Organomagnesium methods in organic synthesis:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
London
Academic Press
1995
|
| Schriftenreihe: | Best synthetic methods
|
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Beschreibung: | The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized. The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as hydromagnesiation of alkenes and alkynes. Systematic coverage is provided on synthetically useful reactions of organomagnesium compounds. Of fundamental importance in organic synthesis are carbon-carbon bond forming reactions; additions to carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur multiple bonds; and nucleophilic substitution at carbon. The formation of carbon-heteroatom bonds in organic compounds is described, where the heteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally, the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds is outlined. Representative experimental procedures are included throughout the book, and tables with references to well-described examples are provided. Key Features * Presents a general overview of the constitution and reactivity of organomagnesium compounds * Provides coverage on the detection and estimation of organomagnesium compounds * Emphasizes practical aspects as well as principles * Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes * Includes preparations by metallation and metal-halogen exchanges * Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes * Outlines information on synthetically useful reactions of organomagnesium compounds * Describes the formation of carbon-heteroatom bonds in organic compounds * Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds * Includes representative procedures and tables with references to well-described examples Includes bibliographical references and index |
| Beschreibung: | 1 Online-Ressource (xvi, 249 pages) |
| ISBN: | 9780127309453 0127309454 9780080538174 0080538177 |
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| 245 | 1 | 0 | |a Organomagnesium methods in organic synthesis |c Basil J. Wakefield |
| 264 | 1 | |a London |b Academic Press |c 1995 | |
| 300 | |a 1 Online-Ressource (xvi, 249 pages) | ||
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| 490 | 0 | |a Best synthetic methods | |
| 500 | |a The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized. The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as hydromagnesiation of alkenes and alkynes. Systematic coverage is provided on synthetically useful reactions of organomagnesium compounds. Of fundamental importance in organic synthesis are carbon-carbon bond forming reactions; additions to carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur multiple bonds; and nucleophilic substitution at carbon. | ||
| 500 | |a The formation of carbon-heteroatom bonds in organic compounds is described, where the heteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally, the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds is outlined. Representative experimental procedures are included throughout the book, and tables with references to well-described examples are provided. | ||
| 500 | |a Key Features * Presents a general overview of the constitution and reactivity of organomagnesium compounds * Provides coverage on the detection and estimation of organomagnesium compounds * Emphasizes practical aspects as well as principles * Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes * Includes preparations by metallation and metal-halogen exchanges * Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes * Outlines information on synthetically useful reactions of organomagnesium compounds * Describes the formation of carbon-heteroatom bonds in organic compounds * Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds * Includes representative procedures and tables with references to well-described examples | ||
| 500 | |a Includes bibliographical references and index | ||
| 650 | 4 | |a Organic compounds / Synthesis | |
| 650 | 7 | |a SCIENCE / Chemistry / Organic |2 bisacsh | |
| 650 | 7 | |a Organic compounds / Synthesis |2 fast | |
| 650 | 7 | |a Organomagnesium compounds |2 fast | |
| 650 | 7 | |a Organometaalverbindingen |2 gtt | |
| 650 | 7 | |a Magnesium |2 gtt | |
| 650 | 7 | |a Sintese organica (quimica) |2 larpcal | |
| 650 | 7 | |a Compostos organometalicos (quimica organica) |2 larpcal | |
| 650 | 7 | |a Magnesiumorganische Verbindungen |2 swd | |
| 650 | 7 | |a Organische Synthese |2 swd | |
| 650 | 4 | |a Chemie | |
| 650 | 4 | |a Organomagnesium compounds | |
| 650 | 4 | |a Organic compounds |x Synthesis | |
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Datensatz im Suchindex
| _version_ | 1804152906181509120 |
|---|---|
| any_adam_object | |
| author | Wakefield, Basil J. 1934- |
| author_GND | (DE-588)172440246 |
| author_facet | Wakefield, Basil J. 1934- |
| author_role | aut |
| author_sort | Wakefield, Basil J. 1934- |
| author_variant | b j w bj bjw |
| building | Verbundindex |
| bvnumber | BV042313750 |
| collection | ZDB-33-ESD ZDB-33-EBS |
| ctrlnum | (OCoLC)162129128 (DE-599)BVBBV042313750 |
| dewey-full | 547.05392 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.05392 |
| dewey-search | 547.05392 |
| dewey-sort | 3547.05392 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Electronic eBook |
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| id | DE-604.BV042313750 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T01:18:09Z |
| institution | BVB |
