Surface chemistry of surfactants and polymers:
Gespeichert in:
| Hauptverfasser: | , , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Chichester
Wiley
2014
|
| Ausgabe: | 1. publ. |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | XIV, 479 S. Illustrationen, Diagramme |
| ISBN: | 9781119961246 |
Internformat
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| 245 | 1 | 0 | |a Surface chemistry of surfactants and polymers |c Bengt Kronberg, Krister Holmberg, Bjorn Lindman |
| 250 | |a 1. publ. | ||
| 264 | 1 | |a Chichester |b Wiley |c 2014 | |
| 300 | |a XIV, 479 S. |b Illustrationen, Diagramme | ||
| 336 | |b txt |2 rdacontent | ||
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| 500 | |a Includes bibliographical references and index | ||
| 650 | 4 | |a Surface chemistry | |
| 650 | 4 | |a Surface active agents | |
| 650 | 4 | |a Polymer solutions | |
| 650 | 4 | |a Suspensions (Chemistry) | |
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Datensatz im Suchindex
| _version_ | 1804152631234396160 |
|---|---|
| adam_text | Titel: Surface chemistry of surfactants and polymers
Autor: Kronberg, Bengt
Jahr: 2014
Contents
Preface xiïi
Acronyms xv
1 Types of Surfactants, their Synthesis, and Applications 1
Definition of a Surfactant 1
Surfactants Adsorb at Interfaces 2
Surfactants Aggregate in Solution and at Interfaces 4
All Surfactants Contain at Least One Polar Head Group and at Least One
Hydrophobic Tail 5
Surface Active Compounds are Plentiful in Nature 7
Surfactant Raw Materials may be Based on Petrochemicals or Oleochemicals 7
Surfactants are Classified by the Polar Head Group 10
Hydrotropes and Solubilization 23
Gemini Surfactants have Special Features 26
Cleavable Surfactants are Attractive from an Environmental Point of View 29
Self-Aggregation of a Surfactant may Increase or Decrease the Hydrolysis
Rate of Surfactants Containing a Labile Bond 36
Use of Polymerizable Surfactants is a Way to Immobilize the Surfactant 40
Applications of Polymerizable Surfactants 42
Special Surfactants Give Extreme Surface Tension Reduction 46
Bibliography 47
2 Environmental and Health Aspects of Surfactants 49
Environmental Concern is a Strong Driving Force for Surfactant
Development 49
The Polar Head Group 50
The Hydrocarbon Tail 53
Biodegradability 53
The Rate of Biodegradation Depends on the Surfactant Structure 55
Aquatic Toxicity 58
Other Regulatory Concerns 58
Dermatological Aspects of Surfactants 59
REACH 62
Bibliography 64
vi Contents
3 Two Fundamental Forces in Surface and Colloid Chemistry 65
Counterion Binding Affects Self-Assembly and Adsorption of Surfactants
and Polymers 65
The Hydrophobic Effect is due to the High Energy Density of Water 70
Bibliography 74
4 Surfactant Self-Assembly: General Aspects and Spherical Micelles 75
Amphiphilic Molecules Self-Assemble 75
Surfactants Start to Form Micelles at the CMC 77
CMC Depends on Chemical Structure 79
Temperature and Cosolutes Affect CMC 81
The Solubility of Surfactants may be Strongly Temperature
Dependent 83
Driving Forces of Micelle Formation and Thermodynamic Models 85
The Association Process and Counterion Binding can be Monitored
by NMR Spectroscopy 88
Hydrophobic Compounds can be Solubilized in Micelles 90
Micelle Size and Structure 91
A Geometrical Consideration of Chain Packing Is Useful 92
Kinetics of Micelle Formation 93
Surfactants may Form Aggregates in Solvents Other than Water 93
General Comments on Amphiphile Self-Assembly 93
Bibliography 94
5 Introduction to Phase Diagrams 95
The Phase Rule Regulates the Number of Phases 95
Binodal and Spinodal—Metastable and Unstable 96
The Gibbs Triangle 98
Phase Behavior and the Gibbs Triangle 99
Examples of How to Read Phase Diagrams 101
Temperature is an Important Parameter 104
Four Components can be Represented by Pseudo-Phase Diagrams 106
Complexes Formed from Species of Opposite Charge Represent
Complicated Phase Diagrams 108
Bibliography 111
6 Surfactant Self-Assembly: Beyond the Spherical Micelle 113
Micelle Type and Size Vary with Concentration 113
Micellar Growth is Different for Different Systems 115
The Shape of the Micelles Affects the Rheology of Solutions
of Gemini Surfactants 119
Surfactant Phases are Built up by Discrete or Infinite Self-Assemblies 121
Contents vii
Micellar Solutions can Reach Saturation 122
Structures of Liquid Crystalline Phases 123
