Modern aspects of diffusion-controlled reactions: cooperative phenomena in bimolecular processes
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam
Elsevier
1996
|
| Schriftenreihe: | Comprehensive chemical kinetics
v. 34 |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Beschreibung: | Includes bibliographical references and indexes This monograph deals with the effects of reactant spatial correlations arising in the course of basic bimolecular reactions describing defect recombination, energy transfer and exciton annihilation in condensed matter. These effects lead to the kinetics considered <IT>abnormal</IT> from the standard chemical kinetics point of view. Numerous bimolecular reaction regimes and conditions are analysed in detail. Special attention is paid to the development and numerous applications of a novel, many-point density (MPD) formalism, which is based on Kirkwood's superposition approximation used for decoupling three-particle correlation functions. The book demonstrates that incorporation of the reaction-induced spatial correlations of <IT>similar</IT> reactants (e.g., vacancy-vacancy) leads to the development of an essentially non-Poisson spectrum of reactant density fluctuations. This can completely change the kinetics at longer times since it no longer obeys the law of mass action. The language of the <IT>correlation lengths</IT> and <IT>critical exponents</IT> similar to physics of critical phenomena is used instead. A relation between MPD theory and synergistics is discussed. The validity of the theorem giving a critical complexity for the two-step reactions exhibiting self-organization phenomena is questioned. Theoretical results are illustrated by numerous experimental data |
| Beschreibung: | 1 Online-Ressource (xxiii, 612 p.) |
| ISBN: | 9780444824721 0444824723 |
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| 246 | 1 | 3 | |a Cooperative phenomena in bimolecular processes |
| 264 | 1 | |a Amsterdam |b Elsevier |c 1996 | |
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| 500 | |a This monograph deals with the effects of reactant spatial correlations arising in the course of basic bimolecular reactions describing defect recombination, energy transfer and exciton annihilation in condensed matter. These effects lead to the kinetics considered <IT>abnormal</IT> from the standard chemical kinetics point of view. Numerous bimolecular reaction regimes and conditions are analysed in detail. Special attention is paid to the development and numerous applications of a novel, many-point density (MPD) formalism, which is based on Kirkwood's superposition approximation used for decoupling three-particle correlation functions. The book demonstrates that incorporation of the reaction-induced spatial correlations of <IT>similar</IT> reactants (e.g., vacancy-vacancy) leads to the development of an essentially non-Poisson spectrum of reactant density fluctuations. This can completely change the kinetics at longer times since it no longer obeys the law of mass action. The language of the <IT>correlation lengths</IT> and <IT>critical exponents</IT> similar to physics of critical phenomena is used instead. A relation between MPD theory and synergistics is discussed. The validity of the theorem giving a critical complexity for the two-step reactions exhibiting self-organization phenomena is questioned. Theoretical results are illustrated by numerous experimental data | ||
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| author | Kotomin, E. A., (Evgeniĭ Alekseevich) |
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| dewey-full | 541.3/94 547/.704594 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry 547 - Organic chemistry |
| dewey-raw | 541.3/94 547/.704594 |
| dewey-search | 541.3/94 547/.704594 |
| dewey-sort | 3541.3 294 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Electronic eBook |
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| isbn | 9780444824721 0444824723 |
| language | English |
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| spelling | Kotomin, E. A., (Evgeniĭ Alekseevich) Verfasser aut Modern aspects of diffusion-controlled reactions cooperative phenomena in bimolecular processes E. Kotomin, V. Kuzovkov Cooperative phenomena in bimolecular processes Amsterdam Elsevier 1996 1 Online-Ressource (xxiii, 612 p.) txt rdacontent c rdamedia cr rdacarrier Comprehensive chemical kinetics v. 34 Includes bibliographical references and indexes This monograph deals with the effects of reactant spatial correlations arising in the course of basic bimolecular reactions describing defect recombination, energy transfer and exciton annihilation in condensed matter. These effects lead to the kinetics considered <IT>abnormal</IT> from the standard chemical kinetics point of view. Numerous bimolecular reaction regimes and conditions are analysed in detail. Special attention is paid to the development and numerous applications of a novel, many-point density (MPD) formalism, which is based on Kirkwood's superposition approximation used for decoupling three-particle correlation functions. The book demonstrates that incorporation of the reaction-induced spatial correlations of <IT>similar</IT> reactants (e.g., vacancy-vacancy) leads to the development of an essentially non-Poisson spectrum of reactant density fluctuations. This can completely change the kinetics at longer times since it no longer obeys the law of mass action. The language of the <IT>correlation lengths</IT> and <IT>critical exponents</IT> similar to physics of critical phenomena is used instead. A relation between MPD theory and synergistics is discussed. The validity of the theorem giving a critical complexity for the two-step reactions exhibiting self-organization phenomena is questioned. Theoretical results are illustrated by numerous experimental data Chemical kinetics fast Diffusion fast Diffusion Chemical kinetics Kondensierte Materie (DE-588)4132810-3 gnd rswk-swf Selbstorganisation (DE-588)4126830-1 gnd rswk-swf Reaktionskinetik (DE-588)4048655-2 gnd rswk-swf Kondensierte Materie (DE-588)4132810-3 s Reaktionskinetik (DE-588)4048655-2 s Selbstorganisation (DE-588)4126830-1 s 1\p DE-604 Kuzovkov, V. N. Sonstige oth http://www.sciencedirect.com/science/book/9780444824721 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Kotomin, E. A., (Evgeniĭ Alekseevich) Modern aspects of diffusion-controlled reactions cooperative phenomena in bimolecular processes Chemical kinetics fast Diffusion fast Diffusion Chemical kinetics Kondensierte Materie (DE-588)4132810-3 gnd Selbstorganisation (DE-588)4126830-1 gnd Reaktionskinetik (DE-588)4048655-2 gnd |
| subject_GND | (DE-588)4132810-3 (DE-588)4126830-1 (DE-588)4048655-2 |
| title | Modern aspects of diffusion-controlled reactions cooperative phenomena in bimolecular processes |
| title_alt | Cooperative phenomena in bimolecular processes |
| title_auth | Modern aspects of diffusion-controlled reactions cooperative phenomena in bimolecular processes |
| title_exact_search | Modern aspects of diffusion-controlled reactions cooperative phenomena in bimolecular processes |
| title_full | Modern aspects of diffusion-controlled reactions cooperative phenomena in bimolecular processes E. Kotomin, V. Kuzovkov |
| title_fullStr | Modern aspects of diffusion-controlled reactions cooperative phenomena in bimolecular processes E. Kotomin, V. Kuzovkov |
| title_full_unstemmed | Modern aspects of diffusion-controlled reactions cooperative phenomena in bimolecular processes E. Kotomin, V. Kuzovkov |
| title_short | Modern aspects of diffusion-controlled reactions |
| title_sort | modern aspects of diffusion controlled reactions cooperative phenomena in bimolecular processes |
| title_sub | cooperative phenomena in bimolecular processes |
| topic | Chemical kinetics fast Diffusion fast Diffusion Chemical kinetics Kondensierte Materie (DE-588)4132810-3 gnd Selbstorganisation (DE-588)4126830-1 gnd Reaktionskinetik (DE-588)4048655-2 gnd |
| topic_facet | Chemical kinetics Diffusion Kondensierte Materie Selbstorganisation Reaktionskinetik |
| url | http://www.sciencedirect.com/science/book/9780444824721 |
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