
(PPH
3
){C
3
(NET2)
3
}]BF4 (FCB-ET-9) 366
8.3.9. [FE(CO)
2
(MENC){C
3
(NET
2
)
3
}]PF
6
(FCB-ET-10) 366
8.3.10. [FE(CO)2(CN BU)
{C
3
(NET
2
)
3
}
]BF
4
(FCB-ET-11) 367
8.3.11. [FE(CO)2(IM-ME4){C
3
(NET2)
3
}]BF
4
(FCB-ET-12) 367
8.3.12. [FE(CO)(PME
3
)
2
{C
3
(NET2)
3
}]PF
6
(FCB-ET-13) 368
8.3.13. [FE(CO)(IM-ME
4
)2{C
3
(NET2)
3
}]BF
4
(FCB-ET-14) 368
8.3.14. [FE(CO)
2
(CL){C
3
(NET
2
)
3
}] (FCB-ET-LS) 369
8.3.15. [FE(CO)2(N
3
){C
3
(NET
2
)
3
}] (FCB-ET-16) 369
8.3.16. [FE(CO)
2
(NC
4
H
4
){C
3
(NET
2
)
3
}] (FCB-ET-17) 370
8.3.17. [FE(CO)
2
(SNME
3
){C
3
(NET
2
)
3
}] (FCB-ET-19) 370
8.3.18. [FE(CO)
2
(CH
3
CO){C
3
(NET
2
)
3
}] (FCB-ET-20) 371
8.3.19. [FE(CO)
2
( BUCO){C
3
(NET2)
3
}] (FCB-ET-21) 371
8.3.20. [FE(CO)
2
(CH
2
CN){C
3
(NET2
3
}] (FCB-ET-22) 371
8.3.21. [FE(CO)2(GECL
2
AI
MTS
){C
3
CNET2)
3
}] (FCB-ET-23) 372
8.3.22. [FE(CO)
2
(PME
3
)2
{C
3
(NET
2
)
3
}
]BF
4
(FCB-ET-24) 372
8.3.23. [FE(CO)(PME
3
)I
2
{C
3
(NET2)
3
}]X (FCB-ET-25) 373
8.3.24. [FE(CO)(CNME)I
2
{C
3
(NET
2
)
3
}]BF
4
(FCB-ET-27) 373
8.3.25. [FE(CNME)
2
L2{C
3
(NET2)
3
}]BF
4
(FCB-ET-29) 374
8.3.26. HG[FE(CO)
3
{C
3
(NET
2
)
3
}]
2
(FCB-ET-30) 374
8.3.27. HG[FE(CO)
2
{C
3
(NET2)
3
}]2
(FCB-ET-31) 375
8.3.28. [FE(CO)
2
(C
3
H
5
CO){C
3
(NET
2
)
3
}] (FCB-ET-32) 375
8.3.29. [FE(CO)2(PME
3
){C
3
(NET2)
3
}] (FCB-ET-34) 376
8.3.30. [FE(CO)
2
(IM-ME
4
){C
3
(NET
2
)
3
}] (FCB-ET-35) 376
8.3.31. [FE(CO)(PME
3
)
2
{C
3
(NET
2
)
3
}] (FCB-ET-36) 377
8.3.32. [FE(CO)
2
(SNME
3
){C
3
(NME
2
)
3
}] (FCB-ME-8) 377
8.3.33. [FE(CO)
2
(CH
3
CO){C
3
(NME2)
3
}] (FCB-ME-9) 378
8.3.34. HG[FE(CO)
3
{C
3
(NME
2
)
3
}]2 (FCB-ME-11) 378
8.3.35. [FE(CO)
2
{TI
4
-C
3
(NET
2
)
3
ME}] (AC-1) 379
8.3.36. [FE(CO)
3
{TI
3
-C
3
(NME
2
)
3
H}] (AC-3) 379
8.3.37. [FE(CO)
3
{CIS-T|
3
-C
3
(NET2)
3
(NC
4
H
4
)}] (AC-4) 380
8.3.38. [FE(CO)
3
{TRANS-T|
3
-C
3
(NET
2
)
3
(NC
4
H
4
)}] (AC-5) 380
8.3.39. [FE(CO)2(PME
3
){N
3
-C
3
(NET
2
)
3
H}] (AC-7) 381
8.3.40. [FE(CO)
3
{K
2
-C(NME2)CH(NME
2
)C(NME2)}] (AC-8) 381
8.3.41. [FE(CO)
3
{N
3
-C
3
(NET
2
)
3
(AUPPH
3
)}] (AC-9) 381
8.3.42. [FE(CO)
3
{R|
3
-C
3
(NME
2
)
3
ME}] (AC-11) 382
8.3.43. [{C5(NME2)5}FE(CO)2( BUNC)]BF4 (PA-CP-3) 382
8.3.44. [{C
5
(NME2)3(NET2)2}FE(CO)2(PME
3
)]BF
4
(PA-CP-6) 383
8.3.45. [{C
5
(NME
2
)5}FE(CO)2(SNME
3
)] (PA-CP-7) 383
8.3.46. [{C
5
(NME
2
)
3
(NET
2
)2}FE(CO)2(SNME
3
)] (PA-CP-8) 384
8.3.47. [{C5(NET
2
)
3
(NME
2
)2}FE(CO)2(CH
2
CN)] (PA-CP-10) 384
8.3.48. [{C
5
(NET
2
)
3
(NME2)2}FE(CO)(CH2CN)]2 (PA-CP-11) 385
8.3.49. [{C
5
(NME2)4PH}FE(CO)
3
]BF
4
(PA-CP-14) 385
8.3.50. [{C
5
(NET
2
)
3
(NME2)PH}FE(CO)2(PET
3
)]BARF2
4
(PA-CP-15) 386
8.3.51. [{C
5
(NME2)5}FE(CO)
2
