Biorefineries: integrated biochemical processes for liquid biofuels
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Amsterdam [u.a.]
Elsevier
2014
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | XVIII, 277 S. Ill., graph. Darst. |
| ISBN: | 9780444594983 |
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Datensatz im Suchindex
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|---|---|
| adam_text | Contents
ñ-
Contributors
............................................................................................................xiii
Preface
......................................................................................................................xv
About the Editors
...................................................................................................xvii
PART I CELLULOSIC BIOMASS PROCESSING
&
BIOREFINERY ROAD MAP
_______________________
CHAPTER
1
An Overview of Existing Individual Unit Operations
........3
1.1
Introduction
.....................................................................................3
1.2
Biochemical Processes
....................................................................5
1.2.1
Biomass
Pretreatment
Technologies and their
Challenges
..............................................................................7
1.2.2
Physical
Pretreatment
............................................................9
1.2.3
Chemical and Physicochemical
Pretreatment
......................10
1.2.4
Biological
Pretreatment
.......................................................11
1.3
Enzymatic Hydrolysis
...................................................................11
1.3.1
Enzymatic Processes
............................................................11
1.3.2
Factors Affecting the Enzymatic Process
............................12
1.4
Ethanol
Production by Fermentation
............................................12
1.4.1
Process Requirements for Ethanol-Fermenting
Organisms
............................................................................13
1.4.2
Fermentation Operations and Processes
..............................14
1.4.3
Fermentation Inhibitors
.......................................................14
1.4.4
Product Recovery
.................................................................15
1.4.5
Methods for Breaking the Azeotrope
..................................16
1.5
Butanol
Production by Fermentation
............................................16
1.5.1
Processes for n-Butanol Production
.....................................16
1.5.2
Fermentation Modes of Operation
.......................................18
1.5.3
Recovery and In Situ Separation
.........................................18
1.5.4
Detoxification of Inhibitory Compounds
.............................20
1.5.5
Strain Improvement
.............................................................21
1.6
Thermochemical Conversion
........................................................22
1.6.1
Initial Processes
—
Preparation Stages
.................................22
1.6.2
Thermochemical Treatment
—
Gasification
..........................22
1.6.3
Cleaning and Conditioning of Syngas
.................................23
1.6.4
Product Manufacturing Stage
—
Catalytic Reaction
and Syngas Fermentation
.....................................................24
1.6.5
Syngas Fermentation
...........................................................24
vi
Contents
1.7
Perspectives
...................................................................................25
References
...........................................................................................26
CHAPTER
2
Biomass for Biorefining: Resources, Allocation,
Utilization, and Policies
........................................37
2.1
Introduction
...................................................................................37
2.1.1
Role of Biomass
...................................................................37
2
Л
.2
Biomass Availability
............................................................38
2.1.3
Allocation of Supply
............................................................39
2.1.4
Overcoming Utilization Issues
.............................................39
2.1.5
Policies and Statutes
............................................................40
2.2
Biomass Resources
.......................................................................40
2.2.1
Types of Biomass
.................................................................40
2.2.2
Supply of Biomass
...............................................................42
2.2.3
Production of Biomass
.........................................................44
2.3
Biomass Allocation
.......................................................................45
2.3.1
Uses of Biomass
..................................................................45
2.3.2
Biomass Logistics
................................................................47
2.4
Biomass Utilization
......................................................................47
2.4.1
Pretreatment
of Biomass
......................................................47
2.4.2
Genetic Modification of Biomass
........................................48
2.4.3
Biomass Sites of Use
...........................................................49
2.5
Biomass Policies
...........................................................................50
2.5.1
Biofuel Policies
....................................................................50
2.5.2
Land Use and GHG Requirements
......................................51
2.5.3
Regulation of Genetic Engineering
......................................52
2.6
Perspectives
