Aging mechanisms in lithium-ion batteries with oxidic cathodes:
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| 1. Verfasser: | |
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| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2014
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | X, 262 S. Ill., graph. Darst. |
Internformat
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| 502 | |a Karlsruhe, KIT, Diss., 2014 | ||
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Datensatz im Suchindex
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| adam_text | TABLE OF CONTENTS
ACKNOWLEDGEMENT V
ABBREVIATIONS VII
1. INTRODUCTION 1
1.1. MOTIVATION 1
1.2. THE OBJECTIVES OF THIS WORK 2
1.3. OUTLINE OF THIS WORK 4
2. FUNDAMENTALS 5
2.1. ELECTROCHEMICAL STORAGE SYSTEMS 5
2.2. ELECTROCHEMICAL PRINCIPLES 7
2.2.1. ELECTRICAL POTENTIAL DIFFERENCE IN A GALVANIC CELL 7
2.2.2. OVERPOTENTIAL 8
2.3. INTRODUCTION TO LITHIUM-ION BATTERIES 11
2.3.1. ASSEMBLY AND PRINCIPLES OF LITHIUM-ION BATTERIES 11
2.3.2. MATERIALS AND COMPOUNDS FOR LITHIUM-ION BATTERIES 12
2.3.3. PRODUCTION OF ELECTRODES AND CONSTRUCTION TYPES 19
2.4. TERMINOLOGY 20
2.5. LITERATURE DATA ON BEV BATTERY ELECTRODE COMPONENTS 21
2.5.1. LITERATURE DATA ON LINII/JCOIAMNI/JOZ 21
2.5.2. LITERATURE DATA ON L1M112O4 23
2.5.3. LITERATURE DATA ON LINII/JCOMMN 1/JO2 / LIMI^OJ BLENDS 26
2.5.4. LITERATURE DATA ON GRAPHITE 27
2.6. LITERATURE DATA ON AGING MECHANISMS IN LITHIUM-ION BATTERIES 30
2.6.1. AGING MECHANISMS OF NEGATIVE ELECTRODE MATERIALS 31
2.6.2. AGING MECHANISMS OF POSITIVE ELECTRODE MATERIALS 34
2.6.3. AGING OF OTHER COMPONENTS 35
2.6.4. LITERATURE DATA ON AGED LIMI^OJ 36
2.6.5. LITERATURE DATA ON AGED LINII/JCO//JMNI/JO2 39
2.6.6. LITERATURE DATA ON AGED LINII/JCOI/JMN 1/3O2 / UM112O4 BLENDS 40
2.6.7. LITERATURE DATA ON AGED GRAPHITE 42
HTTP://D-NB.INFO/1058986716
2.6.8. LITERATURE DATA ON AGED FULL CELLS 45
2.6.9. CONCLUSIONS 47
3. EXPERIMENTAL 51
3.1. EXPERIMENTAL CELL SETUPS 51
3.1.1. GENERAL ELECTRODE ARRANGEMENTS 51
3.1.2. 18650 CELL 51
3.1.3. LABORATORY TEST CELL 52
3.2. ELECTROCHEMICAL CHARACTERIZATION METHODS 53
3.2.1. CHARACTERIZATION OF SAMSUNG SDI ICR 18650-20F CELLS 53
3.2.2. CHARACTERIZATION OF LABORATORY TEST CELLS 54
3.2.3. CYCLIC VOLTAMMETRY 54
3.2.4. THE MEASUREMENT ACCURACY OF ELECTROCHEMICAL CHARACTERIZATION 55
3.2.5. ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY 56
3.3. ANALYTICAL CHARACTERIZATION METHODS 65
3.3.1. X-RAY DIFFRACTION 65
3.3.2. MICROSTRUCTURAL INVESTIGATION 67
3.3.3. MICROSTRUCTURE RECONSTRUCTION 69
3.3.4. GAS CHROMATOGRAPHY - MASS SPECTROSCOPY (GC-MS) 74
3.3.5. INDUCTIVELY COUPLED PLASMA - OPTICAL EMISSION SPECTROSCOPY
(ICP-OES) 75
3.3.6. RAMAN SPECTROSCOPY 75
3.4. POST-MORTEM ANALYSIS 76
3.4.1. PREPARATION OF ANODE AND CATHODE MATERIALS FOR TEST CELLS 77
3.4.2. CHALLENGES DURING PREPARATION AND REASSEMBLY OF TEST CELLS 77
3.5. AGING OF SAMSUNG SDI ICR 18650-20F LITHIUM-ION CELLS 78
3.5.1. CYCLE AGING TESTS 78
3.5.2. CALENDAR AGING TESTS 80
4. RESULTS AND DISCUSSION 81
4.1. CHARACTERIZATION OF THE NEW SAMSUNG SDI ICR 18650-20F 81
4.1.1. RATE CAPABILITY OF SAMSUNG SDI ICR 18650-20F CELL 81
4.1.2. ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY OF SAMSUNG SDI ICR
18650-20F
CELL 82
4.1.3. ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY ON SYMMETRIC CELLS 86
4.1.4. EQUIVALENT CIRCUIT MODELING OF ELECTROCHEMICAL IMPEDANCE SPECTRA
88
4.1.5. CHARACTERIZATION OF THE NEW CATHODE 91
4.1.6. CHARACTERIZATION OF THE NEW ANODE 97
4.1.7. CHARACTERIZATION OF THE ELECTROLYTE 100
4.1.8. CHARACTERIZATION OF THE SEPARATOR 102
