Synthesis techniques for polymer nanocomposites:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2015
|
| Schriftenreihe: | Polymer nano-, micro- & macrocomposites
6 |
| Schlagworte: | |
| Online-Zugang: | Klappentext Inhaltsverzeichnis |
| Beschreibung: | XVI, 297 S. Ill., graph. Darst. |
| ISBN: | 9783527334551 9783527670307 |
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Datensatz im Suchindex
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| adam_text | WlLEY-VCH
The book series ‘Polymer Nano-, Micro- and Macrocomposites’ provides complete and
comprehensive information on all important aspects of polymer composite research
and development, including, but not limited to synthesis, filler modification, modeling,
characterization as well as application and commercialization issues. Each book focuses
on a particular topic and gives a balanced in-depth overview of the respective subfield of
polymer composite science and its relation to industrial applications. With the books the
readers obtain dedicated resources with information relevant to their research, thereby
helping to save time and money.
Summarizing all the most important synthesis techniques used in the lab as well
as in industry, this book is comprehensive in its coverage from chemical, physical and
mechanical viewpoints.
This book helps readers to choose the correct synthesis routes, such as suspension
and miniemulsion polymerization, living polymerization, sonication, mechanical
methods or the use of radiation, and so achieve the desired composite properties.
Vikas Mittal is an Associate Professor at the Chemical Engineering
Department of The Petroleum Institute, Abu Dhabi. He obtained his
PhD in 2006 in Polymer and Materials Engineering from the Swiss
Federal Institute of Technology in Zurich, Switzerland. Later, he worked
as Materials Scientist in the Active and Intelligent Coatings section of
SunChemical in London, UK and as Polymer Engineer at BASF Polymer
Research in Ludwigshafen, Germany. His research interests include polymer
nanocomposites, novel filler surface modifications, thermal stability
enhancements, polymer latexes with functionalized surfaces etc. He has
authored over 40 scientific publications, book chapters and patents on these
subjects.
Volume 6
Contents^
Preface XI
List of Contributors XIII
1 Synthesis of Polymer Nanocomposites: Review of Various
Techniques 1
Joel Fowoz and Vikas Mittal
1.1 Introduction 1
1.2 Synthesis Methods 4
1.2.1 Melt Intercalation 4
1 /2.2 Exfoliation Adsorption 9
L2.2.1 Solution Intercalation 9
1.2.2.2 Emulsion Polymerization 11
1.2.3 /« Situ Polymerization i6
1.2.4 Nontraditional Methods 23
References 26
2 Masterbatch Approach to Generate HDPE/CPE/Graphene
Nanocomposites 31
AH U. Chaudhry and Vikas Mittal
2.1 Introduction 31
2.2 Experimental 33
2.2.1 Materials 33
2.2.2 Preparation of Graphite Oxide and Graphene Oxide 34
2.2.3 Nanocomposite Generation 35
2.2.4 Material Characterization 36
2.3 Results and Discussion 37
2.4 Conclusions 47
Acknowledgments 48
References 48
VI
Contents
3 Preparation and Applications of Hydroxyapatite Nanocomposites
Based on Biodegradable and Natural Polymers 51
Pou Turon, LuisJ. del Valle, Carlos Aleman, and Jordi Puiggali
3.1 Introduction 51
3.2 Preparation of HAp Nanocrystals 52
3.3 Preparation of HAp Nanocomposites 58