...................................................................................54
References
...........................................................................................55
CHAPTER
3
Biorefinery Roadmaps
...........................................59
3.1
Introduction: The Biorefinery Vision for Energy, Chemical,
and Material Sustainability
...........................................................59
3.2
Sustainability as a New Business Model
......................................63
3.3
Achieving Integrated Processing
..................................................65
3.4
Perspectives
...................................................................................67
References
...........................................................................................67
CHAPTER
4
Integration of
(Hemü-Cellulosic
Biofuels
Technologies with Chemical Pulp Production
.........73
4.1
Integrated Forest Biorefinery Concepts
........................................73
4.1.1
Woody Biomass as a Multiproduct Feedstock
.....................73
4Л
.2
Opportunities for Integration
...............................................74
4,1.3
Recovery and Utilization of Non-Hemicellulose
Fractions
..............................................................................75
Contents
vii
4.2 Hemicelluloses
Derived from Chemical Pulping Processes
.........79
4.2.1
Hemicelluloses
.....................................................................79
4.2.2
Hemicelluloses from Thermomechanical Pulping and
Chemomechanical Pulping
..................................................80
4.2.3
Hemicelluloses from
Sulfite
Pulping
...................................81
4.2.4
Hemicelluloses from Dissolving Pulp Production
...............82
4.2.5
Hemicellulose Preextractions Prior to Pulping:
Autohydrolysis
.....................................................................83
4.2.6
Hemicellulose Preextractions Prior to Pulping: Alkaline
Extraction
.............................................................................86
4.3
Integration of Hemicellulose Recovery and Utilization
...............88
4.3.1
Processing Options for the Generation of Products from
Recovered Polymeric Hemicellulose
...................................88
4.3.2
Processing Options for the Generation of Products from
Hemicellulose Monomers
....................................................89
4.4
Perspectives
...................................................................................91
References
...........................................................................................91
CHAPTER
5
Integrated Processes for Product Recovery
..........101
5.1
Introduction....
.............................................................................101
5.2
Alternative Product Recovery Techniques
..................................102
5.2.1
Adsorption
.........................................................................102
5.2.2
Liquid-liquid Extraction
....................................................104
5.2.3
Pervaporation
.....................................................................106
5.2.4
Vacuum Fermentation and Simultaneous Recovery
..........107
5.2.5
Gas Stripping
.....................................................................108
5.2.6
Use of Other Separation Techniques
.................................109
5.3
Integrated Product Recovery Processes
......................................110
5.3.1
Ethanol
...............................................................................110
5.3.2
Butanol
...............................................................................
Ill
5.3.3
2,3-ButanedioI
...................................................................112
5.4
Perspectives
.................................................................................115
Acknowledgments
..............................................................................115
References
.........................................................................................116
PART II CELLULOSIC
ETHANOL
__________________________
CHAPTER
6
Development of Growth-Arrested Bioprocesses with
Corynebacterium glutamicum for Cellulosic
Ethanol
Production from Complex Sugar Mixtures
.............121
6.1
Introduction
.................................................................................121
6.2
What is a Growth-Arrested
bioprocess?
.....................................122
6.2.1
Characteristics of Growth-Arrested Bioprocesses
.............122
viii Contents
6.2.2
Process Design Options for Growth-Arrested Bioprocesses
... 123
6.3
Research and Development for Cellulosic
Ethanol
Production
by C. glutamicum
........................................................................125
6.3.1
Metabolic Engineering for Highly Efficient Conversion
of Sugar Mixtures
..............................................................126
6.3.2
Tolerance to Fermentation Inhibitors Derived from
Lignocellulosic Biomass
....................................................127
6.4
Other Applications of Growth-Arrested
Bioprocess
in
Biorefineries
................................................................................128
6.4.1
Amino
Acids
......................................................................128
6.4.2
Isobutanol
...........................................................................132
6.4.3
D-Lactic Acid
....................................................................133
6.5
Perspectives
.................................................................................134
References
.........................................................................................135
CHAPTER
7
Consolidated
Bioprocessing
for
Ethanol
Production
.........................................................141