]2 (PA-CP-17) 386
8.3.52. [{C
5
(NME
2
)5}FE(CO)
2
(H)] (PA-CP
-18)
387
5
8.3.53. [{C
5
(NME
2
)5}FE(CO)2(CL)] (PA-CP-19) 387
8.3.54. [{C
5
(NME
2
)
5
}
2
FENI(CO)3] (PA-CP-20) 388
8.3.55. [{N
1
-C
5
(NME
2
)5H}PT(CO)(CL)][FECL4,NH2ME
2
] (PA-CP-21) 388
8.3.56. FE{C
5
(NME
2
)
5
}
2
(PA-CP-22) 389
8.3.57. [FE{C
5
(NME
2
)
5
}2][CUCL
2
] (PA-CP-23) 389
8.3.58. [{C
5
(NME
2
)
3
(NET
2
)
2
ME}FE(CO
)2]2
390
8.3.59. [{{C
5
(NME
2
)
5
}FE(CO)2}2CL]BARF24 390
8.3.60. [((ME2N)
2
C)HC=CH(C(NME
2
)
2
)]2I (26) 391
8.3.61.
[{K
4
-C
6
(NET
2
)6}FE
2
(CO
)S]
(38) 391
8.3.62. [{N
2
,RI
3
-C3(NET2)2}FE2(CO)] (39) 391
8.3.63. [{AR
TNP
GEC
3
(NME2)
3
}FE(CO)
4
] (43) 392
8.3.64. [{AR
MES
SNC
3
(NET
2
)
3
}FE(CO)
3
{SN^-OH^AR^] (44) 392
8.3.65. [FE(CO)
3
{C
3
(NET
2
)
3
N}] (45) 393
8.3.66. [FE(CO)
3
{C
3
(NME
2
)
3
N}] (46) 393
8.3.67. [FE(CO)
3
{C
8
H
5
(NET2)
3
}] (47) 394
8.3.68. [FE(CO)
3
{C
8
H
5
(NME
2
)
3
}] (48) 394
8.3.69. [FE(CO)2(PME
3
){C
8
H5(NET
2
)
3
}] (49) 395
8.3.70. [FE(C0)2(PME
3
)2
{K
2
-C(NET2)C{C(NET2)(C
5
H4)}C(0)}] (50) 395
8.3.71. [FE(CO
)
2
{K
4
-C
5
(NET2)
4
PH}]BARF24 (56) 396
8.3.72. [FE(CO)
2
{K
4
-C
5
(NET2)
3
(NME
2
)PH}]BARF
24
(57) 396
8.3.73. FE
2
(CO)4
(K
2
-ET
2
PC=CPET2){C
3
(NET2)
3
}2][BARF24]2 (58) 397
8.3.74. [RU(CO)2(PPH
3
)(TI
2
-ET2NOCNET
2
)] (RU-3) 397
8.4 OATH OF COMPLIANCE WITH THE PRINCIPLES OF SCIENTIFIC INTEGRITY 399
8.5 SCIENTIFIC CONTRIBUTIONS 400
8.6 CURRICULUMVITAE 402
|
| any_adam_object | 1 |
| author | Das, Ujjal 1984- |
| author_GND | (DE-588)1064965180 |
| author_facet | Das, Ujjal 1984- |
| author_role | aut |
| author_sort | Das, Ujjal 1984- |
| author_variant | u d ud |
| building | Verbundindex |
| bvnumber | BV042375919 |
| ctrlnum | (OCoLC)904025769 (DE-599)BVBBV042375919 |
| dewey-full | 547.05621 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.05621 |
| dewey-search | 547.05621 |
| dewey-sort | 3547.05621 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV042375919 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T01:19:53Z |
| institution | BVB |
| isbn | 9783863875510 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027812095 |
| oclc_num | 904025769 |
| open_access_boolean | |
| owner | DE-29T |
| owner_facet | DE-29T |
| physical | III, 403 S. graph. Darst. 21 cm |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | mbv, Mensch-und-Buch-Verl. |
| record_format | marc |