3.4 Applications of HAp/DNA Nanocomplexes as Gene Carriers 61
3.5 Tissue Engineering Applications of HAp Nanocomposites Based on
Biodegradable Polymers 65
3.6 Applications of HAp Nanocomposites Based on Biodegradable
Polymers as Drug Delivery Systems 72
3.7 Miscellaneous Applications of HAp Nanocomposites Based on
Biodegradable Polymers 76
3.8 Concluding Remarks 79
Acknowledgments 80
References 80
4 Synthetic Methods for Nanocomposites Based on Polyester Resins 8
Michał Kędzierski
4.1 Introduction 87
4.2 Nanocomposites with Zero-Dimensional Nanorillers 89
4.2.1 Silicon-Containing Nanospheres 89
4.2.2 Metal Oxides 91
4.2.3 Other 0-D Nanoparticles 93
4.3 Nanocomposites with One-Dimensional Nanofillers 93
4.3.1 Carbon Nanotubes and Nanofibers 93
4.3.2 Cellulose Nanofibers 96
4.3.3 Other 1-D Nanofillers 97
4.4 Nanocomposites with Two-Dimensional Nanorillers 97
4.4.1 Layered Aluminosilicate Clays 97
4.4.1.1 Mixing Methods 98
4.4.1.2 Effects of the Clay Modification 99
4.4.1.3 Nanocomposites with MMT Introduced during the Synthesis of
Pre-polymer 102
4.4.1.4 Various Properties and Multiphase Nanocomposites 103
4.4.1.5 Vinyl Ester-Clay Nanocomposites 106
4.4.2 Layered Double Hydroxides 106
4.4.3 Graphene-Based Nanofillers 107
4.5 Conclusions 109
Abbreviations 110
References 110
Contents
VII
5
5.1
5.2
5.3
5.3.1
5.3.2
5.3.3
5.3.4
5.3.5
5.3.6
5.4
6
6.1
6.2
6.2.1
6.2.1.1
6.3
6.4
6.5
6.6
7
7.1
7.2
7.2.1
7.2.1.1
7.2.1.2
7.2.2
7.2.2.1
7.2.2.2
Synthesis Fabrication and Characterization of Ag/CNT-Polymer
Nanocomposites 115
Vijoya K. Rongari and Sanchit Dey
Introduction 115
Experimental Procedure 118
Results and Discussion 119
XRD analysis 119
Transmission Electron Microscopy 119
TGA Analysis of Nanoparticles 121
Thermal Response of the Polymer Composites 121
Compression Test Results of Polymer Composites 124
Flexure Test Results of Polymer Composites 125
Conclusion 127
Acknowledgments 127
References 127
Preparation and Characterization of PVDF-Based
Nanocomposites 131
Derman Vatansever Bayramol, Tahir Shah, Navneet Soin, and Elias Siores
Synthesis of Poly(vinylidene fluoride) (PVDF) 131
Structure and Piezoelectric Properties of PVDF 131
Relationships and Equations 135
The Piezoelectric Charge Constant and Piezoelectric Voltage
Constant 136
Processing of PVDF for Energy Harvesting Applications 137
Processing of PVDF Based Materials: Polymer/Polymer,
Polymer/Nanofiller, Polymer/Ionomer Blends 138
PVDF Based Nanocomposites for Energy Harvesting
Applications 139
Conclusion 140
References 141
In Situ Thermal, Photon, and Electron-Beam Synthesis of Polymer
Nanocomposites 145
Luana Persa no, Andrea Camposeo, Anna Maria Laera, Francesca Di
Benedetto, Vincenzo Resta, Leander Tapfer, and Dario Pisignano
Introduction 145
Thermal-Assisted In Situ Synthesis: Material Choice and
Nanocomposite Characterization 146
Precursor Molecules 146
Metal Salts 147
Organometallic Compounds 147
Thermal Synthesis and Composites Characterization 151
Microstructural Characterization 152
Optical Spectroscopy Experiments 154
VIII
Contents
7.3 Fabrication of Nanocomposites and Patterning 155
7.3.1 Nanocomposites by Photoirradiation 157
7.3.1.1 UV and Visible Irradiation 157
7.3.1.2 Multiphoton Irradiation 160
7.3.2 Nanocomposites by Electron-Beam Writing 160
7.3.3 Nanocomposite Polymer Fibers 765
7.3.3.1 Photo-Assisted Synthesis 167
7.3.3.2 Thermal-Assisted Synthesis 169