How to Determine Phase Diagrams 125
Binary Surfactant-Water Phase Diagrams can be Very Different 127
Three-Component Phase Diagrams are Complex but have a Direct
Bearing on Applications 129
Surfactant Geometry and Packing Determine Aggregate Structure:
The Packing Parameter is a useful Concept 131
Polar Lipids Show the same Phase Behavior as other Amphiphiles 134
Liquid Crystalline Phases may form in Solvents other than Water 135
Bibliography 136
7 Surfactants and Polymers Containing Oxyethylene Groups Show
a Complex Behavior 137
Polyoxyethylene Chains make up the Hydrophilic Part of Many Surfactants
and Polymers 137
CMC and Micellar Size of Oxyethylene-Based Surfactants are Strongly
Temperature Dependent 138
Phase Diagrams are Very Different at Different Temperatures 140
The L3 or Sponge Phase 143
Sequence of Self-Assembly Structures as a Function of Temperature 143
The Critical Packing Parameter and the Spontaneous Curvature Concepts
are Useful Tools 143
Clouding is a Characteristic Feature of Polyoxyethylene-Based Surfactants
and many Nonionic Polymers 145
Clouding is Strongly Dependent on Cosolutes 147
Physicochemical Properties of Block Copolymers Containing
Polyoxyethylene Segments Resemble those of Polyoxyethylene-Based
Surfactants 148
Temperature Anomalies of Oxyethylene-Based Surfactants and Polymers
are Ubiquitous 150
Temperature Anomalies are Present in Solvents Other than Water and for
Other Polymers 151
Bibliography 152
8 Surfactant Adsorption at Solid Surfaces 153
Surfactant Adsorption at Hydrophobic Surfaces 154
Surfactant Adsorption at Hydrophilic Surfaces 159
Surfactant Self-Assemblies at Surfaces Have Various Shapes 166
Adsolublization is the Solubilization of Substrates in the Surface
Aggregates 168
Analysis of Surfactant Adsorption Isotherms 169
Model Surfaces and Methods to Determine Adsorption 171
Bibliography 173
viii Contents
9 Polymers in Solution 175
Polymer Properties are Governed by the Choice of Monomers 175
Molecular Weight is an Important Parameter 176
Dissolving a Polymer can be a Problem 178
The Solubility Parameter is Used to Find the Right Solvent 178
Polyelectrolytes are Polymers with Charges 179
Polymer Size and Shape are Important Characteristics 180
There are Various Classes of Water-Soluble Polymers 182
Polymers are Used as Thickeners 185
Polymers in Solution Differ from Ordinary Mixtures 186
There is a Bridge to Colloidal Systems 189
Phase Equilibrium Considerations 190
Mixtures of Two Polymers in Water 191
Bibliography 195
10 Surface Active Polymers 197
Surface Active Polymers can be Designed in Different Ways 197
Polymers with a Hydrophilic Backbone and Hydrophobic
Side Chains 198
Polymers with a Hydrophobic Backbone and Hydrophilic
Side Chains 203
Polymers with Alternating Hydrophilic and Hydrophobic Blocks 207
Polymeric Surfactants have Attractive Properties 209
Bibliography 209
11 Adsorption of Polymers at Solid Surfaces 211
The Adsorbed Amount Depends on Polymer Molecular Weight 212
Solubility has a Profound Influence on the Adsorption 215
Adsorption of Polyelectrolytes 217
Polymer Adsorption is Practically Irreversible 222
Polymers can be Desorbed 223
The Kinetics of Polymer Adsorption is Limited by Rearrangement 225
Measurement of Polymer Adsorption 226
Bibliography 229
12 Surface and Interfacial Tension 231
The Surface Tension of Droplets Increases their Pressure 233
Surface Tension is Related to Adsorption 233
The Surface Tension of Surfactant Solutions 236
Dynamic Surface Tension 240
Impurities in Surfactant Samples can Play a Major Role 242
Surface Tension of Polymer Solutions 243
Interfacial Tension
Measurement of Surface Tension
Bibliography
13 Mixed Surfactant Systems
The Behavior of Surfactant Mixtures Depends on the Relative Surface
Activities and on Interactions
The CMC of an Ideal Mixture has a Simple Relationship to the Individual
CMC Values
Many Other Surfactant Systems Require a Net Interaction
The Concept of Mixed Micelles can also be Applied to Amphiphiles
not Forming Micelles
Mixed Surfactant Systems at Surfaces
Competitive Adsorption can be Understood from Thermodynamic
Considerations
Surfactant Mediated Surfactant Adsorption
Surfactant Mixtures at the Air-Water Interface
Mixed Surfactant Systems at Higher Concentrations Show
Interesting Features
Bibliography
14 Surfactant-Polymer Systems
There are many Technical Applications of Polymer-Surfactant