7.1
Introduction
.................................................................................141
7.2
Biochemical Processes for
Ethanol
Production from Cellulosic
Biomass
.......................................................................................142
7.2.1
Pretreatment
.......................................................................142
7.2.2
Cellulase Production
..........................................................142
7.2.3
Enzymatic Hydrolysis
........................................................144
7.2.4
Microbial Fermentation
.....................................................144
7.2.5
Product Recovery
...............................................................146
7.3
Development of Biomass Processing Configurations
.................146
7.4
Aspects of Consolidated
Bioprocessing
.....................................147
7.4.1
Economic Benefits of
СВР
................................................147
7.5
Approaches to Developing CBP-enabling Microorganisms
.......149
7.5.1
The Native Strategy for Developing CBP-enabling
Microorganisms
.................................................................149
7.5.2
The
Recombinant
Strategy for Developing CBP-enabling
Microorganisms
.................................................................151
7.6
Perspectives
.................................................................................153
References
.........................................................................................153
CHAPTER
8
Integration of
Ethanol
Fermentation with Second
Generation Biofuels Technologies
........................161
8.1
Integration of Fermentation into Cellulosic Biofuel Processes
.....161
8.2
Fermentation Approaches Employed in First-Generation
Ethanol
Processes
.......................................................................163
8.2.1
Processes for First-Generation
Ethanol
.............................163
8.2.2
Mode of Operation and Cell Recycle
................................164
Contents ix
8.3 Integration
of
Lignocellulose Hydroly
zate
Fermentation...........167
8.3.1 Hydrolyzate-Derived Inhibitors.........................................168
8.3.2
Xylose
Fermentation..........................................................169
8.3.3 High-Solids Integration and Fermentation
Mode of
Operation...........................................................................170
8.3.4
Examples of
Fermentation Integration in Cellulosic
Biofuel
Processes
...............................................................171
8.4
Aerobic Yeast Cultivation for the Production of Cell Mass
.......172
8.4.1
Production of Yeast Cell Mass from Sugar and Starch
Streams
..............................................................................172
8.4.2
Generation of Cell Mass from Hydrolyzates
.....................174
8.5
Case Study: Aerobic Cultivation of S. cerevisiae TMB-
3400-FT30-3 on Dilute Acid-Pretreated Softwood
Hydrolyzate
.................................................................................175
8.5.1
Media Requirements for Aerobic Growth
.........................176
8.6
Perspectives
.................................................................................178
References
.........................................................................................179
PART III CELLULOSIC
BUTANOL
__________________________
CHAPTER
9
Mixed Sugar Fermentation by Clostridia and
Metabolic Engineering for
Butanol
Production
.........................................................191
9.1
Introduction
.................................................................................191
9.2
Mixed-Sugar Fermentation by Solventogenic Clostridia
...........194
9.3
Metabolic Engineering of Solventogenic Clostridia for
Butanol
Production
.....................................................................196
9.3.1
Simultaneous and Efficient Use of Pentose and Hexose
Sugars
................................................................................196
9.3.2
Production of Enhanced Levels of
Butanol
.......................197
9.3.3
Elimination of Acetone Production
...................................199
9.4
Perspectives
.................................................................................200
Acknowledgments
..............................................................................201
References
.........................................................................................201
CHAPTER
10
Integrated
Bioprocessing
and Simultaneous
Product Recovery for
Butanol
Production
..........
í
205
10.1
Introduction
..............................................................................205
10.2
Recovery of
Butanol
by Adsorption
.........................................207
10.2.1
Use of Glucose
..............................................................208
10.3
Recovery of
Butanol
by Extraction
..........................................208
10.3.1
Use of Glucose
..............................................................208
10.3.2
Use of Whey Permeate
..................................................210
Contents
10.3.3
Extractive Production of
Butanol
from
Lignocelluloses
......................................................-.......211
10.4
Recovery of
Butanol
by Perstraction
........................................212
10.4.1
Use of Glucose
..............................................................212
10.4.2
Use of Potato Waste
......................................................212
10.4.3
Use of Whey Permeate or Lactose
................................212
10.4.4
Use of Lignocellulosic Biomass
....................................213
10.5
Separation of
Butanol
by Gas Stripping....
