Stereochemical control, bonding, and steric rearrangements:
Gespeichert in:
| Format: | Elektronisch E-Book |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Amsterdam
Elsevier
1990
|
| Schriftenreihe: | Stereochemistry of organometallic and inorganic compounds
4 |
| Schlagworte: | |
| Online-Zugang: | FAW01 Volltext |
| Beschreibung: | Includes bibliographical references and index The authors of this fourth volume in the series have reviewed the making and breaking of chemical bonds in a sophisticated manner. In particular, new pressures brought about by environmental concerns, larger demands for the medical and pharmaceutical sectors and economics of the market place are forcing us into demanding greater stereochemical control and better product yields for chemical reactions capable of producing useful products. The chapters are written by leading experts in this area and give excellent overviews of the strengths and weaknesses of the various methodologies. In Chapter 1 newer discoveries in such tried and true methods of C-C bond formation as alkylations and aldol reactions of metal enolates are reviewed. The author of Chapter 2 discusses the ability of ab-initio methods to justify the results of empirical observations in the field of transition metal derivatives of small molecules such as N<INF>2</INF>, CO<INF>2</INF> and similar small molecules. Having established the strengths and weaknesses of the various approaches to such theoretical calculations, a more interesting approach to these methods is pursued, namely, their ability to predict, in those areas in which they are particularly strong and reliable, chemical and stereochemical events and/or results in advance of experiments, later carried out in the laboratory. Finally, Chapter 3 reviews the stereochemical results of electron transfer reactions in mononuclear copper compounds |
| Beschreibung: | 1 Online-Ressource (x, 384 pages) |
| ISBN: | 0444597328 0444888411 9780444597328 9780444888419 |
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| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.2/23 s |
| dewey-search | 541.2/23 s |
| dewey-sort | 3541.2 223 S |
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| discipline | Chemie / Pharmazie |
| format | Electronic eBook |
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| genre | 1\p (DE-588)4143413-4 Aufsatzsammlung gnd-content |
| genre_facet | Aufsatzsammlung |
| id | DE-604.BV042304985 |
| illustrated | Not Illustrated |
| indexdate | 2024-07-10T01:17:51Z |
| institution | BVB |
| isbn | 0444597328 0444888411 9780444597328 9780444888419 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027741977 |
| oclc_num | 704481784 |
| open_access_boolean | |
| owner | DE-1046 |
| owner_facet | DE-1046 |
| physical | 1 Online-Ressource (x, 384 pages) |
| psigel | ZDB-33-ESD ZDB-33-ESD FAW_PDA_ESD |
| publishDate | 1990 |
| publishDateSearch | 1990 |
| publishDateSort | 1990 |
| publisher | Elsevier |
| record_format | marc |
| series2 | Stereochemistry of organometallic and inorganic compounds |
| spelling | Stereochemical control, bonding, and steric rearrangements edited by Ivan Bernal Amsterdam Elsevier 1990 1 Online-Ressource (x, 384 pages) txt rdacontent c rdamedia cr rdacarrier Stereochemistry of organometallic and inorganic compounds 4 Includes bibliographical references and index The authors of this fourth volume in the series have reviewed the making and breaking of chemical bonds in a sophisticated manner. In particular, new pressures brought about by environmental concerns, larger demands for the medical and pharmaceutical sectors and economics of the market place are forcing us into demanding greater stereochemical control and better product yields for chemical reactions capable of producing useful products. The chapters are written by leading experts in this area and give excellent overviews of the strengths and weaknesses of the various methodologies. In Chapter 1 newer discoveries in such tried and true methods of C-C bond formation as alkylations and aldol reactions of metal enolates are reviewed. The author of Chapter 2 discusses the ability of ab-initio methods to justify the results of empirical observations in the field of transition metal derivatives of small molecules such as N<INF>2</INF>, CO<INF>2</INF> and similar small molecules. Having established the strengths and weaknesses of the various approaches to such theoretical calculations, a more interesting approach to these methods is pursued, namely, their ability to predict, in those areas in which they are particularly strong and reliable, chemical and stereochemical events and/or results in advance of experiments, later carried out in the laboratory. Finally, Chapter 3 reviews the stereochemical results of electron transfer reactions in mononuclear copper compounds Chemical bonds fast Organic compounds / Synthesis fast Stereochemistry fast Stéréochimie ram Composés organiques / Synthèse ram Liaisons chimiques ram Stereochemie swd Reaktionsmechanismus swd Aufsatzsammlung swd Chemische Bindung swd Umlagerung swd Organische Chemie swd Kupferkomplexe swd Elektrochemie swd Übergangsmetallkomplexe swd Kohlenstoff-Kohlenstoff-Bindung swd Kupplungsreaktion swd Metallorganische Verbindungen swd SCIENCE / Chemistry / Computational & Molecular Modeling bisacsh Chemie Stereochemistry Chemical bonds