7.4 Conclusions 171
Acknowledgments 172
References 172
8 Synthesis of Polymer Nanocomposites by Water-Assisted
Extrusion 179
Naïma Sallem֊ldrissi, Michel Sclavons, and Jacques Devaux
8.1 Introduction 179
8.2 Nanocomposites Structure and Characterization 180
8.2.1 Clays 180
8.2.2 Organomodification of Layered Silicates 181
8.2.3 Nanocomposites Structure and Characterization 182
8.3 Nanocomposites Preparation 183
8.3.1 Intercalation from Solution 183
8.3.2 In Situ Polymerization 183
8.3.3 Melt Compounding 184
8.3.3.1 Melt Blending of Polymer/Organoclay Nanocomposites 184
8.3.3.2 Melt Blending of Polymer/Pristine Clay Nanocomposites 186
8.4 Nanocomposite Properties 195
8.4.1 Thermal Stability 195
8.4.2 Flame Retardancy 197
8.5 Toward Fully Green Composites? 198
References 201
9 In Situ Preparation of Conducting Polymer Nanocomposites 211
Liping Yang, Cher Ling Toh, and Xuehong Lu
9.1 Introduction 211
9.1.1 Electrically Conductive Polymer Nanocomposites and Their
Applications 212
9.1.2 Percolation Theory 213
9.1.3 Factors Affecting the Electrical Conductivity of
Nanocomposites 214
9.1.3.1 Physical Properties of the Fillers 214
9.1.3.2 Filler Distribution and Dispersion 216
9.1.3.3 Physical Properties of Polymer Matrices 216
9.1.3.4 Filler Orientation and Alignment 217
9.1.3.5 Nanocomposite Fabrication Methods and Conditions 218
Contents
IX
9.2 9.2.1 9.2.1.1 9.2.1.2 9.2.1.3 9.2.2 9.2.2.1 9.2.2.2 9.3 In Situ Preparation of Conductive Nanocomposites 219 In Situ Polymerization Strategy 219 Step Growth 220 Chain Growth 224 Aligning Conductive Fillers in in situ Polymerization Processes 227 In Situ Formation of Conducting Polymer Nanocomposites 228 In Situ Formation of rGO-Based Polymer Nanocomposites 228 In Situ Formation of Metallic Conductive Pathways 232 Challenges and Outlook 233 References 235
10 Near [R Spectroscopy for the Characterization of Dispersion in Polymer-Clay Nanocomposites 241 Ana Vera Machado՝, Joana Margarida Barbas, and Jose Antonio Covas
10.1 10.2 10.3 10.4 10.5 10.6 10.7 Introduction 241 Morphology and Properties 241 Preparation Methods 243 Characterization Techniques 243 Dispersion by Melt Mixing 247 Online and Inline Monitoring of Dispersion 249 Conclusions 259 References 259
11 Synthesis of Polymer Nanocomposites in Supercritical C02 267 Yuvaraj Haldorai andJae֊Jin Shim
11.1 11.2 11.3 11.4 Introduction 267 Background on Supercritical C02 268 Physical and Chemical Properties of scC02 270 Preparation of Polymer/Inorganic Filler Nanocomposites in Supercritical C02 272
11.4.1 11.4.1.1 11.4.1.2 11.4.2 11.4.2.1 11.4.2.2 11.5 Ex Situ Method 272 Solution Blending 272 Melt Blending 272 In Situ Method 276 Synthesis of Nanocomposites by Dispersion Polymerization 277 Synthesis of Nanocomposites by Other Techniques 281 Conclusions 286 References 286
Index 291
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| id | DE-604.BV042211198 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T01:15:24Z |
| institution | BVB |
| isbn | 9783527334551 9783527670307 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027649887 |
| oclc_num | 915520010 |
| open_access_boolean | |
| owner | DE-11 DE-703 DE-29T |
| owner_facet | DE-11 DE-703 DE-29T |
| physical | XVI, 297 S. Ill., graph. Darst. |
| publishDate | 2015 |
| publishDateSearch | 2015 |
| publishDateSort | 2015 |
| publisher | Wiley-VCH |
