Solution thermodynamics and its application to aqueous solutions: a differential approach
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| 1. Verfasser: | |
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| Format: | Elektronisch E-Book |
| Sprache: | English |
| Veröffentlicht: |
Amsterdam
Elsevier
2007
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| Schlagworte: | |
| Online-Zugang: | Volltext |
| Beschreibung: | As the title suggests, we introduce a novel differential approach to solution thermodynamics and use it for the study of aqueous solutions. We evaluate the quantities of higher order derivative than the normal thermodynamic functions. We allow these higher derivative data speak for themselves without resorting to any model system. We thus elucidate the molecular processes in solution, (referred to in this book mixing scheme), to the depth equal to, if not deeper, than that gained by spectroscopic and other methods. We show that there are three composition regions in aqueous solutions of non-electrolytes, each of which has a qualitatively distinct mixing scheme. The boundary between the adjacent regions is associated with an anomaly in the third derivatives of G. The loci of the anomalies in the temperature-composition field form the line sometimes referred as Koga line. We then take advantage of the anomaly of a third derivative quantity of 1-propanol in the ternary aqueous solution, 1-propanol sample species H2O. We use its induced change as a probe of the effect of a sample species on H2O. In this way, we clarified what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. We also apply the same methodology to ions that have been ranked by the Hofmeister series. We show that the kosmotropes (salting out, or stabilizing agents) are either hydrophobes or hydration centres, and that chaotropes (salting in, or destablizing agents) are hydrophiles. - A new differential approach to solution thermodynamics - A particularly clear elucidation of the mixing schemes in aqueous solutions - A clear understandings on the effects of hydrophobes, hydrophiles, and amphiphiles to H2O - A clear understandings on the effects of ions on H2O in relation to the Hofmeister effect - A new differential approach to studies in muti-component aqueous solutions Includes bibliographical references and index |
| Beschreibung: | 1 Online-Ressource (xiv, 296 p.) |
| ISBN: | 9780444530738 0444530738 9780080551876 0080551874 |
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| 500 | |a As the title suggests, we introduce a novel differential approach to solution thermodynamics and use it for the study of aqueous solutions. We evaluate the quantities of higher order derivative than the normal thermodynamic functions. We allow these higher derivative data speak for themselves without resorting to any model system. We thus elucidate the molecular processes in solution, (referred to in this book mixing scheme), to the depth equal to, if not deeper, than that gained by spectroscopic and other methods. We show that there are three composition regions in aqueous solutions of non-electrolytes, each of which has a qualitatively distinct mixing scheme. The boundary between the adjacent regions is associated with an anomaly in the third derivatives of G. The loci of the anomalies in the temperature-composition field form the line sometimes referred as Koga line. We then take advantage of the anomaly of a third derivative quantity of 1-propanol in the ternary aqueous solution, 1-propanol sample species H2O. We use its induced change as a probe of the effect of a sample species on H2O. In this way, we clarified what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. We also apply the same methodology to ions that have been ranked by the Hofmeister series. We show that the kosmotropes (salting out, or stabilizing agents) are either hydrophobes or hydration centres, and that chaotropes (salting in, or destablizing agents) are hydrophiles. - A new differential approach to solution thermodynamics - A particularly clear elucidation of the mixing schemes in aqueous solutions - A clear understandings on the effects of hydrophobes, hydrophiles, and amphiphiles to H2O - A clear understandings on the effects of ions on H2O in relation to the Hofmeister effect - A new differential approach to studies in muti-component aqueous solutions | ||
| 500 | |a Includes bibliographical references and index | ||
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| 650 | 7 | |a Thermodynamics |2 fast | |
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| 650 | 4 | |a Solution (Chemistry) | |
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| author | Koga, Yoshikata |
| author_facet | Koga, Yoshikata |
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| author_sort | Koga, Yoshikata |
