Biopolymers: processing and products
Gespeichert in:
1. Verfasser: | |
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Format: | Buch |
Sprache: | English |
Veröffentlicht: |
Amsterdam [u.a.]
Elsevier, William Andrew
2015
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Schriftenreihe: | PDL handbook series
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Schlagworte: | |
Online-Zugang: | Klappentext Inhaltsverzeichnis |
Beschreibung: | XIV, 601 S. Ill. |
ISBN: | 9780323266987 |
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adam_text | -4 Volume in the Plastics Design Library Series
Biopolymers: Processing and Products
Michael Niaounakis
The authoritative book on all aspects of biopolymer product development, from processing properties to intellectual property
Biopolymers and biodegradable plastics arc finding new applications in various sectors, from packaging to medical, automotive,
and many more. As synthetic plastics are increasingly replaced by their bioplastic equivalents, engineers are facing new challenges
including processing, costs, environmental sustainability, and—ultimately—developing successful products.
Biopolymers: Processing and Products, the second book of a trilogy dedicated to biopolymers gives a detailed insight into all aspects
of processing, seamlessly linking the science of biopolymers to the latest trends in the development of new products. Processes covered
in the book include blending, compounding, treatment, and shaping, as well as the formation of biocomposites. Biopolymer coatings
and adhesives are also investigated.
The coverage of processing will help engineers and designers to improve output and efficiency of every stage of the product development
process, and will form an indispensable tool in selecting the right biopolymer and processing technique for any given application,
covering medical, automotive, food packaging, and more. It will assist also engineers, material scientists, and researchers to improve
existing biopolymer processes and deliver better products at lower cost.
ABOUT THE AUTHOR
Michael Niaounakis has been working for more than 20 years at the European Patent Office as a patent examiner in the technical areas
of polymer recycling and biopolymer composition. He holds a BSc degree in Physics from the National University of Athens, an MSc
in Polymer Science Technology from the University of Manchester Institute of Science and Technology and a PhD in the Physics of
Polymers and Composite Materials from the National Technical University of Athens.
RELATED TITLES
Biopolymers Reuse, Recycling, and Disposal, Michael Niaounakis, 9781455731459, June 2013
Biopolymers and Biodegradable Plastics, Sina Ebncsajjad (ed.), 9781455728343, September 2012
Bio-Based Polymers and Composites, Wool Sun, 9780127639529, August 2005
Polylactic Acid, Sin, Rahmat Rahman, 9781437744590, October 2012
Contents
Foreword
Abbreviations of Biopolymers
1. Introduction
1.1 Definition of Terms
1.2 Classification of Biopolymers
1.3 Types and Chemistry of Biopolymers
1.4 Polyesters
1.4.1 Poly(hydroxy acid)s
1.4.2 Polyfalkylene dicarboxylate)s
1.5 Poly(ether-ester)s (Bio-Based)
1.5.1 Polydioxanone
1.6 Aliphatic Polycarbonates
1.6.1 Polyethylene carbonate)
1.6.2 Polypropylene carbonate)
1.6.3 Poiy(trimethylene carbonate)
1.6.4 Poly(butylene carbonate)
1.7 Polyamides
1.7.1 Polycondensation of Diamines
and Dicarboxylic Acids
1.7.2 Polycondensation of co-Amino
Carboxylic Acids or Lactams
1.7.3 Poly(a-amino acids)
1.8 Poly(ester amides)
1.9 Poly(ether amide)s
1.10 Polyurethanes (Bio-Based PU)
1.11 Polysaccharides
1.11.1 Cellulose
1.11.2 Starch
1.11.3 Chitin, Chitosan
1.12 Lignin
1.13 Vinyl Polymers
1.13.1 Polyolefins (Bio-Based)
1.13.2 Poly(vinyl chloride) (Bio-Based PVC)
1.13.3 Polyfvinyl alcohol)