4.2. CHARACTERIZATION OF CYCLE AGED SAMSUNG SDI ICR 18650-20F 103
4.2.1. CONTINUOUS DISCHARGE (1C, SOCIOO
- SOCO) CYCLE AGED SAMSUNG 20F 105
4.2.2. COMPARISON OF WIDE (SOCIOO - SOCO) AND SHALLOW (SOC60 - SOC40)
PULSE
DISCHARGE CYCLE AGED SAMSUNG SDI ICR 18650-20F 132
4.2.3. COMPARISON OF PULSE DISCHARGE CYCLE AGED SAMSUNG SDI ICR
18650-20F
BATTERY IN THE LOW (SOC50 - SOCO), MIDDLE (SOC75 - SOC25) AND HIGH
(SOCIOO - SOC50) SOC AREAS 145
4.3. CHARACTERIZATION OF CALENDAR AGED SAMSUNG SDI ICR 18650-20F 149
4.3.1. COMPARISON OF CALENDAR AGED SAMSUNG SDI ICR 18650-20F AT SOCIOO
AND
SOC80 AT 60 C 152
4.3.2. COMPARISON OF CALENDAR AGED SAMSUNG SDI ICR 18650-20F AT SOC50 AT
60 C AND ROOM TEMPERATURE 173
5. SUMMARY AND OUTLOOK 189
6. ZUSAMMENFASSUNG UND AUSBLICK 197
7. CURRICULUM VITAE 199
LIST OF PUBLICATIONS 201
LIST OF FIGURES 203
LIST OF TABLES 213
BIBLIOGRAPHY 215
APPENDIX A: SPECIFICATION OF SAMSUNG SDI ICR 18650-20F 221
APPENDIX B: SUPPLEMENTS TO EXPERIMENTAL PART 222
APPENDIX C: OCV TABLES 227
APPENDIX D: POTENTIAL TEST RESULTS 233
APPENDIX E: SEM IMAGES 235
APPENDIX F: LIGHT MICROSCOPY IMAGES 238
APPENDIX G: GC-MS SPECTRA 240
APPENDIX H: RAMAN SPECTROSCOPY 243
APPENDIX I: FURTHER RESULTS 245
III
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| author | Stiaszny, Barbara 1987- |
| author_GND | (DE-588)1058374168 |
| author_facet | Stiaszny, Barbara 1987- |
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| dewey-full | 621.312424 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 621 - Applied physics |
| dewey-raw | 621.312424 |
| dewey-search | 621.312424 |
| dewey-sort | 3621.312424 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Elektrotechnik / Elektronik / Nachrichtentechnik |
| format | Thesis Book |
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| spelling | Stiaszny, Barbara 1987- Verfasser (DE-588)1058374168 aut Aging mechanisms in lithium-ion batteries with oxidic cathodes von Barbara Stiaszny 2014 X, 262 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Karlsruhe, KIT, Diss., 2014 Grafitverbindungen (DE-588)4158077-1 gnd rswk-swf Lithium-Ionen-Akkumulator (DE-588)7681721-0 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Lithium-Ionen-Akkumulator (DE-588)7681721-0 s Grafitverbindungen (DE-588)4158077-1 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027729705&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Stiaszny, Barbara 1987- Aging mechanisms in lithium-ion batteries with oxidic cathodes Grafitverbindungen (DE-588)4158077-1 gnd Lithium-Ionen-Akkumulator (DE-588)7681721-0 gnd |
| subject_GND | (DE-588)4158077-1 (DE-588)7681721-0 (DE-588)4113937-9 |
| title | Aging mechanisms in lithium-ion batteries with oxidic cathodes |
| title_auth | Aging mechanisms in lithium-ion batteries with oxidic cathodes |
| title_exact_search | Aging mechanisms in lithium-ion batteries with oxidic cathodes |
| title_full | Aging mechanisms in lithium-ion batteries with oxidic cathodes von Barbara Stiaszny |
| title_fullStr | Aging mechanisms in lithium-ion batteries with oxidic cathodes von Barbara Stiaszny |
| title_full_unstemmed | Aging mechanisms in lithium-ion batteries with oxidic cathodes von Barbara Stiaszny |
| title_short | Aging mechanisms in lithium-ion batteries with oxidic cathodes |
| title_sort | aging mechanisms in lithium ion batteries with oxidic cathodes |
| topic | Grafitverbindungen (DE-588)4158077-1 gnd Lithium-Ionen-Akkumulator (DE-588)7681721-0 gnd |
| topic_facet | Grafitverbindungen Lithium-Ionen-Akkumulator Hochschulschrift |
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