| author_variant | y k yk |
| building | Verbundindex |
| bvnumber | BV042305664 |
| collection | ZDB-33-ESD ZDB-33-EBS |
| ctrlnum | (OCoLC)228147953 (DE-599)BVBBV042305664 |
| dewey-full | 541.3416 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.3416 |
| dewey-search | 541.3416 |
| dewey-sort | 3541.3416 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Electronic eBook |
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| id | DE-604.BV042305664 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T01:17:53Z |
| institution | BVB |
| isbn | 9780444530738 0444530738 9780080551876 0080551874 |
| language | English |
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| physical | 1 Online-Ressource (xiv, 296 p.) |
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| spelling | Koga, Yoshikata Verfasser aut Solution thermodynamics and its application to aqueous solutions a differential approach Yoshikata Koga Amsterdam Elsevier 2007 1 Online-Ressource (xiv, 296 p.) txt rdacontent c rdamedia cr rdacarrier As the title suggests, we introduce a novel differential approach to solution thermodynamics and use it for the study of aqueous solutions. We evaluate the quantities of higher order derivative than the normal thermodynamic functions. We allow these higher derivative data speak for themselves without resorting to any model system. We thus elucidate the molecular processes in solution, (referred to in this book mixing scheme), to the depth equal to, if not deeper, than that gained by spectroscopic and other methods. We show that there are three composition regions in aqueous solutions of non-electrolytes, each of which has a qualitatively distinct mixing scheme. The boundary between the adjacent regions is associated with an anomaly in the third derivatives of G. The loci of the anomalies in the temperature-composition field form the line sometimes referred as Koga line. We then take advantage of the anomaly of a third derivative quantity of 1-propanol in the ternary aqueous solution, 1-propanol sample species H2O. We use its induced change as a probe of the effect of a sample species on H2O. In this way, we clarified what a hydrophobe, or a hydrophile, and in turn, an amphiphile, does to H2O. We also apply the same methodology to ions that have been ranked by the Hofmeister series. We show that the kosmotropes (salting out, or stabilizing agents) are either hydrophobes or hydration centres, and that chaotropes (salting in, or destablizing agents) are hydrophiles. - A new differential approach to solution thermodynamics - A particularly clear elucidation of the mixing schemes in aqueous solutions - A clear understandings on the effects of hydrophobes, hydrophiles, and amphiphiles to H2O - A clear understandings on the effects of ions on H2O in relation to the Hofmeister effect - A new differential approach to studies in muti-component aqueous solutions Includes bibliographical references and index SCIENCE / Chemistry / Physical & Theoretical bisacsh Solution (Chemistry) fast Thermodynamics fast Chemie Solution (Chemistry) Thermodynamics http://www.sciencedirect.com/science/book/9780444530738 Verlag Volltext |
| spellingShingle | Koga, Yoshikata Solution thermodynamics and its application to aqueous solutions a differential approach SCIENCE / Chemistry / Physical & Theoretical bisacsh Solution (Chemistry) fast Thermodynamics fast Chemie Solution (Chemistry) Thermodynamics |
| title | Solution thermodynamics and its application to aqueous solutions a differential approach |
| title_auth | Solution thermodynamics and its application to aqueous solutions a differential approach |
| title_exact_search | Solution thermodynamics and its application to aqueous solutions a differential approach |
| title_full | Solution thermodynamics and its application to aqueous solutions a differential approach Yoshikata Koga |
| title_fullStr | Solution thermodynamics and its application to aqueous solutions a differential approach Yoshikata Koga |
| title_full_unstemmed | Solution thermodynamics and its application to aqueous solutions a differential approach Yoshikata Koga |
| title_short | Solution thermodynamics and its application to aqueous solutions |
| title_sort | solution thermodynamics and its application to aqueous solutions a differential approach |
| title_sub | a differential approach |
| topic | SCIENCE / Chemistry / Physical & Theoretical bisacsh Solution (Chemistry) fast Thermodynamics fast Chemie Solution (Chemistry) Thermodynamics |
| topic_facet | SCIENCE / Chemistry / Physical & Theoretical Solution (Chemistry) Thermodynamics Chemie |
| url | http://www.sciencedirect.com/science/book/9780444530738 |
| work_keys_str_mv | AT kogayoshikata solutionthermodynamicsanditsapplicationtoaqueoussolutionsadifferentialapproach |