Inorganic polymeric glasses:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam
Elsevier
1992
|
| Schriftenreihe: | Studies in inorganic chemistry
15 |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Beschreibung: | Includes bibliographical references and index The author describes a novel method of preparing hydrolysis-stable non-silicate glasses which is based on experimental work accomplished over the past twenty years. As such, the method is the beginning of a new approach to glass-making by the use of a molecularly-polymerizable precursor. The book elucidates the technical details required to produce such molecularly-polymerized glasses from carefully prepared inorganic molecular monomers. Essentially, only silicate-based glasses have been known to be stable, whereas non-silicate glasses could not be attributed with such properties. Such glasses have, therefore, not found widespread usage in industry. The new phosphate glasses described here exhibit stabilities superior to many of the silicate glasses. For example, the nuclear-waste glass shows no measurable loss at all in boiling water, something entirely foreign to the zinc borosilicate glasses developed for nuclear waste encapsulation in the U.S. by Battelle-Northwest. The exceptional stability of the new glasses is achieved by selecting an inorganic compound capable of being polymerized, and then causing it to polymerize in a proper manner, in the absence of <Q>chain-stoppers</Q>. To obtain glasses equal or superior in hydrolysis stability to silicate-based systems it is imperative to employ molecular polymerization in situ, starting from carefully prepared precursors of exact stoichiometric proportion. Researchers in glass and glass properties will find this volume extremely useful and those involved in organic polymers will be intrigued by the similarities and disparities of the two systems |
| Beschreibung: | 1 Online-Ressource (xiv, 321 pages) |
| ISBN: | 9781483291390 1483291391 0444895000 9780444895004 |
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| 490 | 0 | |a Studies in inorganic chemistry |v 15 | |
| 500 | |a Includes bibliographical references and index | ||
| 500 | |a The author describes a novel method of preparing hydrolysis-stable non-silicate glasses which is based on experimental work accomplished over the past twenty years. As such, the method is the beginning of a new approach to glass-making by the use of a molecularly-polymerizable precursor. The book elucidates the technical details required to produce such molecularly-polymerized glasses from carefully prepared inorganic molecular monomers. Essentially, only silicate-based glasses have been known to be stable, whereas non-silicate glasses could not be attributed with such properties. Such glasses have, therefore, not found widespread usage in industry. The new phosphate glasses described here exhibit stabilities superior to many of the silicate glasses. For example, the nuclear-waste glass shows no measurable loss at all in boiling water, something entirely foreign to the zinc borosilicate glasses developed for nuclear waste encapsulation in the U.S. by Battelle-Northwest. The exceptional stability of the new glasses is achieved by selecting an inorganic compound capable of being polymerized, and then causing it to polymerize in a proper manner, in the absence of <Q>chain-stoppers</Q>. To obtain glasses equal or superior in hydrolysis stability to silicate-based systems it is imperative to employ molecular polymerization in situ, starting from carefully prepared precursors of exact stoichiometric proportion. Researchers in glass and glass properties will find this volume extremely useful and those involved in organic polymers will be intrigued by the similarities and disparities of the two systems | ||
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Datensatz im Suchindex
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| author | Ropp, R. C. |
| author_facet | Ropp, R. C. |
| author_role | aut |
| author_sort | Ropp, R. C. |
| author_variant | r c r rc rcr |
| building | Verbundindex |
| bvnumber | BV042306368 |
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| ctrlnum | (OCoLC)881849383 (DE-599)BVBBV042306368 |
| dewey-full | 666/.1 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 666 - Ceramic & allied technologies |
| dewey-raw | 666/.1 |
| dewey-search | 666/.1 |
| dewey-sort | 3666 11 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie |
| format | Electronic eBook |
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| illustrated | Not Illustrated |
| indexdate | 2024-07-10T01:17:54Z |
| institution | BVB |
| isbn | 9781483291390 1483291391 0444895000 9780444895004 |
| language | English |
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| spelling | Ropp, R. C. Verfasser aut Inorganic polymeric glasses R.C. Ropp Amsterdam Elsevier 1992 1 Online-Ressource (xiv, 321 pages) txt rdacontent c rdamedia cr rdacarrier Studies in inorganic chemistry 15 Includes bibliographical references and index The author describes a novel method of preparing hydrolysis-stable non-silicate glasses which is based on experimental work accomplished over the past twenty years. As such, the method is the beginning of a new approach to glass-making by the use of a molecularly-polymerizable precursor. The book elucidates the technical details required to produce such molecularly-polymerized glasses from carefully prepared inorganic molecular monomers. Essentially, only silicate-based glasses have been known to be stable, whereas non-silicate glasses could not be attributed with such properties. Such glasses have, therefore, not found widespread usage in industry. The new phosphate glasses described here exhibit stabilities superior to many of the silicate glasses. For example, the nuclear-waste glass shows no measurable loss at all in boiling water, something entirely foreign to the zinc borosilicate glasses developed for nuclear waste encapsulation in the U.S. by Battelle-Northwest. The exceptional stability of the new glasses is achieved by selecting an inorganic compound capable of being polymerized, and then causing it to polymerize in a proper manner, in the absence of <Q>chain-stoppers</Q>. To obtain glasses equal or superior in hydrolysis stability to silicate-based systems it is imperative to employ molecular polymerization in situ, starting from carefully prepared precursors of exact stoichiometric proportion. Researchers in glass and glass properties will find this volume extremely useful and those involved in organic polymers will be intrigued by the similarities and disparities of the two systems Anorganische Polymere swd Glas swd Verre ram Polymères inorganiques ram Glass fast Inorganic polymers fast TECHNOLOGY & ENGINEERING / Chemical & Biochemical bisacsh Glass Inorganic polymers Anorganische Polymere (DE-588)4142565-0 gnd rswk-swf Glas (DE-588)4021142-3 gnd rswk-swf Anorganische Polymere (DE-588)4142565-0 s Glas (DE-588)4021142-3 s 1\p DE-604 http://www.sciencedirect.com/science/book/9780444895004 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Ropp, R. C. Inorganic polymeric glasses Anorganische Polymere swd Glas swd Verre ram Polymères inorganiques ram Glass fast Inorganic polymers fast TECHNOLOGY & ENGINEERING / Chemical & Biochemical bisacsh Glass Inorganic polymers Anorganische Polymere (DE-588)4142565-0 gnd Glas (DE-588)4021142-3 gnd |
| subject_GND | (DE-588)4142565-0 (DE-588)4021142-3 |
| title | Inorganic polymeric glasses |
| title_auth | Inorganic polymeric glasses |
| title_exact_search | Inorganic polymeric glasses |
| title_full | Inorganic polymeric glasses R.C. Ropp |
| title_fullStr | Inorganic polymeric glasses R.C. Ropp |
| title_full_unstemmed | Inorganic polymeric glasses R.C. Ropp |
| title_short | Inorganic polymeric glasses |
| title_sort | inorganic polymeric glasses |
| topic | Anorganische Polymere swd Glas swd Verre ram Polymères inorganiques ram Glass fast Inorganic polymers fast TECHNOLOGY & ENGINEERING / Chemical & Biochemical bisacsh Glass Inorganic polymers Anorganische Polymere (DE-588)4142565-0 gnd Glas (DE-588)4021142-3 gnd |
| topic_facet | Anorganische Polymere Glas Verre Polymères inorganiques Glass Inorganic polymers TECHNOLOGY & ENGINEERING / Chemical & Biochemical |
| url | http://www.sciencedirect.com/science/book/9780444895004 |
| work_keys_str_mv | AT ropprc inorganicpolymericglasses |