Mixtures
Polymers can Induce Surfactant Aggregation
Attractive Polymer-Surfactant Interactions Depend on both Polymer
and Surfactant
Surfactant Association to Surface Active Polymers can be Strong
The Interaction between a Surfactant and a Surface Active Polymer
is Analogous to Mixed Micelle Formation
Phase Behavior of Polymer-Surfactant Mixtures Resembles that
of Mixed Polymer Solutions
Phase Behavior of Polymer-Surfactant Mixtures in Relation to
Polymer-Polymer and Surfactant-Surfactant Mixtures
Oppositely Charged Systems are Complex: Phase Structures and
Phase Diagrams
Polymer-Surfactant Interactions are Significant for Gel Swelling and
Gel Particles
Polymers may Change the Phase Behavior of Infinite Surfactant
Self-Assemblies
DNA is Compacted by Cationic Surfactants, which Gives Opportunities
for Gene Therapy
Bibliography
X Contents
15 Surfactant-Protein Mixtures 295
Proteins are Amphophilic 295
Surfactant-Protein Interactions have Broad Relevance 295
Surfactants Associate to Proteins and may Change their
Conformation 296
Surface Tension and Solubilization give Evidence for
Surfactant Binding to Proteins 297
The Binding Isotherms are Complex 298
Protein-Surfactant Solutions may have High Viscosities 299
Protein-Surfactant Solutions may give rise to Phase Separation 300
Surfactants may Induce Denaturation of Proteins 302
Bibliography 303
16 Surfactant-Polymer Mixtures at Interfaces 305
Surfactant-Polymer Interactions can both Increase and Decrease
Adsorption 307
Surfactant-Polymer Systems Showing Associative Phase Separation
Adsorb at Hydrophilic Surfaces 309
Surfactant-Polymer Complexes also Adsorb at Hydrophobic Surfaces 311
Surfactant-Polymer Systems Showing Segregative Phase Separation give
Competitive Adsorption 312
Polymer-Surfactant Mixtures at the Liquid-Air Interface 313
Bibliography 314
17 Microemulsions 315
The Term Microemulsion is Misleading 315
Oil-Water-Surfactant Systems can be Illustrated by Phase Diagrams 315
The Choice of Surfactant is Decisive 318
Ternary Phase Diagrams can be Complex 320
Microemulsions Based on CmEn Surfactants and Alkanes Clearly
Illustrate the Importance of a Balanced System 320
Microemulsions with Alkyl Polyglucosides 324
Adding a Polymer can Significantly Increase the Efficiency
of the Surfactant 324
Microemulsions with Single-Chain Ionic Surfactants Usually Require
a Hydrophobic Cosurfactant 326
The Microstructure is Controlled by Surfactant Properties 326
Molecular Self-Diffusion Probes Microstructure 328
Confinement, Obstruction, and Solvation Determine Solvent
Self-Diffusion in Microemulsions 329
Self-Diffusion Gives Evidence for a Bicontinuous Structure
at Balanced Conditions 332
Bibliography 333
Contents xi
18 Colloidal Stability 335
The Attractive Forces 335
Instabilities of Colloidal Dispersions—Six Routes to Destabilize
Dispersions 338
Stabilization with Particles 354
Stabilization by Lamellar Liquid Crystals 356
Electrophoretic Mobility—A Versatile Tool in the Assessment of Colloids 357
Bibliography 359
19 An Introduction to the Rheology of Polymer and Surfactant
Solutions 361
Rheology Deals with how Materials Respond to Deformation 361
Viscosity Measures how a Simple Fluid Responds to Shear 362
The Presence of Particles Changes the Flow Pattern and the Viscosity 365
The Rheology is Often Complex 367
Viscoelasticity 369
The Rheological Behavior of Surfactant and Polymer Solutions
Shows an Enormous Variation: Some Further Examples 370
Mixed Polymer-Surfactant Systems 374
Bibliography 375
20 Wetting and Wetting Agents, Hydrophobization
and Hydrophobizing Agents 377
Liquids Spread on Surfaces 377
The Critical Surface Tension of a Solid is a Useful Concept 380
The Critical Surface Tension can be Applied to Coatings 382
Capillary Forces are Related to Wetting 383
Surface Active Agents can Promote or Prevent Wetting and Spreading 383
Wetting Agents 385
Hydrophobizing Agents 386
Measuring Contact Angles 387
Bibliography 390
21 Solid Dispersions 391
Synthesis of Particles 392
Control of Nucleation and Growth is the Key to Monodispersity 392
Stabilization of Suspensions with Polymers 396
Stabilization of Suspensions with Surfactants 397
The Shape of Particles can be Regulated with Surfactants 398
The Surface of Particles can be Manipulated 399
Ceramic Processing Relates of Surface Chemistry 399
Particles Attach to Surfaces 401
Bibliography 401