1.14 Diene Polymers
1.14.1 c/s-1,4-Polyisoprene
1.15 Other Biodegradable Polymers
1.15.1 Poly(ortho ester)s
1.15.2 Polyanhydrides
1.15.3 Polyphosphazenes
1.16 Sources of Biopolymers
Patents
References
2. Properties 9
2.1 Intrinsic Properties 79
2.1.1 Density 79
2.1.2 Transition Temperatures
and Crystallinity 79
2.1.3 Solubility 81
2.1.4 Mechanical Properties 81
2.1.5 Gas Barrier Properties 83
2.1.6 Transparency 86
2.1.7 Electromagnetic Properties 87
2.2 Processing Properties 87
2.2.1 Poly(lactic acid) 87
2.2.2 Poly(glycolic acid) 88
2.2.3 Polyhydroxyalkanoates 88
2.2.4 Poly(e-caprolactone) 89
2.3 Product Properties 89
2.3.1 Mechanical Behavior 89
2.3.2 Heat Resistance 90
2.3.3 Water Resistance 92
2.3.4 Antistatic Properties 92
2.3.5 Flammabiiity/Flame Retardancy 92
2.3.6 Aesthetic Properties 92
2.3.7 Environmental Behavior 94
Patents 100
References 115
3. Blending
3.1 Blends in General 117
3.2 Blending Biopolymers with Other
Biopolymers 118
3.2.1 Blending Different Aliphatic (co)
polyesters 118
3.2.2 Blending Aliphatic-Aromatic
Copolyesters with Aliphatic (co)polyesters 125
3.2.3 Blending Aliphatic Polycarbonates with
Aliphatic Polyesters 126
3.2.4 Blending Cellulose Derivatives with
Biodegradable Polymers 127
3.2.5 Blending Starch with Biodegradable
Polymers 128
3.2.6 Blending Lignin with Biodegradable
Polymers 131
3.2.7 Blending Natural Rubber with
Biodegradable Polymers 132
ix
xiii
1
2
4
4
4
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23
24
24
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25
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VI
Contents
3.3 Blending Biopolymers with Synthetic
Nlonbiodegradable Polymers 133
3.3.1 Biopolymer in Majority 133
3.3.2 Biopolymer in Minority 143
3.4 Commercial Products 150
Patents 152
References 183
4. Emulsions/Dispersions/Solutions/Gels
4.1 Making Emulsions and Dispersions 187
4.1.1 Solvent-Based Methods 187
4.1.2 Thermomechanical Methods 192
4.1.3 Nonsolvent Destructuring Methods 194
4.2 Making Solutions 195
4.3 Making (Hydro)Gels 197
Patents 199
References 214
5. Compounding and Additives
5.1 General 215
5.2 Compounding by Shear and Heat 215
5.2.1 Compounding with Inorganic
Compounds 215
5.2.2 Compounding with Organic
Compounds 217
5.3 Compounding in Liquid or Solution 218
5.3.1 Compounding in Liquid or Solution
with Inorganic Compounds 218
5.3.2 Compounding in Liquid or Solution
with Organic Compounds 218
5.4 Making Masterbatches 219
5.5 Additives and Modifiers 223
5.5.1 Processability Boosters 223
5.5.2 Performance Boosters 228
Patents 242
References 262
6. Powdering
6.1 Pelletization 263
6.2 Pulverization 264
6.3 Dissolution-Deposition 265
6.4 Emulsion-Precipitation 266
6.5 Coagulating Dispersions 268
6.6 Supercritical Fluid Technology 268
Patents 270
References 276
7. Chemical Treatment (in Bulk)
7.1 Introduction of Functional Groups 277
7.2 Controlled Degradation 283
7.3 Increasing the Molecular Weight 284
7.4 Radiation (in Bulk) 284
7.5 Interreacting Polymers 285
7.5.1 Polymer Branching/Bridging 285
7.5.2 Crosslinking 286
7.5.3 Interpenetrating Polymeric Networks 289
Patents 290
References 300
8. Surface Treatment
8.1 General 303
8.2 Physical Treatment 303
8.2.1 Physical Treatment with Solvents/
Swelling Agents 303
8.2.2 Roughening 304
8.2.3 Heat Treatment 304
8.3 Chemical Treatment 304
8.3.1 Hydrolysis/Aminolysis 305
8.3.2 Incorporation of Functional Groups 305
8.3.3 Grafting 307
8.4 Coating 308
8.4.1 Coating with Inorganic Materials 308
8.4.2 Coating with Low-Molecular-Weight
Organic Materials 310
8.4.3 Single Polymer Coating 311
8.4.4 Multiple Coatings 313
8.5 Printing 313
8.5.1 3D Printing 315
Patents 317
References 326
9. Foaming and Foamed Products
9.1 Biopolymer Foams 327
9.2 Types of Biopolymers 327
9.2.1 Polyesters 327
9.2.2 Starch 328