...............................213
10.5.1
Use of Whey Permeate
..................................................213
10.5.2
Use of Glucose
..............................................................214
10.5.3
Use of Cellulosic Hydrolyzates and Cellulosic
Biomass
.........................................................................215
10.6
Recovery of
Butanol
by Reverse Osmosis
...............................215
10.6.1
Use of Glucose
..............................................................215
10.7
Recovery of
Butanol
by Pervaporation
....................................216
10.7.1
Use of Glucose
..............................................................216
10.7.2
Use of Whey Permeate
..................................................217
10.8
Recovery of
Butanol
Using a Vacuum
.....................................218
10.8.1
Use of Glucose
..............................................................218
10.9
Process Economics of
Butanol
Production
...............................218
10.10
Perspectives
............................................................................219
References
.........................................................................................219
CHAPTER
11
Integrated Production of
Butanol
from Glycerol
.... 225
11.1
Introduction: Glycerol Glut
......................................................225
11.1.1
Value-Added Conversion of Glycerol
...........................226
11.2
Glycerol-to-Butanol Conversion
..............................................227
11.2.1
Improving Product Yield and Productivity
....................228
11.2.2
Butanol
Toxicity
and Extractive Fermentation
............,.229
11.3
Integrated Biorefinery
...............................................................230
11.4
Perspectives
..............................................................................231
References
.........................................................................................231
PART IV PROCESS ECONOMICS
&
FARM-BASED
________
BIOREFINERY
__________________________________
CHAPTER
12
Process Economics of Renewable Biorefineries:
Butanol
and
Ethanol
Production in Integrated
Bioprocesses from Lignocellulosics and Other
Industrial By-Products
........................................237
12.1
Introduction
..............................................................................237
12.2
Program for Material and Energy Balance and Economic
Analysis
....................................................................................239
Contents xi
12.3
Process
Development
and Economics of
Butanol
Production
from Corn
.................................................................................239
12.4
Process Economics of
Butanol
Production from Glycerol
.......243
12.5
Economics of
Butanol
Production from Lignocellulosic
Biomass
....................................................................................245
12.6
Economics of
Ethanol
Production from Corn and
Lignocellulosic Biomass
.........................................................247
12.7
Perspectives
..............................................................................251
Acknowledgments
..............................................................................252
References
.........................................................................................252
CHAPTER
13
Integrated Farm-Based Biorefinery
.......................255
13.1
Introduction
..............................................................................255
13.2
The Integrated Farm-Based Biorefinery (IFBBR)
....................257
13.3
Biological Conversion Chemistry
............................................258
13.4
Mass-and-Energy Balances
......................................................261
13.5
Advantages of the IFBBR System over Corn Stover
Ethanol
Production
................................................................................265
13.6
Perspectives
..............................................................................266
Acknowledgment
................................................................................269
References
.........................................................................................269
Index
...................................................................................................271
Biorefineries
Integrated Biochemical Processes for Liquid Biofuels
Edited by
Nasib Qureshi, United States Department of Agriculture, National Center for Agricultural Utilization
Research (Bioenergy Research),
ARS,
Peoría,
IL, USA; David
Hodge, Michigan
State
University,
MI, USA
and
Alain A. Vertes,
London
Business
School, NxR Biotechnologies GmbH, Basel, Switzerland
Presents an integrated approach to the
ethanol
and
butanol
production
processes from agricultural residues and bioenergy crops, and discusses
improvements through research, consolidation, and integration of the processes
Biorefineries details the production of
ethanol
and
butanol
from cellulosic biomass and glycerol.
The commercialization of technologies for cellulosic biofuels depends on overcoming a number of
challenges. Foremost among these are successful integration of individual unit operations as well as
product diversification. This book addresses opportunities for improved efficiency and economics
through process integration. The scope of this book covers a range of related topics that include
biomass availability and policy aspects, process cost comparison and business risk management,
and a presentation of the range of technologies and operational strategies for the integration of
pretreatment,
enzymatic hydrolysis, fermentation, product, and water recovery along with process
integration concepts for forest and farm-based biorefineries. Overall, a strong emphasis is placed
on technologies for process integration and consolidation that would reduce cost of production of
these biofuels.