| spelling | Das, Ujjal 1984- Verfasser (DE-588)1064965180 aut Closed-shell and open-shell ferracyclobutadienes-syntheses, characterization and reactivity studies Ujjal Das Berlin mbv, Mensch-und-Buch-Verl. 2014 III, 403 S. graph. Darst. 21 cm txt rdacontent n rdamedia nc rdacarrier Zugl.: Bonn, Univ., Diss., 2014 Cyclobutadienderivate (DE-588)4148500-2 gnd rswk-swf Strukturaufklärung (DE-588)4183788-5 gnd rswk-swf Chemische Synthese (DE-588)4133806-6 gnd rswk-swf Reaktivität (DE-588)4208182-8 gnd rswk-swf Eisenorganische Verbindungen (DE-588)4151587-0 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Eisenorganische Verbindungen (DE-588)4151587-0 s Cyclobutadienderivate (DE-588)4148500-2 s Chemische Synthese (DE-588)4133806-6 s Strukturaufklärung (DE-588)4183788-5 s Reaktivität (DE-588)4208182-8 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027812095&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Das, Ujjal 1984- Closed-shell and open-shell ferracyclobutadienes-syntheses, characterization and reactivity studies Cyclobutadienderivate (DE-588)4148500-2 gnd Strukturaufklärung (DE-588)4183788-5 gnd Chemische Synthese (DE-588)4133806-6 gnd Reaktivität (DE-588)4208182-8 gnd Eisenorganische Verbindungen (DE-588)4151587-0 gnd |
| subject_GND | (DE-588)4148500-2 (DE-588)4183788-5 (DE-588)4133806-6 (DE-588)4208182-8 (DE-588)4151587-0 (DE-588)4113937-9 |
| title | Closed-shell and open-shell ferracyclobutadienes-syntheses, characterization and reactivity studies |
| title_auth | Closed-shell and open-shell ferracyclobutadienes-syntheses, characterization and reactivity studies |
| title_exact_search | Closed-shell and open-shell ferracyclobutadienes-syntheses, characterization and reactivity studies |
| title_full | Closed-shell and open-shell ferracyclobutadienes-syntheses, characterization and reactivity studies Ujjal Das |
| title_fullStr | Closed-shell and open-shell ferracyclobutadienes-syntheses, characterization and reactivity studies Ujjal Das |
| title_full_unstemmed | Closed-shell and open-shell ferracyclobutadienes-syntheses, characterization and reactivity studies Ujjal Das |
| title_short | Closed-shell and open-shell ferracyclobutadienes-syntheses, characterization and reactivity studies |
| title_sort | closed shell and open shell ferracyclobutadienes syntheses characterization and reactivity studies |
| topic | Cyclobutadienderivate (DE-588)4148500-2 gnd Strukturaufklärung (DE-588)4183788-5 gnd Chemische Synthese (DE-588)4133806-6 gnd Reaktivität (DE-588)4208182-8 gnd Eisenorganische Verbindungen (DE-588)4151587-0 gnd |
| topic_facet | Cyclobutadienderivate Strukturaufklärung Chemische Synthese Reaktivität Eisenorganische Verbindungen Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027812095&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT dasujjal closedshellandopenshellferracyclobutadienessynthesescharacterizationandreactivitystudies |