9.3 Foaming Agents 329
9.3.1 Physical Foaming Agents 330
9.3.2 Chemical Foaming Agents 332
9.4 Compounding Ingredients 332
9.4.1 Inorganic Compounds 332
9.4.2 Organic Compounds 333
9.4.3 Polymer Components 335
9.4.4 Mixtures of Compounding Ingredients 335
9.5 Expandable Particles 336
9.5.1 Sintering Expandable Particles 339
9.6 Composite Foams 340
9.7 Crosslinking 341
9.8 After Treatment of Foams 342
9.8.1 Heat Treatment 342
9.8.2 Coating 343
9.8.3 Elimination of a Liquid or Solid
Phase from a Biopolymer Composition
or Article (e.g., Leaching Out) 343
Patents 345
Contents
10. Manufacture of Films/Laminates
10.1 Films
10.1.1 Films by Chemical Type
10.1.2 Shrinkable Films
10.1.3 Porous Films
10.2 Laminates
Patents
11. Manufacture of Fibers and Fabrics
11.1 Fiber Formation
11.1.1 Polyflactic acid)
11.1.2 Polyhydroxyalkanoates
11.1.3 Aliphatic-Aromatic Polyesters
11.1.4 Aromatic Polyesters (Bio-Based)
11.1.5 Starch
11.2 Nonwoven
11.2.1 Carpets
11.3 Woven/Knitted
11.4 Nanofibers
11.5 Wearing Resistance of Fibers
11.6 Antistatic Fibers
Patents
12. Manufacture of Biocomposites
12.1 General
12.2 Reinforcing Biopolymers with Loose or
Coherent Fibrous Material
12.2.1 With Carbon Fibers
12.2.2 With Glass Fibers
12.2.3 With Vegetable or Animal Fibers
12.2.4 With Synthetic Polymeric Fibers
or Their Mixtures
12.2.5 With Pretreated Fibers
12.3 Reinforcing Biopolymers with Fillers
12.3.1 With Inorganic Fillers
12.3.2 With Organic Fillers
12.3.3 Nanobiocomposites
12.4 Manufacture of Prepregs
12.5 Bonding Preformed Biopolymers to
the Same or Other Solid Material
12.5.1 Using Adhesives
12.5.2 Using Heat
12.5.3 Using Surface Treatment
Patents
References
13. Coating Compositions
13.1 General
13.2 Thermoplastic Coating Compositions
13.2.1 Polyhydroxyalkanoate(s)
13.2.2 Poly(Lactic Acid)
vii
13.2.3 Starch 434
13.2.4 Cellulose Derivatives 434
13.3 Powder Coatings 435
13.4 Temporary or Strippable Coatings 435
Patents 439
14. Inks
14.1 Inks in General 447
14.2 Jet Printing Inks 447
14.2.1 Hot Melt Inks 448
14.3 Flexographic Inks, Gravure Inks,
and Screen Inks 449
14.4 Electrophotographic Toners 451
14.5 Color Changing Inks 452
14.6 Writing Inks 452
Patents 454
15. Adhesive Compositions
15.1 Classification of Adhesives 459
15.2 Nonreactive Adhesives 459
15.2.1 Drying Adhesives 459
15.2.2 Pressure-Sensitive
Adhesives 461
15.2.3 Hot-Melt Adhesives 464
15.3 Reactive Adhesives 466
15.3.1 One-Component Reactive
Adhesives 466
15.3.2 Multicomponent Reactive
Adhesives 467
15.4 Bio-Based Adhesives 467
15.4.1 Proteins 467
15.4.2 Starch 468
15.4.3 Chitin, Chitosan 468
15.4.4 Natural Resins 468
Patents 469
References 480
16. Recycling
16.1 Reuse 481
16.1.1 Recuperation 481
16.1.2 Restabilization 483
16.1.3 Blending Recycled Biopolymers
with Other Polymers 484
16.1.4 Modification of the Chemical
Structure 485
16.1.5 Multiple Processing 486
16.2 Physical Recycling 487
16.2.1 General 487
16.2.2 Grinding 487
16.2.3 Sorting 488
16.2.4 Drying 496
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VIII
Contents
Chemical Recycling 496 Patents 515
16.3.1 Dry-Heat Depolymerization References 529
(in the Melt) 497
16.3.2 Hydrolysis/Solvolysis
(Alcoholysis) 500 Glossary 531
16.3.3 Hydrothermal Index 543
Depolymerization 505 Index of Companies 553
16.3.4 Enzymatic Depolymerization 510 Index of in venters 557
16.3.5 Miscellaneous Processes 514 Index of patents 571
|
any_adam_object | 1 |
author | Niaounakis, Michael |
author_facet | Niaounakis, Michael |
author_role | aut |
author_sort | Niaounakis, Michael |
author_variant | m n mn |
building | Verbundindex |
bvnumber | BV042229893 |
classification_rvk | UV 9250 UV 9450 UV 9500 WD 2200 |
ctrlnum | (OCoLC)900949439 (DE-599)BVBBV042229893 |
dewey-full | 668.4 |
dewey-hundreds | 600 - Technology (Applied sciences) |