Biorefineries
•
Outlines the economic benefits of process consolidation and integration in biorefineries
employing biochemical conversions for the production of cellulosic biofuels
•
Includes an overview of existing technologies for fractionation and biochemical conversion of
lignocellulosic biomass to fermentation-derived biofuels with a strong focus on opportunities
for integration within the processes and potential synergies with other processes such as
chemical pulp production and anaerobic digestion
•
Covers economic analysis of
ethanol
and
butanol
production from corn (for cost
comparisons), agricultural residues, and glycerol using technologies for energy-efficient
product recovery and process integration
•
Focuses on biofuels with the potential to act as a stepping-stone to cost-efficient processes for
the production of an array of cellulosic biomass-derived commodity chemicals
|
| any_adam_object | 1 |
| building | Verbundindex |
| bvnumber | BV042203633 |
| classification_rvk | VN 5470 WF 9700 ZP 3760 |
| ctrlnum | (OCoLC)903208466 (DE-599)BVBBV042203633 |
| discipline | Chemie / Pharmazie Biologie Energietechnik |
| format | Book |
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| id | DE-604.BV042203633 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T01:15:13Z |
| institution | BVB |
| isbn | 9780444594983 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-027642464 |
| oclc_num | 903208466 |
| open_access_boolean | |
| owner | DE-29T DE-703 |
| owner_facet | DE-29T DE-703 |
| physical | XVIII, 277 S. Ill., graph. Darst. |
| publishDate | 2014 |
| publishDateSearch | 2014 |
| publishDateSort | 2014 |
| publisher | Elsevier |
| record_format | marc |
| spelling | Biorefineries integrated biochemical processes for liquid biofuels ed. by Nasib Qureshi ... Amsterdam [u.a.] Elsevier 2014 XVIII, 277 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Biokraftstoff (DE-588)4145658-0 gnd rswk-swf Bioraffinerie (DE-588)7742513-3 gnd rswk-swf Chemieanlage (DE-588)4121084-0 gnd rswk-swf Kraftstoffherstellung (DE-588)4165454-7 gnd rswk-swf Biomasse (DE-588)4006877-8 gnd rswk-swf Biochemie (DE-588)4006777-4 gnd rswk-swf Bioverfahrenstechnik (DE-588)4307166-1 gnd rswk-swf Bioraffinerie (DE-588)7742513-3 s Biokraftstoff (DE-588)4145658-0 s DE-604 Biomasse (DE-588)4006877-8 s Bioverfahrenstechnik (DE-588)4307166-1 s Kraftstoffherstellung (DE-588)4165454-7 s Biochemie (DE-588)4006777-4 s Chemieanlage (DE-588)4121084-0 s Qureshi, Nasib Sonstige oth Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027642464&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027642464&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Biorefineries integrated biochemical processes for liquid biofuels Biokraftstoff (DE-588)4145658-0 gnd Bioraffinerie (DE-588)7742513-3 gnd Chemieanlage (DE-588)4121084-0 gnd Kraftstoffherstellung (DE-588)4165454-7 gnd Biomasse (DE-588)4006877-8 gnd Biochemie (DE-588)4006777-4 gnd Bioverfahrenstechnik (DE-588)4307166-1 gnd |
| subject_GND | (DE-588)4145658-0 (DE-588)7742513-3 (DE-588)4121084-0 (DE-588)4165454-7 (DE-588)4006877-8 (DE-588)4006777-4 (DE-588)4307166-1 |
| title | Biorefineries integrated biochemical processes for liquid biofuels |
| title_auth | Biorefineries integrated biochemical processes for liquid biofuels |
| title_exact_search | Biorefineries integrated biochemical processes for liquid biofuels |
| title_full | Biorefineries integrated biochemical processes for liquid biofuels ed. by Nasib Qureshi ... |
| title_fullStr | Biorefineries integrated biochemical processes for liquid biofuels ed. by Nasib Qureshi ... |
| title_full_unstemmed | Biorefineries integrated biochemical processes for liquid biofuels ed. by Nasib Qureshi ... |
| title_short | Biorefineries |
| title_sort | biorefineries integrated biochemical processes for liquid biofuels |
| title_sub | integrated biochemical processes for liquid biofuels |
| topic | Biokraftstoff (DE-588)4145658-0 gnd Bioraffinerie (DE-588)7742513-3 gnd Chemieanlage (DE-588)4121084-0 gnd Kraftstoffherstellung (DE-588)4165454-7 gnd Biomasse (DE-588)4006877-8 gnd Biochemie (DE-588)4006777-4 gnd Bioverfahrenstechnik (DE-588)4307166-1 gnd |
| topic_facet | Biokraftstoff Bioraffinerie Chemieanlage Kraftstoffherstellung Biomasse Biochemie Bioverfahrenstechnik |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027642464&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027642464&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT qureshinasib biorefineriesintegratedbiochemicalprocessesforliquidbiofuels |