xii Contents
22 Surfactant Assemblies as Templates 403
Mesoporous Materials 403
Inorganic Nanoparticles 409
A Microemulsion can be Used as Reaction Medium for Organic Synthesis 413
Microemulsions are Useful as Media for Enzymatic Reactions 416
Bibliography 417
23 Foaming of Surfactant Solutions 419
There are Transient Foams and Stable Foams 419
Two Conditions must be Fulfilled for a Foam to be Formed 420
There are Four Forces Acting on Foams 422
The Critical Packing Parameter Concept is a Useful Tool 424
Addition of Polymers might Increase or Decrease Foam Stability 427
Particles and Proteins can Stabilize Foams 428
Various Additives are Used to Break Foams 428
Bibliography 430
24 Emulsions and Emulsifiers 431
Emulsions are Dispersions of One Liquid in Another 431
Emulsifiers are Surfactants that Assist in Creating an Emulsion 432
The PIT Concept 432
The PIT Method of Selecting Emulsifier is Often Useful 435
Nonionic Surfactants are Versatile Emulsifiers 435
Ionic Surfactants have Analogous Behavior 437
Using Surfactant Mixtures as Emulsifiers 438
Bancroft s Rule may be Explained as a Marangoni Effect 439
Bancroft s Rule may be Related to the Surfactant Geometry 440
Hydrodynamics may Control what Type of Emulsion will Form 441
Other Stabilizing Agents for Emulsions 441
Emulsions can be Very Concentrated 441
Spontaneous Emulsification 443
Ouzo Emulsions 444
Other Types of Emulsions 445
Bibliography 445
25 Microemulsions for Soil and Oil Removal 447
A Detergent Formulation is Complex 447
Particulate Soil Removal 448
Oily Soil Removal 449
Microemulsion-Based Cleaning Formulations are Efficient 458
In Situ Generated Microemulsions are of Interest for Enhanced Oil Recovery 460
Bibliography 465
Index
467
|
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| indexdate | 2024-07-10T01:13:47Z |
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| publisher | Wiley |
| record_format | marc |
| spelling | Kronberg, Bengt Verfasser (DE-588)1064169740 aut Surface chemistry of surfactants and polymers Bengt Kronberg, Krister Holmberg, Bjorn Lindman 1. publ. Chichester Wiley 2014 XIV, 479 S. Illustrationen, Diagramme txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Surface chemistry Surface active agents Polymer solutions Suspensions (Chemistry) Polymere (DE-588)4046699-1 gnd rswk-swf Tensid (DE-588)4128790-3 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf Polymere (DE-588)4046699-1 s Oberflächenchemie (DE-588)4126166-5 s DE-604 Tensid (DE-588)4128790-3 s Holmberg, Krister 1946- Verfasser (DE-588)173571425 aut Lindman, Björn 1942 Verfasser (DE-588)1064169732 aut HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027584205&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kronberg, Bengt Holmberg, Krister 1946- Lindman, Björn 1942 Surface chemistry of surfactants and polymers Surface chemistry Surface active agents Polymer solutions Suspensions (Chemistry) Polymere (DE-588)4046699-1 gnd Tensid (DE-588)4128790-3 gnd Oberflächenchemie (DE-588)4126166-5 gnd |
| subject_GND | (DE-588)4046699-1 (DE-588)4128790-3 (DE-588)4126166-5 |
| title | Surface chemistry of surfactants and polymers |
| title_auth | Surface chemistry of surfactants and polymers |
| title_exact_search | Surface chemistry of surfactants and polymers |
| title_full | Surface chemistry of surfactants and polymers Bengt Kronberg, Krister Holmberg, Bjorn Lindman |
| title_fullStr | Surface chemistry of surfactants and polymers Bengt Kronberg, Krister Holmberg, Bjorn Lindman |
| title_full_unstemmed | Surface chemistry of surfactants and polymers Bengt Kronberg, Krister Holmberg, Bjorn Lindman |
| title_short | Surface chemistry of surfactants and polymers |
| title_sort | surface chemistry of surfactants and polymers |
| topic | Surface chemistry Surface active agents Polymer solutions Suspensions (Chemistry) Polymere (DE-588)4046699-1 gnd Tensid (DE-588)4128790-3 gnd Oberflächenchemie (DE-588)4126166-5 gnd |
| topic_facet | Surface chemistry Surface active agents Polymer solutions Suspensions (Chemistry) Polymere Tensid Oberflächenchemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=027584205&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT kronbergbengt surfacechemistryofsurfactantsandpolymers AT holmbergkrister surfacechemistryofsurfactantsandpolymers AT lindmanbjorn surfacechemistryofsurfactantsandpolymers |