NOx related chemistry:
Gespeichert in:
Weitere Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Amsterdam ; Heidelberg [u.a.]
Elsevier Acad. Press
2015
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Ausgabe: | 1. ed. |
Schriftenreihe: | Advances in inorganic chemistry
67 |
Schlagworte: | |
Online-Zugang: | Inhaltsverzeichnis |
Beschreibung: | XII, 375 S. Ill., graph. Darst. 23 cm |
ISBN: | 9780128017357 012801735X |
Internformat
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Datensatz im Suchindex
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adam_text | Titel: NOx related chemistry
Autor: Eldik, Rudi van
Jahr: 2015
CONTENTS Contributors ix Preface xi 1. NO x Linkage Isomerization in Metal Complexes 1 Dennis Awasabisah and George B. Richter-Addo 1 . Introduction 2 2. Linkage Isomerism in Non-Porphyrin NO* Complexes 7 3. Linkage Isomerism in NO*-Coordinated Metalloporphyrins 28 4 . Conclusion 78 Acknowledgment 78 References 78 2. Three Redox States of Metallonitrosyls in Aqueous Solution 87 Sara E. Bari, José A. Olabe, and Leonardo D. Slep 1 . Introduction: General Scope 88 2. Complexes with n = 6 89 3. Complexes with n = 7 108 4 . Complexes with n = 8 123 5. Conclusions 136 References 137 3. Recent Progress in Photoinduced NO Delivery With Designed Ruthenium Nitrosyl Complexes 145 Tara R. deBoer and Pradip K. Mascharak 1 . Introduction 145 2. Photoactive Ru Nitrosyls: What We Knew Before Our Work 150 3. Photoactive {RuNO} 6 Nitrosyls Derived from Pentadentate Polypyridine Ligands 152 4 . Tuning the Photosensitivity of Ru Nitrosyls to Light of Longer Wavelengths 155 5. Incorporation of Ru Nitrosyls Into Polymeric Matrices 159 6. Enhancement of Light Absorption of {Ru-NO} 6 Nitrosyls Through Direct Attachment of Dyes 160 7 . Conclusion . 167 Acknowledgments 168 References 168 v
VI Contents 4. Metal-Assisted Activation of Nitric Oxide—Mechanistic Aspects of Complex Nitrosylation Processes 171 Alicja Franke, Maria Oszajca, Ma?gorzata Brindell, Gra?yna Stochel, and Rudi van Eldik 1 . Introduction 172 2. Nitric Oxide Activation by lron(ll)/(lll) Centers 173 3. Nitric Oxide Activation by Ruthenium(lll) Centers 212 4 . Reductive Nitrosylation Reactions 224 5. Concluding Remarks 235 Acknowledgments 235 References 236 5. New Insights on {FeNO} (n = 7, 8) Systems as Enzyme Models and HNO Donors 243 Todd C. Harrop 1. Background 244 2. {FeNO} 7 Complexes as Models for Nonheme Oxygenase Enzymes 245 3. {FeNO} 7 Complexes as Precursors to {FeNO} 8 Complexes 251 4 . Dllron Complexes Containing {FeNO} 7 Unit(s) 257 5. Summary and Outlook 260 References 262 6. Design, Reactivity, and Biological Activity of Ruthenium Nitrosyl Complexes 265 Roberto Santana da Silva, Renata Galvao de Lima, and Sergio de Paula Machado 1. Introduction 266 2. Tetraaza Ruthenium Complexes 268 3. Polypyridine Ruthenium Complexes as NO Delivery Systems 269 4 . UV-Vis Electronic Spectrum 272 5. Electrochemistry 275 6. FTIR 277 7 . Photochemical Reactivity 279 8. Vasorelaxation 282 9. Cytotoxicity 287 10 . Neglected Tropical Diseases 289 11. Trlnuclear Oxo-Centered Ruthenium Carboxylates 290 References 292
Contents VH 7. Complete and Partial Electron Transfer Involving Coordinated NO* 295 Wolfgang Kaim 1. Introduction and Presentation of NO Oxidation States 295 2. Nitrosylmetal Complexes Without Additional Redox-Active Ligands 299 3 . Nitrosylmetal Complexes with Additional Redox-Active Ligands 300 4. Noninnocent Ligand Potential of the N0 2 ~/N0 2 ‘ Redox System 308 5. Conclusions 309 Acknowledgments 310 References 311 8. Oxidation Mechanism of Hydroxamic Acids Forming HNO and NO: Implications for Biological Activity 315 Sara Goldstein and Amram Samuni 1. Introduction 316 2. HXs Oxidation In Vitro and In Vivo 317 3 . Conclusions 330 Acknowledgment 331 References 331 9. Reaction Steps in Nitrogen Monoxide Autoxidation 335 Reinhard Kissner 1. History 335 2. Gas-Phase Reaction and Atmospheric Chemistry 337 3 . Liquid-Phase Reaction and Biology 338 4. Thermochemistry and Kinetics 339 5. Mechanisms 341 6. Conclusions 352 Acknowledgments 352 References 353 Index 355 Contents of Previous Volumes 365
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id | DE-604.BV042328117 |
illustrated | Illustrated |
indexdate | 2024-07-10T01:18:33Z |
institution | BVB |
isbn | 9780128017357 012801735X |
language | English |
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physical | XII, 375 S. Ill., graph. Darst. 23 cm |
publishDate | 2015 |
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publisher | Elsevier Acad. Press |
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series | Advances in inorganic chemistry |
series2 | Advances in inorganic chemistry |
spelling | NOx related chemistry ed. by Rudi van Eldik ... 1. ed. Amsterdam ; Heidelberg [u.a.] Elsevier Acad. Press 2015 XII, 375 S. Ill., graph. Darst. 23 cm txt rdacontent n rdamedia nc rdacarrier Advances in inorganic chemistry 67 Chemistry, Inorganic Atmospheric chemistry Anorganische Chemie (DE-588)4002145-2 gnd rswk-swf Anorganische Chemie (DE-588)4002145-2 s DE-604 Eldik, Rudi van 1945- (DE-588)124564194 edt Advances in inorganic chemistry 67 (DE-604)BV005678699 67 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027764926&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
spellingShingle | NOx related chemistry Advances in inorganic chemistry Chemistry, Inorganic Atmospheric chemistry Anorganische Chemie (DE-588)4002145-2 gnd |
subject_GND | (DE-588)4002145-2 |
title | NOx related chemistry |
title_auth | NOx related chemistry |
title_exact_search | NOx related chemistry |
title_full | NOx related chemistry ed. by Rudi van Eldik ... |
title_fullStr | NOx related chemistry ed. by Rudi van Eldik ... |
title_full_unstemmed | NOx related chemistry ed. by Rudi van Eldik ... |
title_short | NOx related chemistry |
title_sort | nox related chemistry |
topic | Chemistry, Inorganic Atmospheric chemistry Anorganische Chemie (DE-588)4002145-2 gnd |
topic_facet | Chemistry, Inorganic Atmospheric chemistry Anorganische Chemie |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027764926&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
volume_link | (DE-604)BV005678699 |
work_keys_str_mv | AT eldikrudivan noxrelatedchemistry |