dewey-ones | 668 - Technology of other organic products |
dewey-raw | 668.4 |
dewey-search | 668.4 |
dewey-sort | 3668.4 |
dewey-tens | 660 - Chemical engineering |
discipline | Chemie / Pharmazie Physik Biologie |
format | Book |
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id | DE-604.BV042229893 |
illustrated | Illustrated |
indexdate | 2024-07-10T01:15:53Z |
institution | BVB |
isbn | 9780323266987 |
language | English |
oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027668224 |
oclc_num | 900949439 |
open_access_boolean | |
owner | DE-11 DE-703 |
owner_facet | DE-11 DE-703 |
physical | XIV, 601 S. Ill. |
publishDate | 2015 |
publishDateSearch | 2015 |
publishDateSort | 2015 |
publisher | Elsevier, William Andrew |
record_format | marc |
series2 | PDL handbook series |
spelling | Niaounakis, Michael Verfasser aut Biopolymers processing and products Michael Niaounakis Amsterdam [u.a.] Elsevier, William Andrew 2015 XIV, 601 S. Ill. txt rdacontent n rdamedia nc rdacarrier PDL handbook series Abbaubarer Kunststoff (DE-588)4305214-9 gnd rswk-swf Biologisch abbaubarer Kunststoff (DE-588)4634464-0 gnd rswk-swf Biopolymere (DE-588)4006893-6 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Mechanische Eigenschaft (DE-588)4217961-0 gnd rswk-swf Nachwachsender Rohstoff (DE-588)4171069-1 gnd rswk-swf Kunststoff (DE-588)4033676-1 gnd rswk-swf Verarbeitung (DE-588)4537851-4 gnd rswk-swf Polymere (DE-588)4046699-1 s Nachwachsender Rohstoff (DE-588)4171069-1 s DE-604 Kunststoff (DE-588)4033676-1 s Abbaubarer Kunststoff (DE-588)4305214-9 s Biopolymere (DE-588)4006893-6 s Biologisch abbaubarer Kunststoff (DE-588)4634464-0 s Mechanische Eigenschaft (DE-588)4217961-0 s Verarbeitung (DE-588)4537851-4 s 1\p DE-604 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027668224&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Klappentext Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027668224&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
spellingShingle | Niaounakis, Michael Biopolymers processing and products Abbaubarer Kunststoff (DE-588)4305214-9 gnd Biologisch abbaubarer Kunststoff (DE-588)4634464-0 gnd Biopolymere (DE-588)4006893-6 gnd Polymere (DE-588)4046699-1 gnd Mechanische Eigenschaft (DE-588)4217961-0 gnd Nachwachsender Rohstoff (DE-588)4171069-1 gnd Kunststoff (DE-588)4033676-1 gnd Verarbeitung (DE-588)4537851-4 gnd |
subject_GND | (DE-588)4305214-9 (DE-588)4634464-0 (DE-588)4006893-6 (DE-588)4046699-1 (DE-588)4217961-0 (DE-588)4171069-1 (DE-588)4033676-1 (DE-588)4537851-4 |
title | Biopolymers processing and products |
title_auth | Biopolymers processing and products |
title_exact_search | Biopolymers processing and products |
title_full | Biopolymers processing and products Michael Niaounakis |
title_fullStr | Biopolymers processing and products Michael Niaounakis |
title_full_unstemmed | Biopolymers processing and products Michael Niaounakis |
title_short | Biopolymers |
title_sort | biopolymers processing and products |
title_sub | processing and products |
topic | Abbaubarer Kunststoff (DE-588)4305214-9 gnd Biologisch abbaubarer Kunststoff (DE-588)4634464-0 gnd Biopolymere (DE-588)4006893-6 gnd Polymere (DE-588)4046699-1 gnd Mechanische Eigenschaft (DE-588)4217961-0 gnd Nachwachsender Rohstoff (DE-588)4171069-1 gnd Kunststoff (DE-588)4033676-1 gnd Verarbeitung (DE-588)4537851-4 gnd |
topic_facet | Abbaubarer Kunststoff Biologisch abbaubarer Kunststoff Biopolymere Polymere Mechanische Eigenschaft Nachwachsender Rohstoff Kunststoff Verarbeitung |
url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027668224&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027668224&sequence=000002&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
work_keys_str_mv | AT niaounakismichael biopolymersprocessingandproducts |