| record_format | marc |
| series | Polymer nano-, micro- & macrocomposites |
| series2 | Polymer nano-, micro- & macrocomposites |
| spelling | Synthesis techniques for polymer nanocomposites ed. by Vikas Mittal Weinheim Wiley-VCH 2015 XVI, 297 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Polymer nano-, micro- & macrocomposites 6 Polymergemisch (DE-588)4175243-0 gnd rswk-swf Nanokomposit (DE-588)4768127-5 gnd rswk-swf Polymere (DE-588)4046699-1 gnd rswk-swf Herstellung (DE-588)4159653-5 gnd rswk-swf Synthese (DE-588)4418958-8 gnd rswk-swf Verbundwerkstoff (DE-588)4062670-2 gnd rswk-swf Kunststoff (DE-588)4033676-1 gnd rswk-swf Nanostrukturiertes Material (DE-588)4342626-8 gnd rswk-swf Polymere (DE-588)4046699-1 s Nanokomposit (DE-588)4768127-5 s Synthese (DE-588)4418958-8 s DE-604 Kunststoff (DE-588)4033676-1 s Verbundwerkstoff (DE-588)4062670-2 s Nanostrukturiertes Material (DE-588)4342626-8 s Herstellung (DE-588)4159653-5 s Polymergemisch (DE-588)4175243-0 s Mittal, Vikas Sonstige (DE-588)1022155490 oth Erscheint auch als Online-Ausgabe, EPUB 978-3-527-67032-1 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-67031-4 Erscheint auch als Online-Ausgabe, PDF 978-3-527-67033-8 Polymer nano-, micro- & macrocomposites 6 (DE-604)BV040393302 6 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027649887&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Klappentext Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027649887&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Synthesis techniques for polymer nanocomposites Polymer nano-, micro- & macrocomposites Polymergemisch (DE-588)4175243-0 gnd Nanokomposit (DE-588)4768127-5 gnd Polymere (DE-588)4046699-1 gnd Herstellung (DE-588)4159653-5 gnd Synthese (DE-588)4418958-8 gnd Verbundwerkstoff (DE-588)4062670-2 gnd Kunststoff (DE-588)4033676-1 gnd Nanostrukturiertes Material (DE-588)4342626-8 gnd |
| subject_GND | (DE-588)4175243-0 (DE-588)4768127-5 (DE-588)4046699-1 (DE-588)4159653-5 (DE-588)4418958-8 (DE-588)4062670-2 (DE-588)4033676-1 (DE-588)4342626-8 |
| title | Synthesis techniques for polymer nanocomposites |
| title_auth | Synthesis techniques for polymer nanocomposites |
| title_exact_search | Synthesis techniques for polymer nanocomposites |
| title_full | Synthesis techniques for polymer nanocomposites ed. by Vikas Mittal |
| title_fullStr | Synthesis techniques for polymer nanocomposites ed. by Vikas Mittal |
| title_full_unstemmed | Synthesis techniques for polymer nanocomposites ed. by Vikas Mittal |
| title_short | Synthesis techniques for polymer nanocomposites |
| title_sort | synthesis techniques for polymer nanocomposites |
| topic | Polymergemisch (DE-588)4175243-0 gnd Nanokomposit (DE-588)4768127-5 gnd Polymere (DE-588)4046699-1 gnd Herstellung (DE-588)4159653-5 gnd Synthese (DE-588)4418958-8 gnd Verbundwerkstoff (DE-588)4062670-2 gnd Kunststoff (DE-588)4033676-1 gnd Nanostrukturiertes Material (DE-588)4342626-8 gnd |
| topic_facet | Polymergemisch Nanokomposit Polymere Herstellung Synthese Verbundwerkstoff Kunststoff Nanostrukturiertes Material |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027649887&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027649887&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV040393302 |
| work_keys_str_mv | AT mittalvikas synthesistechniquesforpolymernanocomposites |