| isbn | 9780127309453 0127309454 9780080538174 0080538177 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027750741 |
| oclc_num | 162129128 |
| open_access_boolean | |
| owner | DE-1046 |
| owner_facet | DE-1046 |
| physical | 1 Online-Ressource (xvi, 249 pages) |
| psigel | ZDB-33-ESD ZDB-33-EBS FAW_PDA_ESD FLA_PDA_ESD |
| publishDate | 1995 |
| publishDateSearch | 1995 |
| publishDateSort | 1995 |
| publisher | Academic Press |
| record_format | marc |
| series2 | Best synthetic methods |
| spelling | Wakefield, Basil J. 1934- Verfasser (DE-588)172440246 aut Organomagnesium methods in organic synthesis Basil J. Wakefield London Academic Press 1995 1 Online-Ressource (xvi, 249 pages) txt rdacontent c rdamedia cr rdacarrier Best synthetic methods The book opens with a general overview of the constitution and reactivity of organomagnesium compounds, followed by information on handling them and on their detection and estimation. Throughout, practical aspects aswell as principles are emphasized. The chapters on the synthesis of organomagnesium compounds cover the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes, as well as the traditional preparation of Grignard reagents. Preparations by metallation and metal-halogen exchanges are also included, as are newer methods such as hydromagnesiation of alkenes and alkynes. Systematic coverage is provided on synthetically useful reactions of organomagnesium compounds. Of fundamental importance in organic synthesis are carbon-carbon bond forming reactions; additions to carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur multiple bonds; and nucleophilic substitution at carbon. The formation of carbon-heteroatom bonds in organic compounds is described, where the heteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally, the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds is outlined. Representative experimental procedures are included throughout the book, and tables with references to well-described examples are provided. Key Features * Presents a general overview of the constitution and reactivity of organomagnesium compounds * Provides coverage on the detection and estimation of organomagnesium compounds * Emphasizes practical aspects as well as principles * Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes * Includes preparations by metallation and metal-halogen exchanges * Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes * Outlines information on synthetically useful reactions of organomagnesium compounds * Describes the formation of carbon-heteroatom bonds in organic compounds * Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds * Includes representative procedures and tables with references to well-described examples Includes bibliographical references and index Organic compounds / Synthesis SCIENCE / Chemistry / Organic bisacsh Organic compounds / Synthesis fast Organomagnesium compounds fast Organometaalverbindingen gtt Magnesium gtt Sintese organica (quimica) larpcal Compostos organometalicos (quimica organica) larpcal Magnesiumorganische Verbindungen swd Organische Synthese swd Chemie Organomagnesium compounds Organic compounds Synthesis Organische Synthese (DE-588)4075695-6 gnd rswk-swf Magnesiumorganische Verbindungen (DE-588)4168537-4 gnd rswk-swf Magnesiumorganische Verbindungen (DE-588)4168537-4 s Organische Synthese (DE-588)4075695-6 s 1\p DE-604 http://www.sciencedirect.com/science/book/9780127309453 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Wakefield, Basil J. 1934- Organomagnesium methods in organic synthesis Organic compounds / Synthesis SCIENCE / Chemistry / Organic bisacsh Organic compounds / Synthesis fast Organomagnesium compounds fast Organometaalverbindingen gtt Magnesium gtt Sintese organica (quimica) larpcal Compostos organometalicos (quimica organica) larpcal Magnesiumorganische Verbindungen swd Organische Synthese swd Chemie Organomagnesium compounds Organic compounds Synthesis Organische Synthese (DE-588)4075695-6 gnd Magnesiumorganische Verbindungen (DE-588)4168537-4 gnd |
| subject_GND | (DE-588)4075695-6 (DE-588)4168537-4 |
| title | Organomagnesium methods in organic synthesis |
| title_auth | Organomagnesium methods in organic synthesis |
| title_exact_search | Organomagnesium methods in organic synthesis |
| title_full | Organomagnesium methods in organic synthesis Basil J. Wakefield |
| title_fullStr | Organomagnesium methods in organic synthesis Basil J. Wakefield |
| title_full_unstemmed | Organomagnesium methods in organic synthesis Basil J. Wakefield |
| title_short | Organomagnesium methods in organic synthesis |
| title_sort | organomagnesium methods in organic synthesis |
| topic | Organic compounds / Synthesis SCIENCE / Chemistry / Organic bisacsh Organic compounds / Synthesis fast Organomagnesium compounds fast Organometaalverbindingen gtt Magnesium gtt Sintese organica (quimica) larpcal Compostos organometalicos (quimica organica) larpcal Magnesiumorganische Verbindungen swd Organische Synthese swd Chemie Organomagnesium compounds Organic compounds Synthesis Organische Synthese (DE-588)4075695-6 gnd Magnesiumorganische Verbindungen (DE-588)4168537-4 gnd |
| topic_facet | Organic compounds / Synthesis SCIENCE / Chemistry / Organic Organomagnesium compounds Organometaalverbindingen Magnesium Sintese organica (quimica) Compostos organometalicos (quimica organica) Magnesiumorganische Verbindungen Organische Synthese Chemie Organic compounds Synthesis |
| url | http://www.sciencedirect.com/science/book/9780127309453 |
| work_keys_str_mv | AT wakefieldbasilj organomagnesiummethodsinorganicsynthesis |