Organic compounds Synthesis Metallorganische Verbindungen (DE-588)4038906-6 gnd rswk-swf Kupferkomplexe (DE-588)4223142-5 gnd rswk-swf Kupplungsreaktion (DE-588)4166199-0 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf Chemische Bindung (DE-588)4009843-6 gnd rswk-swf Umlagerung (DE-588)4061594-7 gnd rswk-swf Kohlenstoff-Kohlenstoff-Bindung (DE-588)4164549-2 gnd rswk-swf Elektrochemie (DE-588)4014241-3 gnd rswk-swf Reaktionsmechanismus (DE-588)4177123-0 gnd rswk-swf Stereochemie (DE-588)4129569-9 gnd rswk-swf Organische Chemie (DE-588)4043793-0 gnd rswk-swf 1\p (DE-588)4143413-4 Aufsatzsammlung gnd-content Stereochemie (DE-588)4129569-9 s Chemische Bindung (DE-588)4009843-6 s 2\p DE-604 Reaktionsmechanismus (DE-588)4177123-0 s 3\p DE-604 Kupferkomplexe (DE-588)4223142-5 s Elektrochemie (DE-588)4014241-3 s 4\p DE-604 Umlagerung (DE-588)4061594-7 s Organische Chemie (DE-588)4043793-0 s 5\p DE-604 6\p DE-604 Metallorganische Verbindungen (DE-588)4038906-6 s 7\p DE-604 Kohlenstoff-Kohlenstoff-Bindung (DE-588)4164549-2 s Kupplungsreaktion (DE-588)4166199-0 s 8\p DE-604 Übergangsmetallkomplexe (DE-588)4131837-7 s 9\p DE-604 Bernal, Ivan Sonstige oth http://www.sciencedirect.com/science/book/9780444888419 Verlag Volltext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 2\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 3\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 4\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 5\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 6\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 7\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 8\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk 9\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Stereochemical control, bonding, and steric rearrangements Chemical bonds fast Organic compounds / Synthesis fast Stereochemistry fast Stéréochimie ram Composés organiques / Synthèse ram Liaisons chimiques ram Stereochemie swd Reaktionsmechanismus swd Aufsatzsammlung swd Chemische Bindung swd Umlagerung swd Organische Chemie swd Kupferkomplexe swd Elektrochemie swd Übergangsmetallkomplexe swd Kohlenstoff-Kohlenstoff-Bindung swd Kupplungsreaktion swd Metallorganische Verbindungen swd SCIENCE / Chemistry / Computational & Molecular Modeling bisacsh Chemie Stereochemistry Chemical bonds Organic compounds Synthesis Metallorganische Verbindungen (DE-588)4038906-6 gnd Kupferkomplexe (DE-588)4223142-5 gnd Kupplungsreaktion (DE-588)4166199-0 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd Chemische Bindung (DE-588)4009843-6 gnd Umlagerung (DE-588)4061594-7 gnd Kohlenstoff-Kohlenstoff-Bindung (DE-588)4164549-2 gnd Elektrochemie (DE-588)4014241-3 gnd Reaktionsmechanismus (DE-588)4177123-0 gnd Stereochemie (DE-588)4129569-9 gnd Organische Chemie (DE-588)4043793-0 gnd |
| subject_GND | (DE-588)4038906-6 (DE-588)4223142-5 (DE-588)4166199-0 (DE-588)4131837-7 (DE-588)4009843-6 (DE-588)4061594-7 (DE-588)4164549-2 (DE-588)4014241-3 (DE-588)4177123-0 (DE-588)4129569-9 (DE-588)4043793-0 (DE-588)4143413-4 |
| title | Stereochemical control, bonding, and steric rearrangements |
| title_auth | Stereochemical control, bonding, and steric rearrangements |
| title_exact_search | Stereochemical control, bonding, and steric rearrangements |
| title_full | Stereochemical control, bonding, and steric rearrangements edited by Ivan Bernal |
| title_fullStr | Stereochemical control, bonding, and steric rearrangements edited by Ivan Bernal |
| title_full_unstemmed | Stereochemical control, bonding, and steric rearrangements edited by Ivan Bernal |
| title_short | Stereochemical control, bonding, and steric rearrangements |
| title_sort | stereochemical control bonding and steric rearrangements |
| topic | Chemical bonds fast Organic compounds / Synthesis fast Stereochemistry fast Stéréochimie ram Composés organiques / Synthèse ram Liaisons chimiques ram Stereochemie swd Reaktionsmechanismus swd Aufsatzsammlung swd Chemische Bindung swd Umlagerung swd Organische Chemie swd Kupferkomplexe swd Elektrochemie swd Übergangsmetallkomplexe swd Kohlenstoff-Kohlenstoff-Bindung swd Kupplungsreaktion swd Metallorganische Verbindungen swd SCIENCE / Chemistry / Computational & Molecular Modeling bisacsh Chemie Stereochemistry Chemical bonds Organic compounds Synthesis Metallorganische Verbindungen (DE-588)4038906-6 gnd Kupferkomplexe (DE-588)4223142-5 gnd Kupplungsreaktion (DE-588)4166199-0 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd Chemische Bindung (DE-588)4009843-6 gnd Umlagerung (DE-588)4061594-7 gnd Kohlenstoff-Kohlenstoff-Bindung (DE-588)4164549-2 gnd Elektrochemie (DE-588)4014241-3 gnd Reaktionsmechanismus (DE-588)4177123-0 gnd Stereochemie (DE-588)4129569-9 gnd Organische Chemie (DE-588)4043793-0 gnd |
| topic_facet | Chemical bonds Organic compounds / Synthesis Stereochemistry Stéréochimie Composés organiques / Synthèse Liaisons chimiques Stereochemie Reaktionsmechanismus Aufsatzsammlung Chemische Bindung Umlagerung Organische Chemie Kupferkomplexe Elektrochemie Übergangsmetallkomplexe Kohlenstoff-Kohlenstoff-Bindung Kupplungsreaktion Metallorganische Verbindungen SCIENCE / Chemistry / Computational & Molecular Modeling Chemie Organic compounds Synthesis |
| url | http://www.sciencedirect.com/science/book/9780444888419 |
| work_keys_str_mv | AT bernalivan stereochemicalcontrolbondingandstericrearrangements |